creation of new materials using phenylenes for nanotechnology

• Project/Area Number: 15K13295
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Nanomaterials chemistry
• Research Institution: National Institute of Technology, Toyota College
• Principal Investigator: MIURA Hirokazu 豊田工業高等専門学校, 一般学科, 教授 (40300587)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: フラーレン / アーキメディン / フェニレン / ナノテクノロジー材料 / 環化付加反応 / ステップワイズな合成手法 / [2+2+2]環化付加反応

Outline of Final Research Achievements

Study of cycloaddition reactions has been conducted for several years using model compounds. In the case of [2+2+2]cycloaddition reactions using model compounds required the planar structure, it did not lead to the finding products to form an aromatic ring with a catalyst obtained commercially. Although the step of structural building at once from an open precursor of bond angle in the final step was present In [2+2+2]cycloaddition reaction of other model compounds did not reach to raise sufficient yield. From these results, it can not be reached in the target compound synthesized, it was obtained that a new approach techniques would develop to achieve the target compound synthesis.