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Foundation of plasma electrochemistry and its application to material process in liquid

Research Project

Project/Area Number 15H03584
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Plasma electronics
Research InstitutionTokyo Metropolitan University

Principal Investigator

Tochikubo Fumiyoshi  首都大学東京, 理工学研究科, 教授 (90244417)

Co-Investigator(Renkei-kenkyūsha) SHIRAI NAOKI  北海道大学, 大学院工学研究院, 准教授 (80552281)
SHINOHARA MASANORI  佐世保工業高等専門学校, 電気電子工学科, 准教授 (80346931)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsプラズマ電気化学 / グロー放電電解 / プラズマ誘起液相反応 / ナノ粒子生成 / 磁性ナノ粒子 / 溶存酸素 / 表面処理 / 放電プラズマ / 液相反応 / 親水化処理 / プラズマ化学 / ナノ材料 / 磁性粒子
Outline of Final Research Achievements

The purpose of this work is the academic foundation of plasma electrochemistry, which is regarded as the liquid-phase reaction induced by glow discharge electrolysis, and its application to material processes in liquid. For that purpose, we carried out (1) investigation of liquid-phase reaction in plasma electrochemistry, (2) magnetic nanoparticle generation, and (3) surface treatment of solid materials. It is clarified that the liquid-phase reaction is started from the very thin layer from the plasma-liquid interface by the electrons/ions/radicals irradiation of liquid surface from the glow discharge. For this application, Au/Ag composite nanoparticles and magnetite nanoparticles were synthesized and their synthesis processes were investigated. In addition, hydrophilization treatment of polypropylene as a target material was performed using plasma electrochemistry.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (43 results)

All 2018 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (38 results) (of which Int'l Joint Research: 18 results,  Invited: 8 results) Remarks (2 results)

  • [Journal Article] Synthesis of magnetic nanoparticles by atmospheric-pressure glow discharge plasma-assisted electrolysis2017

    • Author(s)
      Naoki Shirai, Taketo Yoshida, Satoshi Uchida and Fumiyoshi Tochikubo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 7 Pages: 076201-076201

    • DOI

      10.7567/jjap.56.076201

    • NAID

      210000148009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of liquid flow induced by atmospheric-pressure DC glow discharge in contact with liquid2017

    • Author(s)
      F. Tochikubo, T. Aoki, N. Shirai, and S. Uchida
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 4 Pages: 7-7

    • DOI

      10.7567/jjap.56.046201

    • NAID

      210000147531

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of magnetic nanoparticles by atmospheric-pressure glow discharge plasma-assisted electrolysis2017

    • Author(s)
      N. Shirai, T. Yoshida, S. Uchida, F. Tochikubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 印刷中

    • NAID

      210000148009

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Numerical simulation of atmospheric-pressure DC glow discharge using liquid electrode with noble gas flow2018

    • Author(s)
      F. Tochikubo, S. Uchida
    • Organizer
      ISPlasma2018 / IC-PLANTS2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 液体電極を有する大気圧直流グロー放電の二次元シミュレーション2018

    • Author(s)
      杤久保文嘉,内田諭
    • Organizer
      第65応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] グロー放電電解によるポリプロピレンの液中での親水化処理2018

    • Author(s)
      塙拓巳,中川雄介,内田諭,杤久保文嘉
    • Organizer
      第65応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Simulation of glow discharge electrolysis for material processing in liquid2017

    • Author(s)
      F. Tochikubo
    • Organizer
      33th International Conference on Phenomena in Ionized Gases
    • Place of Presentation
      リスボン(ポルトガル)
    • Year and Date
      2017-07-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 液体電極を有する大気圧直流グロー放電によって誘起される電解反応を用いたマグネタイトナノ粒子合成における液中反応経路の検討2017

    • Author(s)
      山﨑裕也,内田諭,杤久保文嘉
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Investigation of chemical reaction process on magnetite nanoparticles synthesis by atmospheric-pressure DC glow discharge electrolysis2017

    • Author(s)
      山﨑裕也,内田諭,杤久保文嘉
    • Organizer
      第34回プラズマプロセシング研究会(SPP34)/ 第29回プラズマ材料科学シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2017-01-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Discussion on physics and chemistry of plasma-liquid Interface predicted from numerical simulation2017

