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Low temperature-catalytic reaction over perovskite-type oxide prepared by utilizing solid-solid transformation

Research Project

Project/Area Number 15K06569
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionEhime University

Principal Investigator

YAHIRO Hidenori  愛媛大学, 理工学研究科(工学系), 教授 (90200568)

Co-Investigator(Renkei-kenkyūsha) YAMAGUCHI Syuhei  愛媛大学, 大学院理工学研究科, 准教授 (50397494)
YAMAURA Hiroyuki  愛媛大学, 大学院理工学研究科, 講師 (40314968)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsペロブスカイト型酸化物 / 金属シアノ錯体 / シアノシリル化反応 / 微小粒子状物質 / 部分置換ペロブスカイト型酸化物 / シアノ錯体熱分解法 / シアノシリル化 / 銀担持触媒 / PM燃焼反応 / シアノ錯体 / 熱分解法 / クネーフェナーゲル縮合反応 / 低温焼成 / 流通系焼成装置
Outline of Final Research Achievements

Perovskite-type oxide catalysts prepared by utilizing solid-solid transformation were applied to several heterogeneous catalytic reactions including liquid-solid and solid-solid catalytic reaction. Perovskite-type oxide exhibited the catalytic activity for cyanosilylation and Knoevenagel condensation reactions (Liquid-Solid catalytic system), suggesting the formation of both Bronsted acid and base on surface. It was found that the catalytic activity of the particulate matter (PM) oxidation over Ag-loaded perovskite-type oxide (Solid-Solid catalytic system) was comparable to that over Ag-loaded cerium dioxide which has been well-known to be the best candidate for PM oxidation. In addition, the novel preparation route of partially-substituted perovskite-type oxide was developed.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (46 results)

All 2018 2017 2016 2015 Other

All Journal Article (14 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 12 results,  Open Access: 5 results,  Acknowledgement Compliant: 5 results) Presentation (29 results) (of which Int'l Joint Research: 13 results,  Invited: 5 results) Remarks (3 results)

  • [Journal Article] Oxidation of cyclic hydrocarbons with hydrogen peroxide over iron complexes encapsulated in cation-exchanged zeolite2018

    • Author(s)
      Yamaguchi Syuhei、Miyake Yuki、Takiguchi Keiko、Ihara Daijiro、Yahiro Hidenori
    • Journal Title

      Catalysis Today

      Volume: 303 Pages: 249-255

    • DOI

      10.1016/j.cattod.2017.10.047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-propagating high-temperature synthesis of highly dispersed noble metals on ceria powder: Application to Pd/CeO 2 catalyst2017

    • Author(s)
      Daniel Sanchez-Rodriguez, Syuhei Yamaguchi, Daijiro Ihara, Hiroyuki Yamaura, Hidenori Yahiro
    • Journal Title

      Ceramics International

      Volume: 43 Issue: 16 Pages: 14533-14536

    • DOI

      10.1016/j.ceramint.2017.07.208

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Anode-supported SOFC with thin film of proton-conducting BaCe<sub>0.8</sub>Y<sub>0.2</sub>O<sub>3&minus;&alpha;</sub> by electrophoretic deposition2017

    • Author(s)
      Y. Itagaki, Y. Yamamoto, H. Aono, H. Yahiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 6 Pages: 528-532

    • DOI

      10.2109/jcersj2.17048

    • NAID

      130006899943

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrogen permeation of BaCe<sub>0.80</sub>Y<sub>0.20</sub>O<sub>3&minus;&delta;</sub>&ndash;Gd<sub>0.1</sub>Ce<sub>0.9</sub>O<i><sub>x</sub></i> dual-phase membranes2017

    • Author(s)
      Yoshiteru Itagaki, Akinori Hiraoka, Hiromichi Aono, Hidenori Yahiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 4 Pages: 338-342

    • DOI

      10.2109/jcersj2.16230

    • NAID

      130005530343

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of LaFeO3 perovskite-type oxide via solid-state combustion of a cyano complex precursor: The effect of oxygen diffusion2017

    • Author(s)
      Daniel Sanchez-Rodriguez, Hiroki Wada, Syuhei Yamaguchi, Jordi Farjas, Hidenori Yahiro
    • Journal Title

