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Gated Ferroelectric Ionic Channel

Research Project

Project/Area Number 15K13664
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionTohoku University

Principal Investigator

Akutagawa Tomoyuki  東北大学, 多元物質科学研究所, 教授 (60271631)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsディスコチック液晶 / 水素結合 / 強誘電体 / イオンチャネル / ゲート機構 / 一方向輸送 / 混晶 / クラウンエーテル / アミド基 / 液晶 / カラムナー相 / 相転移 / アルキルアミド / 誘電率
Outline of Final Research Achievements

Artificial gated ionic channel structure was designed by a mixing of ferroelectric discotic columnar liquid crystal and ionic channel one. Both liquid crystalline states can coexist in domain separation, and the inner electric filed according to the ferroelectric hysteresis affected the transport environment of ionic channel. Formation of mixed crystal and ion doping are confirmed in this study, which propose one of the designing strategy for artificial gated ionic channel.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (46 results)

All 2017 2016 2015

All Journal Article (15 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 15 results,  Acknowledgement Compliant: 9 results,  Open Access: 3 results) Presentation (31 results) (of which Int'l Joint Research: 5 results,  Invited: 8 results)

  • [Journal Article] Electronic and Crystal Structures of 1,2,3-Triazole-Fused p-Benzoquinone Derivatives2017

    • Author(s)
      Masahiro Sato, Takashi Takeda, Norihisa Hoshino, Tomoyuki Akutagawa
    • Journal Title

      CrystEngComm

      Volume: 19 Issue: 6 Pages: 910-917

    • DOI

      10.1039/c6ce02167k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anisotropic Dissociation of π-π Stacking and Flipping Motion Induce Crystal Jumping in Alkylacridones and their Dicyanomethylene Derivatives2016

    • Author(s)
      Takashi Takeda, Tomoyuki Akutagawa
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 23 Pages: 7763-7770

    • DOI

      10.1002/chem.201600794

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Successive Phase Transition, Dielectric Ordering, and Liquid Crystalline Behavior of Simple (Laurylammonium)(Phenyl Phosphates) Salts2016

    • Author(s)
      Z. S. Cai, S. Uchikawa, N. Hoshino, T. Takeda, L. M. Zheng, S. Noro, T. Nakamura and T. Akutagawa
    • Journal Title

      J. Phys. Chem. B

      Volume: 120 Issue: 27 Pages: 6761-6770

    • DOI

      10.1021/acs.jpcb.6b02213

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Alkylamide-Substituted Tetraphenylethylene: Three Modes of Fluorescence Based on a Hydrogen-Bonded Excimer2016

    • Author(s)
      Takashi Takeda, Shunsuke Yamamoto, Masaya Mitsuishi, and Tomoyuki Akutagawa
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 14 Issue: 38 Pages: 8922-8926

    • DOI

      10.1039/c6ob01110a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] One-dimensional Supramolecular Columnar Structure of trans-syn-trans-dicyclohexano[18]crown-6 and Organic Ammonium Cations2016

    • Author(s)
      Y. Ohshima, K. Kubo, T. Matsumoto, H. Y. Ye, S. Noro, T. Akutagawa and T. Nakamura
    • Journal Title

      CrystEngComn

      Volume: 18 Issue: 41 Pages: 7959-7964

    • DOI

      10.1039/c6ce00980h

    • NAID

      120005859711

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] The crystal design of polar one-dimensional hydrogen-bonded copper coordination complexes2016

    • Author(s)
      Takahashi, K.; Hoshino, N.; Takeda, T.; Satomi, K.; Suzuki, Y.; Noro, S.; Nakamura, T.; Kawamata, J.; Akutagawa, T.
    • Journal Title

      Dalton Transactions

      Volume: 45 Issue: 8 Pages: 3398-3406

    • DOI

      10.1039/c5dt04865f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conformational Transformations of (C12H25NH3+)(Pyridinesulfonate) in the Solid State2016

    • Author(s)
      Atsushi Funada, Shota Uchikawa, Norihisa Hoshino, Takashi Takeda, and Tomoyuki Akutagawa
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 6 Pages: 915-925

    • DOI

      10.1002/asia.201501442

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystal Structures and Redox Responses Coupled with Ion Recognition of p-Benzoquinone- and Hydroquinone-Fused [18]crown-62015

    • Author(s)
      Takayuki Kobayashi, Yuta Nakane, Takashi Takeda, Norihisa Hoshino, Hidetoshi Kawai, Tomoyuki Akutagawa
    • Journal Title

      Chem. Asian. J.

