Analysis with microspectroscopy for reaction engineering of micro catalysis

• Project/Area Number: 15H04178
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Reaction engineering/Process system
• Research Institution: Nagoya University
• Principal Investigator: Tagawa Tomohiko 名古屋大学, 工学研究科, 名誉教授 (10171571)
• Co-Investigator(Kenkyū-buntansha): 山田 博史 名古屋大学, 工学研究科, 助教 (70293644)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2015: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
• Keywords: 反応工学 / マイクロリアクタ / 触媒工学 / 顕微分光法 / 顕微ラマン分光 / 液多相反応 / 相間移動触媒 / 顕微分光分析 / 触媒反応 / 反応解析 / ラマン分光 / 個体触媒反応 / ラマン分光分析 / 固体触媒反応

Outline of Final Research Achievements

Using Pt catakyst supported on silicon microchannel wall, in situ analysis of gas phse catalytic reactions were conducted with micro spectroscopy. In addition to micro infradred spectroscopy and micro ultraviolet spectroscopy, allycation of micro-Raman spectroscopy was successfully conducted. With the aid of micro-Raman spectroscopy, details of carbon depositon was discussed. As for liquid phase multiphse reaction system, reaction was analyzed under microscopy observation. Formation and role of 3rd phase of phase transfer catalysts was discussed.

Research Products

• [Int'l Joint Research] チュラロンコン大学/シルパコン大学(タイ)
• [Int'l Joint Research] チュラロンコン大学/シルパコン大学(タイ)
• [Int'l Joint Research] チュラロンコン大学(タイ)
• [Journal Article] Epoxidation of methyl oleate in a TiO2 coated-wall capillary microreactor (2017)
  • Author(s): Songphon Phimsen, Hiroshi Yamada, Tomohiko Tagawa, Worapon Kiatkittipong, Kunlanan Kiatkitipong, Navadol Laosiripojana, Suttichai Assabumrungrat
  • Journal Title: Chemical Engineering Journal Volume: 314 Pages: 594-599
• [Journal Article] Phenol Transfer trough Thiird Phase for Phenyl Benzoate Formation (2016)
  • Author(s): H. Yamada, T. Sengoku, T. Tagawa
  • Journal Title: Journa; of Japan Petrolueum INｓｔ。 Volume: 59 Pages: 204-210
  • Peer Reviewed / Open Access
• [Journal Article] Ultraviolet-Visible (UV-Vis) microspectroscopic system designed for the in situ characterization of the dehydrogenation reaction over platinum (Pt) supported catalytic microchannel reactor (2016)
  • Author(s): Emee Grace Tabares Suarnaba, Yi Fuan Lee, Hiroshi Yamada、 Tomohiko Tagawa
  • Journal Title: Applied Spectroscopy Volume: 70 Pages: 1-5
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Comparison between parallel and checked arrangement of micro reformer for H2 production from methane (2015)
  • Author(s): T.Jiwanuruk, S. Putivisutisak, p. Ponpesh, C. Kositanont, T. tagawa, H. Yamada, C. Fukuhara, S. Assabumrungrat
  • Journal Title: Chemical Engineering Journal Volume: 268 Pages: 135-143
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Presentation] シリコンマイクロrチャンネル壁面に担持した白金触媒の顕微紫外分光を用いたin-situキャラクタリゼーション (2017)
  • Author(s): 浅井優作、 山田博史、田川智彦
  • Organizer: 化学工学会年会
  • Place of Presentation: 東京
  • Year and Date: 2017-03-06
• [Presentation] The Effect of Catalyst Phase on Phenyl Benzoate Production in the Three Liquid Phases Micro Reactor (2017)
  • Author(s): Hiroshi Yamada, Tetsuhiro Nukushina, Tomohiko Tagawa
  • Organizer: CAMURE-10 and ISMR-9,
  • Int'l Joint Research
• [Presentation] マイクロチャンネル壁面に担持した触媒の顕微赤外分光法を用いたキャラクタリゼーション (2015)
  • Author(s): 林、山田、田川
  • Organizer: 石油学会 第４５回石油・石油化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2015-11-05
• [Presentation] マイクロチャンネル壁面に担持した触媒の顕微紫外分光法を用いたキャラクタリゼーション (2015)
  • Author(s): 浅井、山田、田川
  • Organizer: 石油学会 第４５回石油・石油化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2015-11-05
• [Presentation] マイクロリアクタ-を用いた安息香酸フェニル生成反応における流動状態の与える影響 (2015)
  • Author(s): 温品、山田、田川
  • Organizer: 石油学会 第４５回石油・石油化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2015-11-05
• [Presentation] In situ monitoring of the dehydrogenaton reaction at differnt temperature using UV-Vis microspectroscopy (2015)
  • Author(s): Tagawa, Yamada, Suarnaba
  • Organizer: 化学工学会 第47秋季大会
  • Place of Presentation: 札幌
  • Year and Date: 2015-09-09
• [Book] 最新 プロセス強化の技術 (2017)
  • Author(s): 田川智彦
  • Total Pages: 235
  • Publisher: 三恵社
  • ISBN: 9784864877763