Development of Formation Process for Metal-Organic Framework Crystals on Metal-Ion Doped Polymer Substrate

• Project/Area Number: 15K05655
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Konan University
• Principal Investigator: TSURUOKA Takaaki 甲南大学, フロンティアサイエンス学部, 講師 (20550239)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000); Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
• Keywords: 金属有機構造体 / 界面反応 / 自己組織化 / 配位結合

Outline of Final Research Achievements

We develop a general methodology for the construction of continuous MOF crystals with fine-tuned thickness through an interfacial reaction by using an ion-doped polymer substrate. This approach involves the adsorption of metal ions onto the polymer substrate through an ion-exchange reaction and selective growth of MOF crystals at the interface between the polymer surface and reaction solution containing only MOF ligands. Selective formation of MOF crystals with high crystallinity on the polymer substrate can be achieved by a kinetically control of formation of frameworks because the elution of adsorbed metal ions. This interfacial approach allows us to readily control the thickness of MOF crystals by tuning the number of adsorbed metal ions, and can also be used to fabricate various types of MOF crystals by adsorbing various species of metal ions.

Research Products

• [Journal Article] Controlling the Orientation of Metal－Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate (2018)
  • Author(s): Takashi Ohhashi, Takaaki Tsuruoka, Seiya Fujimoto, Yohei Takashima, and Kensuke Akamatsu
  • Journal Title: Cryst. Growth Des. Volume: 18 Issue: 1 Pages: 402-408
  • DOI: 10.1021/acs.cgd.7b01402
  • Peer Reviewed
• [Journal Article] Crystal conversion between metal-organic frameworks with different crystal topologies for efficient crystal design on two-dimensional substrates (2018)
  • Author(s): Takaaki Tsuruoka, Kohei Inoue, Ayumi Miyanaga, Kaho Tobiishi, Takashi Ohhashi, Manami Hata, Yohei Takashima, Kensuke Akamatsu
  • Journal Title: J. Cryst. Growth Volume: 487 Pages: 1-7
  • DOI: 10.1016/j.jcrysgro.2018.02.007
  • Peer Reviewed
• [Journal Article] Rational composition control of mixed-lanthanide metal-organic frameworks by an interfacial reaction with metal ion-doped polymer substrates (2017)
  • Author(s): Takaaki Tsuruoka, Ayumi Miyanaga, Takashi Ohhashi, Manami Hata, Yohei Takashima, Kensuke Akamatsu
  • Journal Title: J. Solid State Chem. Volume: 253 Pages: 43-46
  • DOI: 10.1016/j.jssc.2017.05.025
  • Peer Reviewed
• [Journal Article] An Integrated Function System Using Metal Nanoparticle@Mesoporous Silica@Metal-Organic Framework Hybrids (2017)
  • Author(s): Takashi Ohhashi, Takaaki Tsuruoka, Kohei Inoue, Yohei Takashima, Kensuke Akamatsu
  • Journal Title: Microporous and Mesoporous Materials Volume: 245 Pages: 104-108
  • DOI: 10.1016/j.micromeso.2017.02.074
  • Peer Reviewed
• [Journal Article] Morphology Control of Metal－Organic Frameworks Based on Paddle-Wheel Units on Ion-Doped Polymer Substrate Using an Interfacial Growth Approach (2016)
  • Author(s): T. Tsuruoka, K. Mantani, A. Miyanaga, T. Matsuyama, T. Ohhashi, T. Takashima, K. Akamatsu
  • Journal Title: Langmuir Volume: 32 Issue: 24 Pages: 6068-6073
  • DOI: 10.1021/acs.langmuir.6b01687
  • Peer Reviewed