      Volume: 10 Issue: 2 Pages: 390-396

    • DOI

      10.1002/asia.201403262

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Mesophases and Ionic Conductivities of Simple Organic Salts of M(m-Iodobenzoate) (M = Li+, Na+, K+, Rb+, and Cs+)2015

    • Author(s)
      Manami Endo, Yuta Nakane, Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 119 Issue: 4 Pages: 1768-1777

    • DOI

      10.1021/jp5112026

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Crystal-to-crystal structural transformation of hydrogen-bonding molecular crystals of (imidazolium)(3-hydroxy-2-quinoxalinecarboxylate) through H2O adsorption-desorption2015

    • Author(s)
      Yoshii, Y.; Sakai, K.; Hoshino, N.; Takeda, T.; Noro, S.; Nakamura, T.; Akutagawa, T.
    • Journal Title

      CrystEngComm

      Volume: 17 Issue: 31 Pages: 5962-5969

    • DOI

      10.1039/c4ce02519a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cation-Anion Dual Sensing of a Fluorescent Quinoxalinone Derivative Using Lactam-Lactim Tautomerism2015

    • Author(s)
      Nakane, Y.; Takeda, T.; Hoshino, N.; Sakai, K.; Akutagawa
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 119 Issue: 24 Pages: 6223-6231

    • DOI

      10.1021/acs.jpca.5b02850

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fluorescent Ferroelectrics of Hydrogen-Bonding Pyrene Derivative2015

    • Author(s)
      Hayato Anetai, Yoshifumi Wada, Takashi Takeda, Norihisa Hoshino, Shunsuke Yamamoto, Masaya Mitsuishi, Taishi Takenobu, Tomoyuki Akutagawa
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 6 Issue: 10 Pages: 1813-1818

    • DOI

      10.1021/acs.jpclett.5b00703

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural Flexibilities and Gas Adsorption Properties of One-Dimensional Copper(II) Polymers with Paddle-Wheel Units by Modification of Benzoate Ligands2015

    • Author(s)
      Takahashi, K.; Hoshino, N.; Takeda, T.; Noro, S.; Nakamura, T.; Takeda, S.; Akutagawa, T.
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 19 Pages: 9423-9423

    • DOI

      10.1021/acs.inorgchem.5b01168

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Collective In-Plane Molecular Rotator Based on Dibromoiodomesitylene pi-Stacks2015

    • Author(s)
      Ichikawa, J.; Hoshino, N.; Takeda, T.; Akutagawa, T.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 40 Pages: 13155-13160

    • DOI

      10.1021/jacs.5b08215

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Liquid Crystalline Phase Induced by Molecular Rotator and Dipole Fluctuation2015

    • Author(s)
      Zhang, Q.-C.; Takeda, T.; Hoshino, N.; Noro, S.; Nakamura, T.; Akutagawa, T.
    • Journal Title

      Crystal Growth & Design

      Volume: 15 Issue: 12 Pages: 5705-5711

    • DOI

      10.1021/acs.cgd.5b00695

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] キラルアンモニウムを導入した二次元ペロブスカイト結晶の相転移挙動、結晶構造および誘電応答2017

    • Author(s)
      高橋正樹、星野哲久、武田貴志、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] グアニジニウム-スルホン酸塩の相転移、結晶構造および誘電応答2017

    • Author(s)
      小林貴博、星野哲久、武田貴志、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] チアゾール骨格を用いた分子性吸脱着材料の開発2017

    • Author(s)
      西山浩史、武田貴志、星野哲久、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] フェニルスルホネート置換ナフタレンジイミド誘導体が形成する分子集合体構造の制御と物性開拓2017

    • Author(s)
      川崎 渉、武田貴志、星野哲久、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] テトラ[3,4]チエニレンテトラカルボン酸および誘導体の合成と物性2017

    • Author(s)
      小澤優喬、武田貴志、星野哲久、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] スルホネート基を導入した2-(2’-ヒドロキシフェニル)ベンゾ チアゾール誘導体の分子構造と発光特性2017

    • Author(s)
      中根由太、武田貴志、星野哲久、坂井賢一、芥川智行
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Control in Ferroelectricity and Optical Properties of Supramolecular Structures of Alkylamide-substituted Pyrene Derivative2017

    • Author(s)
      ANETAI, Hayato; TAKEDA, Takashi; HOSHINO, Norihisa; AKUTAGAWA, Tomoyuki
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hydrogen-Bonding Molecular Assemblies of Alkylamide-Substituted Amphiphilic Isophthalic Acid Derivative2017

    • Author(s)
      LU, Chao; TAKEDA, Takashi; HOSHINO, Norihisa; AKUTAGAWA, Tomoyuki
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分子集合体中のプロトンダイナミクスを利用した強誘電性と強弾性の創製2017

    • Author(s)
      芥川智行
    • Organizer
      北海道大学電子科学研究所ダイナミックアライアンス研究支援事業
    • Place of Presentation
      北海道大学電子科学研究所(北海道・札幌市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] キラルなアルキルアミド基を導入したピレンの分子集合構造と誘電物性2016

    • Author(s)
      姉帯 勇人、武田 貴志、星野 哲久、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルキルアミド鎖を導入した三回対称性分子が形成する分子集合体構造と誘電物性2016

    • Author(s)
      赤羽 悟、武田 貴志、星野 哲久、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分子性結晶におけるプロトン移動と強弾性機能の発現、第10回分子科学討論会2016