      Ceramics International

      Volume: 43 Issue: 3 Pages: 3156-3165

    • DOI

      10.1016/j.ceramint.2016.11.134

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Investigation on Reduction Behaviors of SnO2 and SnO2-Supported CuO Sensor Materials by Temperature-Programmed Reduction Method Combined with Resistance Measurement2016

    • Author(s)
      Hiroyuki Yamaura, Shinsuke Hirao, Syuhei Yamaguchi, Hidenori Yahiro
    • Journal Title

      Sensors and Materials

      Volume: 28 Pages: 1203-1210

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cyanosilylation of benzaldehyde with TMSCN over A-site metal substituted perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano complex precursors2016

    • Author(s)
      Syuhei Yamaguchi, Hiroki Wada, Takahisa Okuwa, Hidenori Yahiro
    • Journal Title

      Ceramics Transactions

      Volume: 257 Pages: 81-90

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cyanosilylation of Benzaldehyde with Trimethylsilyl cyanide over Zn-Sn Mixed Oxide Catalysts with Cubic-shaped Particles2016

    • Author(s)
      Syuhei Yamaguchi, Hiroyuki Yamaura, Kenta Morihara, Masataka Iwasaki, Hidenori Yahiro
    • Journal Title

      Chemistry Letters

      Volume: 45 Issue: 8 Pages: 851-853

    • DOI

      10.1246/cl.160320

    • NAID

      130005254584

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 活性炭を利用した水銀処理の開発動向2016

    • Author(s)
      山浦弘之,八尋秀典
    • Journal Title

      ファインケミカル

      Volume: 45(7) Pages: 14-19

    • Related Report
      2016 Research-status Report
  • [Journal Article] Synthesis of perovskite-type oxide, LaFeO<sub>3</sub>, from coordination polymer precursor, La[Fe(CN)<sub>6</sub>]&middot;5H<sub>2</sub>O2016

    • Author(s)
      Syuhei Yamaguchi, Hiroki Wada, Daniel Sanchez-Rodriguez, Jordi Farjas and Hidenori Yahiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 1 Pages: 7-12

    • DOI

      10.2109/jcersj2.15198

    • NAID

      130005117391

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 金属シアノ錯体からのぺロブスカイト型酸化物触媒の合成2016

    • Author(s)
      山口修平,八尋秀典
    • Journal Title

      セラミックス

      Volume: 51 Pages: 12-15

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Self-propagating high-temperature synthesis of LaMO3 perovskite-type oxide using heteronuclear cyano metal complex precursors2015

    • Author(s)
      Daniel Sanchez-Rodriguez, Hiroki Wada, Syuhei Yamaguchi, Jordi Farjas, and Hidenori Yahiro
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 649 Pages: 1291-1299

    • DOI

      10.1016/j.jallcom.2015.07.246

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Impedance study of anodic properties of Ni-Fe impregnated SDC2015

    • Author(s)
      Yoshiteru Itagaki, Tomohisa Takemasa, Syuhei Yamaguchi, Hidenori Yahiro
    • Journal Title

      ECS Trans.

      Volume: 68 Issue: 1 Pages: 1427-1434

    • DOI

      10.1149/06801.1427ecst

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Cyanosilylation of benzaldehyde with TMSCN over perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano complex precursors2015

    • Author(s)
      Syuhei Yamaguchi, Takahisa Okura, Hiroki Wada, Hiroyuki Yamaura, Hidenori Yahiro
    • Journal Title

      Research on Chemical Intermediates

      Volume: 未定巻 Issue: 12 Pages: 9551-9560

    • DOI

      10.1007/s11164-015-1980-y

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ペロブスカイト型酸化物を用いたPM燃焼反応のための銀担持方法の検討2018

    • Author(s)
      山浦弘之、髙橋浩紀、山口修平、八尋秀典
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Property of Ni-SDC Anodes for SOFC with H2 and NH3 Fuels2017

    • Author(s)
      Jian CUI、Naoto ITO、Yoshiteru ITAGAKI、Syuhei YAMAGUCHI、Hidenori YAHIRO
    • Organizer
      16th Korea-Japan Symposium on Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalysis of perovskite-type oxide prepared by the decomposition of heteronuclear cyano complex2017

