| Project/Area Number |
15K13636
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Saitama University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
NAGASE Shigeru 埼玉大学, 大学院理工学研究科, 教授 (30134901)
|
|---|
| Research Collaborator |
OKANO Ippei
TODA Mizuki
|
|---|
| Project Period (FY) |
2015-04-01 – 2017-03-31
|
| Project Status |
Completed (Fiscal Year 2016)
|
| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
|---|
| Keywords | 窒素分子 / 典型元素 / 活性化 / 窒素固定 / 元素戦略 / シリレン / シラシクロペンタジエニリデン / 小分子の活性化 / リチオスタンニレン |
|---|
| Outline of Final Research Achievements |
To activate dinitrogen molecule by main group compounds, an unprecedented main group element-dinitrogen complex should be necessary. In this work, we targeted a lithiostannylene and a silacyclopentadienylidene that were predicted to form stable complexes with dinitrogen molecules. Reduction of Cp*SnCl with lithium did not afford the targeted Cp*SnLi, which was thought to be thermally unstable. We nest chose 3,5-dimesitylphenyl group as a steric protection group succeeded in the synthesis of a dichlorosilole, which is stable under air. The generation of a silacyclopentadienylidene was achieved by the reduction of thus-obtained dichlorosilole with potassium graphite.
|