• [Journal Article] Site-selective growth of metal-organic frameworks using an interfacial growth approach combined with VUV photolithography (2016)
  • Author(s): T. Tsuruoka, T. Matsuyama, A. Miyanaga, T. Ohhashi, T. Takashima, K. Akamatsu
  • Journal Title: RSC Advances Volume: 6 Issue: 81 Pages: 77297-77300
  • DOI: 10.1039/c6ra18340a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate (2016)
  • Author(s): Takaaki Tsuruoka, Misato Kumano, Koji Mantani, Tetsuhiro Matsuyama, Ayumi Miyanaga, Takashi Ohhashi, Yohei Takashima, Hideto Minami, Toyoko Suzuki, Kaori Imagawa, Kensuke Akamatsu
  • Journal Title: Crystal Growth & Design Volume: 16 Issue: 5 Pages: 2472-2476
  • DOI: 10.1021/acs.cgd.6b00007
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] 二次元基板上での金属有機構造体の結晶交換 (2018)
  • Author(s): 鶴岡孝章、井上康平、大橋卓史、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第98春季年会
• [Presentation] 金属イオン吸着高分子表面上での多孔性金属錯体の結晶成長制御 (2018)
  • Author(s): 畠茉奈美、大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第98春季年会
• [Presentation] Controlling the Orientation of Metal-Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate (2018)
  • Author(s): Takashi Ohhashi, Takaaki Tsuruoka, Seiya Fujimoto, Yohei Takashima, Kensuke Akamatsu
  • Organizer: 日本化学会第98春季年会
• [Presentation] 固液界面反応による蛍光性金属有機構造体の作製 (2017)
  • Author(s): 鶴岡孝章、宮永あゆみ、大橋卓史、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応大学（神奈川県・横浜市）
  • Year and Date: 2017-03-16
• [Presentation] 固液界面での配位高分子形成メカニズムの解明 (2017)
  • Author(s): 大橋卓史、鶴岡孝章、藤本聖也、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応大学（神奈川県・横浜市）
  • Year and Date: 2017-03-16
• [Presentation] 金属ナノ粒子＠メソポーラスシリカ＠多孔性金属錯体3層構造体の作製 (2017)
  • Author(s): 大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第68回コロイドおよび界面化学討論会
• [Presentation] 金属イオンドープ高分子膜上でのMOF成長プロセスの開発 (2017)
  • Author(s): 畠茉奈美、鶴岡孝章、大橋卓史、髙嶋洋平、赤松謙祐
  • Organizer: 第68回コロイドおよび界面化学討論会
• [Presentation] Orientational Contorol of Metal-Organic Frameworks Using an Interfacial Growth Approach on a Metal Ions-Doped Polymer Substrate (2017)
  • Author(s): 大橋卓史、鶴岡孝章、藤本聖也、髙嶋洋平、赤松謙祐
  • Organizer: 錯体化学会第67回討論会
• [Presentation] 金属イオンドープ高分子フィルム上での多孔性金属有機構造体の作製および形態制御 (2017)
  • Author(s): 鶴岡孝章、萬谷浩司、大橋卓史、髙嶋洋平、赤松謙祐
  • Organizer: 錯体化学会第67回討論会
• [Presentation] Morphology Control of Metal-Organic Frameworks by and Interfacial Synthetic Approach using Metal Ion-Doped Polymer Substrates (2017)
  • Author(s): Takaaki Tsuruoka, Takashi Ohhashi, Yohei Takashima, Kensuke Akamatsu
  • Organizer: The 4th International Symposium on Hybrid Materials and Processing（HyMaP 2017）
  • Int'l Joint Research
• [Presentation] Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-doped Polymer Substrate (2017)
  • Author(s): Takashi Ohhashi, Takaaki Tsuruoka, Yohei Takashima, Kensuke Akamatsu
  • Organizer: The 4th International Symposium on Hybrid Materials and Processing（HyMaP 2017）
  • Int'l Joint Research
• [Presentation] 高分子フィルム上での相互嵌入型MOFの合成 (2017)
  • Author(s): 濵上留帆、大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第19回関西表面技術フォーラム
• [Presentation] 結晶変換による金属有機構造体の形態デザイン (2017)
  • Author(s): 井上康平、大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第19回関西表面技術フォーラム
• [Presentation] 二次元基板上での金属有機構造体の配向制御 (2017)
  • Author(s): 藤本聖也、大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第19回関西表面技術フォーラム
• [Presentation] 固液界面における蛍光性金属有機構造体の作製 (2016)