    • Author(s)
      Hidenori YAHIRO、Syuhei YAMAGUCHI
    • Organizer
      the 12th Pacific Rim Conference on Ceramic and Glass Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] シアノ錯体前駆体から調整した銀担持ペロブスカイト型酸化物触媒のPM酸化反応2017

    • Author(s)
      髙橋浩紀、山浦弘之、西堀麻衣子、山口修平、八尋秀典
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] シアノ錯体熱分解法により調整したペロブスカイト型複合金属酸化物La1-xSrxFeO3を触媒としたシアノシリル化反応2017

    • Author(s)
      福岡諒、山口修平、八尋秀典
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ni担持したBaCe0.8Y0.2O3-δ多孔体のアンモニア分解活性と電気的特性2017

    • Author(s)
      武多瞭、渡邉悠暉、板垣吉晃、青野宏通、八尋秀典
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Improvement of electrochemical performance of SOFC composite electrode formed by EPD2017

    • Author(s)
      Hidenori YAHIRO
    • Organizer
      Composites at Lake Louise 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] PM oxidation of Ag-loaded perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano-complex precursor2017

    • Author(s)
      hiroki TAKAHASHI、Hiroyuki YAMAURA、Makoto FUKUOKA、Syuhei YAMAGUCHI、Hidenori YAHIRO
    • Organizer
      the 8th Japan-China Workshop on Environmental Catalysis and Eco-materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ペロブスカイト型酸化物への Ag 担持が及ぼす PM 酸化活性 への影響2017

    • Author(s)
      髙橋浩紀,山浦弘之,西堀 麻衣子,山口修平,八尋秀典
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京南大沢キャンパス(東京都・八王子市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 立方体型形状を有するスズ‐金属複合酸化物触媒の調製2017

    • Author(s)
      山浦弘之,田島永美里,西堀 麻衣子,山口修平,八尋秀典
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京南大沢キャンパス(東京都・八王子市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Improvement of Electrochemical Performance of Bilayer SOFC2016

    • Author(s)
      Y. Itagaki, H. Yahiro
    • Organizer
      19th Topical Meeting of the International Society of electrochemistry
    • Place of Presentation
      オークランド(ニュージーランド)
    • Year and Date
      2016-04-17
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Self-propagating high-temperature synthesis of LaMO3 perovskite-type oxide using heteronuclear cyano metal complex precursors2016

    • Author(s)
      Daniel Sanchez-Rodriguez, Hiroki Wada, Hiroyuki Yamaura, Syuhei Yamaguchi and Hidenori Yahiro
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Preparation of Mixed Metal Oxide Nanoparticles and Their Catalytic Properties in Liquid Phase2016

    • Author(s)
      Hidenori Yahiro
    • Organizer
      Rare Metal Conference
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-propagating high-temperature synthesis of LaMO3 perovskite-type oxide catalyst using heteronuclear cyano metal complex precursors2016

    • Author(s)
      Daniel Sanchez-Rodriguez, Hiroki Wada, Yuki Hasegawa, Syuhei Yamaguchi, Jordi Farjas, Hidenori Yahiro
    • Organizer
      16th International Congress on Catalysis
    • Place of Presentation
      北京(中国)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anode characteristics of Ni‐loaded SDC prepared by co‐precipitation method2016

    • Author(s)
      Jian Cui, Yoshiteru Itagaki, Syuhei Yamaguchi, Hidenori Yahiro
    • Organizer
      2016 Asian SOFC Symposium
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Ni/(SmO1.5)x(CeO2)1‐x as anode material for direct ammonia fueled SOFC2016

    • Author(s)
      Naoto Ito, Yoshiteru Itagaki, Hiromichi Aono, Hidenori Yahiro
    • Organizer
      2016 Asian SOFC Symposium
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrophoretic deposition of dense BaCe0.8Y0.2O3‐δ electrolyte thin films2016

    • Author(s)
      Yuga Yamamoto, Yoshiteru Itagaki, Hiromichi Aono, Hidenori Yahiro
    • Organizer
      2016 Asian SOFC Symposium
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Durability of Ag/CeO2 and perovskite-type oxides for PM oxidation2016

