experimental test on dynamics of telecheric polymers

• Project/Area Number: 15K05519
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Kyoto University
• Principal Investigator: Matsumiya Yumi 京都大学, 化学研究所, 准教授 (00378853)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: 会合性高分子 / テレケリック高分子 / 粘弾性 / 誘電緩和 / 粘弾性緩和 / 化学平衡 / 高分子ダイナミクス / Rouse 緩和 / Rouse緩和

Outline of Final Research Achievements

For the model associative polymers undergoing head-to-head association, dynamics of the polymer chain combined with association/dissociation reaction were theoretically analyzed. The reaction activates mutual conformational transfer between the unimer and dimer. Coupling occurs for the anisotropy decay modes of the unimer and dimer due to this transfer, and the viscoelastic relaxation of the unimer and dimer, exhibit retarded and accelerated relaxation compared to those without reaction. In contrast, the memory decay modes of the unimer and dimer are only pair-wisely coupled, so that the reaction-induced accerelation and retardation for the dielectric relaxation of unimer and dimer are much weaker than those seen for the viscoelastic relaxation. This theoretical prediction is experimentally confirmed.

Research Products

• [Int'l Joint Research] Sungkyunkwan University(韓国)
• [Journal Article] Dynamics of Rouse chains undergoing head-to-head association and dissociation: Difference between dielectric and viscoelastic relaxation (2017)
  • Author(s): Hiroshi Watanabe, Yumi Matsumiya, and Youngdon Kwon
  • Journal Title: Journal of Rheology Volume: 61 Issue: 6 Pages: 1151-1170
  • DOI: 10.1122/1.4997579
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Revisit the Elongational Viscosity of FENE Dumbbell Model (2017)
  • Author(s): Hiroshi Watanabe and Yumi Matsumiya
  • Journal Title: Nihon Reoroji Gakkaishi Volume: 45 Issue: 4 Pages: 185-190
  • DOI: 10.1678/rheology.45.185
  • NAID: 130006107445
  • ISSN: 0387-1533, 2186-4586
  • Peer Reviewed
• [Journal Article] Rheology of Nano-Cellulose Fiber Suspension (2016)
  • Author(s): Yumi Matsumiya, Hiroshi Watanabe, Kentaro Abe, Yasuki Matsumura, Fumito Tani, Yasuo Kase, Shojiro Kikkawa, Yasushi Suzuki, and Nanase Ishii
  • Journal Title: Nihon Reoroji Gakkaishi Volume: 45 Issue: 1 Pages: 3-11
  • DOI: 10.1678/rheology.45.3
  • NAID: 130005440010
  • ISSN: 0387-1533, 2186-4586
  • Peer Reviewed
• [Journal Article] Experimental Test for Viscoelastic Relaxation of Polyisoprene Undergoing Monofunctional Head-to-Head Association and Dissociation (2016)
  • Author(s): Y. Matsumiya, H. Watanabe, O. Urakawa and T. Inoue
  • Journal Title: Macromolecules Volume: 49 Issue: 18 Pages: 7088-7095
  • DOI: 10.1021/acs.macromol.6b01313
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Nonlinear Stress Relaxation of Miscible Polyisoprene/Poly(p-tert-butylstyrene) Blends in Pseudomonodisperse State (2016)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Journal Title: Macromolecules Volume: 49 Issue: 12 Pages: 4544-4556
  • DOI: 10.1021/acs.macromol.6b00910
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Viscoelastic and Orientational Relaxation of Linear and Ring Rouse Chains Undergoing Reversible End-Association and Dissociation (2016)
  • Author(s): Y. Kwon, Y. Matsumiya, and H. Watanabe
  • Journal Title: Macromolecules Volume: 49 Issue: 9 Pages: 3593-3607
  • DOI: 10.1021/acs.macromol.6b00424
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Dielectric Relaxation and Ionic Conductivity of a Chitosan/Poly(ethylene oxide) Blend Doped with Potassium and Calcium Cations (2016)
  • Author(s): N. Rakkapao, H. Watanabe, Y. Matsumiya, and Y. Masubuchi
  • Journal Title: Nihon Reoroji Gakkaishi Volume: 44 Issue: 2 Pages: 89-97
  • DOI: 10.1678/rheology.44.89
  • NAID: 130005152410
  • ISSN: 0387-1533, 2186-4586
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Dielectric Relaxation and Ionic Conductivity of a Chitosan/Poly(ethylene oxide) Blend Doped with Potassium and Calcium Cations (2016)
  • Author(s): Rakkapao, N.; Watanabe, H. ; Matsumiya, Y.; Masubuchi, Y.
  • Journal Title: J. Soc. Rheol. Jpn Volume: 44 Pages: 87-95
  • NAID: 130005152410
