Development of hydrogenation and dehydrogenation catalysts using electride with hydrogen storage ability
| Project/Area Number |
15H04183
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Kitano Masaaki 東京工業大学, 元素戦略研究センター, 准教授 (50470117)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
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| Keywords | エレクトライド / 水素化物 / 選択水素化 / アンモニア合成 / ルテニウム / 触媒・化学プロセス / 水素化 |
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| Outline of Final Research Achievements |
In the present study, we have focused on the hydrogenation or dehydrogenation reactions over electride (or hydride) supported metal nanoparticle catalysts. And the relationship between the catalytic activity and the hydrogen storage ability was investigated. C12A7 supported Ru-Fe bimetallic catalyst exhibited high activity for selective hydrogenation of unsaturated aldehydes. Ca2NH and Ca(NH2)2 supported Ru catalysts showed excellent activity for low-temperature ammonia synthesis.
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Report
(4 results)
Research Products
(60 results)
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[Journal Article] Efficient and Stable Ammonia Synthesis by Self-Organized Flat Ru Nanoparticles on Calcium Amide2016
Author(s)
Yasunori Inoue, Masaaki Kitano, Kazuhisa Kishida, Hitoshi Abe, Yasuhiro Niwa, Masato Sasase, Yusuke Fujita, Hiroki Ishikawa, Toshiharu Yokoyama, Michikazu Hara, Hideo Hosono
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Journal Title
ACS Catalysis
Volume: 6
Issue: 11
Pages: 7577-7584
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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