  • Author(s): 宮永あゆみ、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第18回関西表面技術フォーラム
  • Place of Presentation: 甲南大学（兵庫県・神戸市）
  • Year and Date: 2016-11-17
• [Presentation] Interfacial Synthetic Approach for Constructing Metal-Organic Framework Crystals Using Metal Ion-Doped Polymer Substrate (2016)
  • Author(s): Takaaki Tsuruoka, Misato Kumano, Koji Mantani, Takashi Ohhashi, Yohei Takashima, Kensuke Akamatsu
  • Organizer: 錯体化学会第66回討論会
  • Place of Presentation: 福岡大学（福岡県・福岡市）
  • Year and Date: 2016-09-10
• [Presentation] Selective Growth of Metal-Organic Frameworks on Metal Nanoparticles for Constructing Hybrid Nanostructures (2016)
  • Author(s): Takaaki Tsuruoka
  • Organizer: EMN Meeting on Nanparticles
  • Place of Presentation: Peninsula Excelsior Hotel, Singapore
  • Year and Date: 2016-05-09
  • Int'l Joint Research / Invited
• [Presentation] Synthesis of Hierarchically Metal Nanoparticle/Mesoporous Silica/Metal-Organic Frameworks Nanostructures (2016)
  • Author(s): Takashi Ohhashi, Takaaki Tsuruoka, Yohei Takashima, Kensuke Akamatsu
  • Organizer: EMN Meeting on Nanparticles
  • Place of Presentation: Peninsula Excelsior Hotel, Singapore
  • Year and Date: 2016-05-09
  • Int'l Joint Research
• [Presentation] Selective Growth of Metal-Organic Frameworks on Metal Nanoparticles for Constructing Hybrid Nanostructures (2016)
  • Author(s): Takaaki Tsuruoka
  • Organizer: EMN Meeting on Nanoparticles
  • Place of Presentation: PENINSULA EXCELSIOR Hotel, Sigapore
  • Year and Date: 2016-05-09
  • Int'l Joint Research / Invited
• [Presentation] 階層的に機能化された機能性無機ナノ結晶/多孔性有機金属錯体複合材料の創製 (2016)
  • Author(s): 大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府・京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 固液界面における多孔性金属有機構造体の作製および形態制御 (2016)
  • Author(s): 鶴岡孝章、萬谷浩司、松山哲大、宮永あゆみ、山田陸登、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府・京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 金属イオンドープ高分子上での部位選択的MOF薄膜の作製 (2016)
  • Author(s): 松山哲大、萬谷浩司、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学（京都府・京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] Selective growth of metal-organic frameworks at solid/liquid interfaces (2016)
  • Author(s): Takaaki Tsuruoka
  • Organizer: The 3rd International Symposium for Green-Innovation Polymers (GRIP2016)
  • Place of Presentation: Japan Adavanced Institute of Science and Technology (Ishikawa・Nomi）
  • Year and Date: 2016-03-04
  • Int'l Joint Research / Invited
• [Presentation] 構造制御可能でかつ汎用性に優れた無機ナノ結晶/MOF複合ナノ結晶創製技術の開発 (2015)
  • Author(s): 大橋卓史、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 奈良女子大学（奈良県・奈良市）
  • Year and Date: 2015-09-21
• [Presentation] 金属イオンドープ材料上での優先的多孔性有機金属構造体成長 (2015)
  • Author(s): 鶴岡孝章
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学（宮城県・仙台市）
  • Year and Date: 2015-09-15
  • Invited
• [Presentation] 金属イオンドープ高分子フィルム上での多孔性有機金属構造体薄膜成長 (2015)
  • Author(s): 鶴岡孝章、熊野未里、松山哲大、髙嶋洋平、赤松謙祐
  • Organizer: 第66回コロイドおよび界面化学討論会
  • Place of Presentation: 鹿児島大学（鹿児島県・鹿児島市）
  • Year and Date: 2015-09-10
• [Presentation] 金属イオンドープ高分子フィルム上での部位選択的MOF薄膜の作製 (2015)
  • Author(s): 松山哲大、熊野未里、鶴岡孝章、髙嶋洋平、赤松謙祐
  • Organizer: 第66回コロイドおよび界面化学討論会
  • Place of Presentation: 鹿児島大学（鹿児島県・鹿児島市）
  • Year and Date: 2015-09-10
• [Remarks] 甲南大学フロンティアサイエンス学部・ナノ材料科学研究室
  • URL: http://www.konan-u.ac.jp/hp/FIRST_nanomaterials/