    • Author(s)
      内川 翔太、安田 陽、星野 哲久、武田 貴志、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] アリールスルホンアミド基を有するアントラキノン:特異な電子状態と溶媒吸着能を有する結晶構造2016

    • Author(s)
      武田 貴志、野呂 真一郎、鈴木 康孝、川俣 純、中村 貴義、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] エラグ酸溶液への光照射によるクロミズムの発現とその反応メカニズム2016

    • Author(s)
      徳冨 尚志、武田 貴志、星野 哲久、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] クラウンエーテル縮合型キノキサリノン誘導体によるカチオン-アニオン蛍光多重センシング2016

    • Author(s)
      中根 由太、武田 貴志、星野 哲久、坂井 賢一、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県・神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 有機分子を用いた次世代多重機能性材料の創製2016

    • Author(s)
      芥川智行
    • Organizer
      東北大学多元研-産総研東北センタージョイントセミナー(第25回Clayteamセミナー)
    • Place of Presentation
      東北大学さくらホール(宮城県・仙台市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 分子集合体中における「動的水素結合」と「π造形」の協同2016

    • Author(s)
      芥川智行
    • Organizer
      九州大学分子システムデバイス国際リーダー教育センターセミナー
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 動的分システムを用いた機能性分子材料の創製2016

    • Author(s)
      芥川智行
    • Organizer
      有機固体を語る会:導電性、磁性そして誘電性
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 分子集合体中における「動的水素結合」と「π造形」2016

    • Author(s)
      芥川智行
    • Organizer
      超分子による革新的マテリアル開発の拠点形成 超然プロジェクト講演会
    • Place of Presentation
      金沢大学(石川県・金沢市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 分子ダイナミクスを利用した分子集合体の機能開拓2015

    • Author(s)
      芥川智行
    • Organizer
      第16回リング・チューブ超分子研究会
    • Place of Presentation
      物質・材料研究機構(つくば)
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] キノキサリノン誘導体のラクタム-ラクチム互変異性によるアニオン-カチオン二重センシング2015

    • Author(s)
      中根 由太, 武田 貴志, 星野 哲久, 坂井 賢一, 芥川 智行
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 強弾性体ホウ酸結晶の水素結合様式と機械的刺激に対する応答2015

    • Author(s)
      内川翔太, 星野哲久, 武田貴志, 芥川智行
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 強誘電性ディスコチックヘキサゴナルカラムナー相へのイオンチャネル構造の導入2015

    • Author(s)
      木村 悠航, 小林 崇幸, 武田 貴志, 星野 哲久, 芥川 智行
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] (Halo-anilinium)(H2PO4)塩における水素結合構造の次元性およびプロトン伝導挙動の相関2015

    • Author(s)
      吉井祐弥, 武田貴志, 星野哲久, 芥川智行
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 強誘電性アルキルアミド置換ピレン誘導体におけるアルキル鎖の影響2015

    • Author(s)
      姉帯 勇人, 武田 貴志, 星野 哲久, 芥川 智行
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Current Switching Behaviour of Hydrogen-Bonding Ferroelectrics2015

    • Author(s)
      Tomoyuki Akutagawa, Hayato Anetai, Takashi Takeda
    • Organizer
      11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2015)
    • Place of Presentation
      Bad Gogging Germany
    • Year and Date
      2015-09-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] erroelectricity in Fluorescent Alkylamide-Substituted Pyrene Derivative2015

    • Author(s)
      Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Tomoyuki Akutagawa
    • Organizer
      11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2015)
    • Place of Presentation
      Bad Gogging Germany
    • Year and Date
      2015-09-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] The current switching property of hydrogen-bonding ferroelectric pyrene derivative2015

    • Author(s)
      Tomoyuki Akutagaw
    • Organizer
      13th European Conference on Molecular Electronics
    • Place of Presentation
      Strasbourg France
    • Year and Date
      2015-09-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 素結合ネットワークのダイナミクスを利用したπ電子系多重機能材料の開発2015

    • Author(s)
      芥川智行
    • Organizer
      錯体化学若手の会
    • Place of Presentation
      湯田温泉セントコア(山口)
    • Year and Date
      2015-08-06
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Cation-Anion Dual Sensing of Fluorescent Quinoxalinone Derivative2015

    • Author(s)
      Yuta Nakane, Takashi Takeda, Norihisa Hoshino, and Tomoyuki Akutagawa,
    • Organizer
      The 5th Asian Conference on Coordination Chemistry (ACCC5)
    • Place of Presentation
      Hong-Kong, China
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Crystal-to-Crystal Structural Transformation of (Imidazolium)(3-Hydroxy-2-quinoxalinecarboxylate) through H2O Adsorption-Desorption2015

    • Author(s)
      Yuya Yoshiia, Ken-ichi Sakaib, Norihisa Hoshino, Takashi Takeda, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Organizer
      The 5th Asian Conference on Coordination Chemistry (ACCC5)
    • Place of Presentation
      Hong-Kong, China
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2018-03-22  

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