| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Iodine(III) compounds are less toxic and safe oxidants and are known to show reactivities similar to transition metals. However, compared with transition metal complexes, which are frequently used in the cycloaddition reaction for the synthesis of heterocycles, iodine(III) compounds show low reactivities and catalytic abilities. Therefore, new iodine(III) compounds with improved abilities of unsaturated bonds were developed, and then our self-developed metal-free cycloaddition reactions were improved and extended to catalytic methods as well as other cycloaddition reactions.
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