    • Author(s)
      杤久保文嘉
    • Organizer
      第34回プラズマプロセシング研究会(SPP34)/ 第29回プラズマ材料科学シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2017-01-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Numerical simulation of atmospheric-pressure glow discharge electrolysis2017

    • Author(s)
      F. Tochikubo, S. Uchida
    • Organizer
      5th East Asia Joint Symposium on Plasma and Electrostatic Technologies for Environmental Application
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Simulation of glow discharge electrolysis for material processing in liquid2017

    • Author(s)
      F. Tochikubo
    • Organizer
      The XXXIII International Conference on Phenomena in Ionized Gases
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Attempt of liquid-phase material processing using atmospheric-pressure glow discharge electrolysis2017

    • Author(s)
      F. Tochikubo, Y. Yamazaki, T. Hanawa, N. Kitakaze, N. Shirai, S. Uchida
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液中での銀ナノ粒子生成における大気圧グロー放電電解のシミュレーション2017

    • Author(s)
      杤久保文嘉,内田諭
    • Organizer
      Plasma Conference 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気圧グロー放電による液中での金属ナノ粒子生成とその機能化2017

    • Author(s)
      北風直志,白井直機,中川雄介,内田諭,杤久保文嘉
    • Organizer
      Plasma Conference 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Simulation of mist-containing low-temperature plasma in atmospheric-pressure helium2017

    • Author(s)
      F. Tochikubo, F. Murayama, S. Uchida
    • Organizer
      70th Annual Gaseous Electronics Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気圧直流グロー放電電解を用いた磁性ナノ粒子合成における反応機構の検討2016

    • Author(s)
      山﨑裕也,白井直機,内田諭,杤久保文嘉
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜情報文化センター
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Liquid-phase reaction during magnetite nanoparticles synthesis using plasma-induced electrolysis2016

    • Author(s)
      F. Tochikubo
    • Organizer
      2016 MRS Fall Meeting
    • Place of Presentation
      ボストン(米国)
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 液体と接する大気圧プラズマのシミュレーション2016

    • Author(s)
      杤久保文嘉
    • Organizer
      第32回九州・山口プラズマ研究会
    • Place of Presentation
      佐賀大学
    • Year and Date
      2016-11-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 液体電極放電を用いた磁性ナノ粒子合成における液中反応経路 の検討2016

    • Author(s)
      山崎裕也, 白井直機, 内田諭, 杤久保文嘉
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 溶存酸素を考慮したグロー放電電解のシミュレーション2016

    • Author(s)
      杤久保文嘉, 内田諭
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Numerical simulation of atmospheric-pressure glow discharge electrolysis2016

    • Author(s)
      F. Tochikubo, N. Shirai, S. Uchida
    • Organizer
      13th Asia-Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      上海(中国)
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of dissolved oxygen on magnetic-nanoparticles synthesis by atmospheric-pressure plasma in contact with liquid2016

    • Author(s)
      Y. Yamazaki, N. Shirai, S. Uchida, F. Tochikubo
    • Organizer
      13th Asia-Pacific Conference on Plasma Science and Technology
    • Place of Presentation
      上海(中国)
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of dissolved oxygen on magnetic-nanoparticles synthesis by atmospheric-pressure plasma in contact with liquid2016

    • Author(s)
      Y. Yamazaki, N. Shira, S. Uchida, F. Tochikubo
    • Organizer
      Asia-Pacific Conference on Plasma Science and Technology 2016
    • Place of Presentation
      上海(中国)
    • Year and Date
      2016-05-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Numerical simulation of atmospheric-pressure glow discharge electrolysis2016

    • Author(s)
      F. Tochikubo, N. Shirai, F. Tochikubo
    • Organizer
      Asia-Pacific Conference on Plasma Science and Technology 2016
    • Place of Presentation
      上海(中国)
    • Year and Date
      2016-05-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 液体電極を用いた大気圧グロー放電による金ナノ粒子合成と放電条件との相関2016

    • Author(s)
      二戸愛仁,白井直機, 内田諭,杤久保文嘉
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大気圧He/H2O直流グロー放電における負イオン生成の影響2016

    • Author(s)
      岡村航太,白井直機, 内田諭,杤久保文嘉
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] プラズマ支援電解を用いた磁性ナノ粒子合成における溶存酸素の影響2016