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Entanglement Length in Miscible Blends of cis-Polyisoprene and Poly(p-tert-butylstyrene) (2015)
  • Author(s): Matsumiya, Y.; Rakkapao, N.; Watanabe, H.
  • Journal Title: Macromolecules Volume: 48 Issue: 21 Pages: 7889-7908
  • DOI: 10.1021/acs.macromol.5b01866
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Revisit the Stress-Optical Rule for Entangled Flexible Chains: Overshoot of Stress, Segmental Orientation, and Chain Stretch on Start-up of Flow (2015)
  • Author(s): Watanabe, H.; Matsumiya, Y.; Inoue, T.
  • Journal Title: Nihon Reoroji Gakkaishi Volume: 43 Issue: 3_4 Pages: 105-112
  • DOI: 10.1678/rheology.43.105
  • NAID: 130005097260
  • ISSN: 0387-1533, 2186-4586
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Viscoelastic Relaxation of Rouse Chains undergoing Head-to-Head Association and Dissociation: Motional Coupling through Chemical Equilibrium (2015)
  • Author(s): Watanabe, H.; Matsumiya, Y.; Masubuchi, Y.; Urakawa, O.; Inoue, T.
  • Journal Title: Macromolecules Volume: 48 Issue: 9 Pages: 3014-3030
  • DOI: 10.1021/acs.macromol.5b00409
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] 誘電緩和法による高分子ダイナミクスの研究 (2018)
  • Author(s): 松宮由実
  • Organizer: 関西接着ワークショップ2017年度第4回研究会
  • Invited
• [Presentation] Nonlinear stress relaxation of miscible polyisoprene/poly(p-tert-butyl styrene) blends in pseudo-monodisperse state (2017)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Organizer: The Society of Rheology 88th Annual Meeting
  • Place of Presentation: Tampa (USA)
  • Year and Date: 2017-02-14
  • Int'l Joint Research
• [Presentation] 高分子のレオロジーとダイナミクス (2017)
  • Author(s): 松宮由実
  • Organizer: 第269回分子工学コロキウム
  • Place of Presentation: 京都大学 (京都府・京都市）
  • Year and Date: 2017-01-13
  • Invited
• [Presentation] 非絡み合い高分子溶融体の一軸伸張粘度 (2017)
  • Author(s): 松宮由実，渡辺 宏
  • Organizer: 第 65 回レオロジー討論会
• [Presentation] Extensional Viscosity of Unentangled Polymer Melts (2017)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Organizer: The Society of Rheology 89th Annual Meeting
  • Int'l Joint Research
• [Presentation] Extensional Viscosity of Unentangled Polymer Melts (2017)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Organizer: 11th Annual European Rheology Conference
  • Int'l Joint Research
• [Presentation] Entanglement Length in Miscible Blends of cis- Polyisoprene and Poly(p- tert-butylstyrene) (2016)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Organizer: 17th International Congress on Rheology (ICR2016)
  • Place of Presentation: 京都テルサ (京都府・京都市）
  • Year and Date: 2016-08-13
  • Int'l Joint Research
• [Presentation] Extensional Behavior of (SIS)p-type Multiblock Copolymer Systems (2016)
  • Author(s): Yumi Matsumiya
  • Organizer: Institute for Chemical Research International Symposium 2016 (ICRIS'16) - Research Network Based on ICR MOU -
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2016-03-08
  • Int'l Joint Research / Invited
• [Presentation] 会合性高分子のダイナミクス (2015)
  • Author(s): 松宮由実
  • Organizer: 第115回 化学研究所 研究発表会
  • Place of Presentation: 京都大学化学研究所
  • Year and Date: 2015-12-11
• [Presentation] Viscoelastic relaxation of Rouse chains undergoing head-to-head association and dissociation. 2. Experimental test (2015)
  • Author(s): Yumi Matsumiya and Hiroshi Watanabe
  • Organizer: The Society of Rheology 87th Annual Meeting
  • Place of Presentation: Baltimore, MD, USA
  • Year and Date: 2015-10-12
  • Int'l Joint Research
• [Presentation] Viscoelastic Relaxation of Rouse Chains undergoing Head-to-Head Association and Dissociation (2015)
  • Author(s): Yumi Matsumiya and Hiroshi Watanabe
  • Organizer: International Symposium on Rheology
  • Place of Presentation: 神戸大学
  • Year and Date: 2015-09-23
  • Int'l Joint Research
• [Presentation] Viscoelastic relaxation of Rouse chains undergoing head‐to‐head association and dissociation: motional coupling through chemical equilibrium (2015)
  • Author(s): Y. Matsumiya and H. Watanabe
  • Organizer: 10th Annual European Rheology Conference
  • Place of Presentation: Nantes, France
  • Year and Date: 2015-04-16
  • Int'l Joint Research