    • Author(s)
      髙橋浩紀,山浦弘之,山口修平,八尋秀典
    • Organizer
      触媒学会西日本支部第7回触媒科学研究発表会
    • Place of Presentation
      大分大学(大分県・大分市)
    • Related Report
      2016 Research-status Report
  • [Presentation] シアノ錯体熱分解法を用いたシリカ担持ペロブスカイト型酸化物の調製2016

    • Author(s)
      長谷川雄紀,山口修平,八尋秀典
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(広島県・東広島市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Ni-SDCアノード触媒の調製とSOFC特性評価2016

    • Author(s)
      崔健,板垣吉晃,青野宏通,山口修平,八尋秀典
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(広島県・東広島市)
    • Related Report
      2016 Research-status Report
  • [Presentation] シアノ錯体から調製したペロブスカイト型酸化物触媒を用いた液相系酸塩基反応2016

    • Author(s)
      山口修平,和田啓暉,福岡涼,八尋秀典
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県・盛岡市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化物触媒の PM 酸化活性と耐久性の評価2016

    • Author(s)
      髙橋浩紀,山浦弘之,山口修平,八尋秀典
    • Organizer
      2016年日本化学会中国四国支部大会 香川大会
    • Place of Presentation
      香川大学幸町キャンパス(香川県・高松市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Catalytic activity of perovskite-type oxide synthesized by assisting exothermic ligand oxidation of heteronuclear cyano complex2015

    • Author(s)
      Hiroki Wada, Daniel Sanchez-Rodriguez, Takahisa Okuwa, Syuhei Yamaguchi and Hidenori Yahiro
    • Organizer
      International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 複核シアノ錯体前駆体の燃焼熱を利用した低温でのペロブスカイト型酸化物触媒の調製2015

    • Author(s)
      山口修平、和田啓暉、Daniel Sanchez-Rodriguez、八尋秀典
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学(富山県富山市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 複核シアノ錯体前駆の燃焼熱を利用した低温での酸化物触媒の調製2015

    • Author(s)
      Daniel Sanchez-Rodriguez、和田啓暉、山口修平、八尋秀典
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(三重県津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Self-propagating high-temperature synthesis of LaMO3 perovskite-type oxide using heteronuclear cyano metal complex precursors2015

    • Author(s)
      Daniel Sanchez-Rodriguez, Hiroki Wada, Syuhei Yamaguchi, Jordi Farjas and Hidenori Yahiro
    • Organizer
      9th International Conference on f-elements 2015
    • Place of Presentation
      オックスフォード(イギリス)
    • Year and Date
      2015-09-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 複合酸化物触媒の新しい展開2015

    • Author(s)
      八尋秀典
    • Organizer
      第53回触媒研究懇談会
    • Place of Presentation
      ANAクラウンプラザホテル長崎グラバーヒル(長崎県長崎市)
    • Year and Date
      2015-07-23
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Cyanosilylation of benzaldehyde with TMSCN over perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano complex precursors2015

    • Author(s)
      Syuhei Yamaguchi, Takahisa Okuwa, Hiroki Wada and Hidenori Yahiro
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      バンクーバー (カナダ)
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Catalytic Activity for Cyanosilylation over Perovskite-type Oxide Catalyst Calcined from Heteronuclear Cyano Complex Precursor under Several Atmosphere2015

    • Author(s)
      和田啓暉、山口修平、八尋秀典
    • Organizer
      触媒学会西日本支部第6回触媒科学研究発表会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2015-06-12
    • Related Report
      2015 Research-status Report
  • [Remarks] 愛媛大学教育研究者要覧

    • URL

      http://kenqweb.office.ehime-u.ac.jp/yoran/

    • Related Report
      2017 Annual Research Report 2015 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.ach.ehime-u.ac.jp/solid/

    • Related Report
      2017 Annual Research Report 2015 Research-status Report
  • [Remarks] 愛媛大学大学院理工学研究科物質生命工学専攻応用化学コース無機材料化学研究室

    • URL

      http://www.ach.ehime-u.ac.jp/solid/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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