    • Author(s)
      山崎裕也,白井直機,内田諭,杤久保文嘉
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Functional Nanoparticles by Plasma-Assisted Electrolysis using Atmospheric DC Glow Discharge in Contact with Liquid2015

    • Author(s)
      N. Shirai, A. Nito, Y. Yamazaki, S. Uchida, F. Tochikubo
    • Organizer
      9th Asia-Pacific International Symposium on the Basics and Applications of Plasma Technology / 28th Symposium of Plasma Science for Materials
    • Place of Presentation
      長崎大学(長崎県長崎市)
    • Year and Date
      2015-12-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気圧プラズマ電気分解による複合金属ナノ粒子の合成2015

    • Author(s)
      白井直機、二戸愛仁、内田諭、杤久保文嘉
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜情報文化センター(神奈川県横浜市)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optical Emission Spectroscopy of Atmospheric-pressure DC Glow Discharge along Helium Flow in Air with Liquid Electrode2015

    • Author(s)
      R. Aoki, N. Shirai, S. Uchida, F. Tochikubo
    • Organizer
      2015 Korea-Japan Joint Symposium on Electrical Discharge and High Voltage Engineering
    • Place of Presentation
      モクポ(韓国)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-dimensional Simulation of Atmospheric-pressure Glow Discharge electrolysis2015

    • Author(s)
      F. Tochikubo, N. Shirai, S. Uchida
    • Organizer
      2015 Korea-Japan Joint Symposium on Electrical Discharge and High Voltage Engineering
    • Place of Presentation
      モクポ(韓国)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 液体を電極とする大気圧グロー放電のシミュレーション -水蒸気の影響-2015

    • Author(s)
      杤久保文嘉, 岡村航太, 白井直機, 内田諭
    • Organizer
      電気学会プラズマ/パルスパワー/放電合同研究会
    • Place of Presentation
      KITENビル(宮崎県宮崎市)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Characteristics of Liquid Flow Induced by Atmospheric Pressure DC Glow Discharge with Liquid Electrode2015

    • Author(s)
      F. Tochikubo, T. Aoki, N. Shirai, S. Uchida
    • Organizer
      8th Annual Gaseous Electronics Conference/9th International Conference on Reactive Plasmas/33rd Symposium on Plasma Processing
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2015-10-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Attempt to control chemical reactions in liquid induced by atmospheric-pressure DC glow discharge2015

    • Author(s)
      A. Nito, N. Shirai, S. Uchida, F. Tochikubo
    • Organizer
      8th Annual Gaseous Electronics Conference/9th International Conference on Reactive Plasmas/33rd Symposium on Plasma Processing
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2015-10-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of magnetic nanoparticles by atmospheric-pressure plasma electrolysis and observation of liquid flow induced by plasma2015

    • Author(s)
      N. Shirai, T. Yoshida, T. Aoki, S. Uchida, F. Tochikubo
    • Organizer
      8th Annual Gaseous Electronics Conference/9th International Conference on Reactive Plasmas/33rd Symposium on Plasma Processing
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2015-10-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plasma-Induced Electrochemical Reaction and Its Application for Magnetite Nanoparticle Generation2015

    • Author(s)
      F. Tochikubo
    • Organizer
      10th Asian-European International Conference on Plasma Surface Engineering (AEPSE2015)
    • Place of Presentation
      チェジュ(韓国)
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 液体と接する大気圧直流グロー放電によって誘起される液中の流動特性2015

    • Author(s)
      杤久保文嘉、青木拓也、白井直機、内田諭
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Attempt of Controlling Chemical Reactions by Ion-Exchange Membrane in Plasma-Assisted Electrolysis Using Atmospheric-Pressure DC Glow Discharge with Liquid Electrode2015

    • Author(s)
      A. Nito, N. Shirai, S. Uchida, F. Tochikubo
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大気圧He直流グロー放電における微量水蒸気の影響評価2015

    • Author(s)
      岡村航太、白井直機、内田諭、杤久保文嘉
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大気圧プラズマによって誘起される電解反応による磁性ナノ粒子合成の制御2015

    • Author(s)
      白井直機、吉田健人、内田諭、杤久保文嘉
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Remarks] 首都大学東京 プラズマ応用研究室

    • URL

      http://www.comp.tmu.ac.jp/gdpal/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 首都大学東京 理工学研究科 プラズマ応用研究室

    • URL

      http://www.comp.tmu.ac.jp/gdpal/

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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