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Construction of a huge porous ferromagnet

Research Project

Project/Area Number 15K13666
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

NAKABAYASHI KOJI  東京大学, 大学院理学系研究科(理学部), 助教 (80466797)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords分子磁性 / ナノ空孔材料 / ネットワーク / 分子認識 / 磁性
Outline of Final Research Achievements

In recent studies on molecule-based magnets, functional magnets showing properties such as dielectricity and photo-responsivity. From the view point of the functionality, porous molecule-based magnets, which can encapsulate guest molecules within their cavity, are interesting materials because they allow control of magnetic properties and higher functionalities by exchange of guest molecules. In this research, a nanoporous ferromagnet with 1 nm-diameter cavity has been synthesized. By using such a nanoporuous ferromagnet, novel ferromagnets containing various functional guest molecules could be synthesized, contributing to open new functional magnetic materials.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (38 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (13 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 13 results,  Acknowledgement Compliant: 4 results) Presentation (20 results) (of which Int'l Joint Research: 13 results,  Invited: 3 results) Remarks (2 results)

  • [Int'l Joint Research] Jagiellonian University(Poland)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ヤゲロニア大学(ポーランド)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] ヤゲロニアン大学(ポーランド)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Achieving white light emission and increased magnetic anisotropy by transition metal substitution in functional materials based on dinuclear DyIII(4-pyridone)[MIII(CN)6]3- (M = Co, Rh) molecules2018

    • Author(s)
      Wang Junhao、Chorazy Szymon、Nakabayashi Koji、Sieklucka Barbara、Ohkoshi Shin-ichi
    • Journal Title

      J. Mater. Chem. C

      Volume: 6 Issue: 3 Pages: 473-481

    • DOI

      10.1039/c7tc03963h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Antiferromagnetic exchange and long-range magnetic ordering in supramolecular networks constructed of hexacyanido-bridged LnIII(3-pyridone)-CrIII (Ln = Gd, Tb) chains2018

    • Author(s)
      Chorazy Szymon、Rams Michal、Wyczesany Maciej、Nakabayashi Koji、Ohkoshi Shin-ichi、Sieklucka Barbara
    • Journal Title

      CrystEngComm

      Volume: 20 Issue: 9 Pages: 1271-1281

    • DOI

      10.1039/c7ce02077e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vanadium pentacyanonitrosylmolybdate-based magnet exhibiting a high magnetic ordering temperature of 200 K2018

    • Author(s)
      Ohkoshi Shin-ichi、Nakagawa Kosuke、Yamada Ryo、Takemura Miho、Ozaki Noriaki、Tomono Keisuke、Imoto Kenta、Nakabayashi Koji、Tokoro Hiroko、Taguchi Takeyoshi、Okamoto Kohei、Ogino Tomoya、Komine Masaya
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 91 Pages: 20-23

    • DOI

      10.1016/j.inoche.2018.01.025

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetization-Induced Second Harmonic Generation (MSHG) in a Pentacyanidonitrosylmolybdate-Based Piezoelectric Ferrimagnet2018

    • Author(s)
      Komine Masaya、Imoto Kenta、Miyamoto Yasuto、Nakabayashi Koji、Ohkoshi Shin-ichi
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2018 Issue: 12 Pages: 1367-1370

    • DOI

      10.1002/ejic.201701453

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral LnIII(tetramethylurea)-[WV(CN)8] Coordination Chains Showing Slow Magnetic Relaxation2018

    • Author(s)
      Stefanczyk Olaf、Majcher Anna M.、Nakabayashi Koji、Ohkoshi Shin-ichi
    • Journal Title

      Crystal Growth & Design

      Volume: 18 Issue: 3 Pages: 1848-1856

    • DOI

      10.1021/acs.cgd.7b01719

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Magnetic Lotus Root Based on a Cyanido-Bridged Co-W Metal Assembly2017

    • Author(s)
      Nakabayashi Koji、Chorazy Szymon、Komine Masaya、Miyamoto Yasuto、Takahashi Daisuke、Sieklucka Barbara、Ohkoshi Shin-ichi
    • Journal Title

      Crystal Growth & Design

      Volume: 17 Issue: 9 Pages: 4511-4515

    • DOI

      10.1021/acs.cgd.7b00794

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fine Tuning of Multicolored Photoluminescence in Crystalline Magnetic Materials Constructed of Trimetallic EuxTb1-x[Co(CN)6] Cyanido-Bridged Chains2017

    • Author(s)
      Chorazy Szymon、Kumar Kunal、Nakabayashi Koji、Sieklucka Barbara、Ohkoshi Shin-ichi
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 9 Pages: 5239-5252

    • DOI

      10.1021/acs.inorgchem.7b00369

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High thermal durability of layered Cs4CoII[WV(CN)8]Cl3 framework: crystallographic and 133Cs NMR spectroscopic studies2016

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, T. Fujimoto, K. Yazawa, D. Takahashi, B. Sieklucka, S. Ohkoshi
    • Journal Title

      Cryst. Eng. Comm.

      Volume: 18 Issue: 48 Pages: 9236-9242

    • DOI

      10.1039/c6ce01363e

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] White light emission and slow magnetic relaxation in bifunctional molecular material constructed of DyIII single-molecule magnets linked by diamagnetic [CoIII(CN)6]3- ions2016

    • Author(s)
      S. Chorazy, M. Rams, K. Nakabayashi, B. Sieklucka, S. Ohkoshi
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 22 Pages: 7371-7375

    • DOI

      10.1002/chem.201601244

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Room-temperature photo-induced drastic color change in a cyanide-bridged Co-W bimetal assembly2016

    • Author(s)
      Y. Miyamoto, N. Ozaki, Y. Umeta, H. Tokoro, K. Nakabayashi and S. Ohkoshi
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 48 Pages: 19249-19256

    • DOI

      10.1039/c6dt03793c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of single crystalline form and first-principles calculations of copper(II) - octacyanidomolybdate(IV) photomagnetic material2016

    • Author(s)
      Y. Umeta, S. Chorazy, K. Nakabayashi, S. Ohkoshi
    • Journal Title

      Euro. J. Inorg.

      Volume: 印刷中 Issue: 13-14 Pages: 1980-1988

    • DOI

      10.1002/ejic.201500823

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tuning of charge transfer assisted phase transition and slow magnetic relaxation functionalities in {Fe9-xCox[W(CN)8]6} (x = 0 - 9) molecular solid solution2016

    • Author(s)
      S. Chorazy, J. Stanek, W. Nogas, A. Majcher, M. Rams, M. Kozieł, E. Juszyńska-Gałązka, K. Nakabayashi, S. Ohkoshi, B. Sieklucka, R. Podgajny
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 5 Pages: 1635-1646

    • DOI

      10.1021/jacs.5b11924

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Visible to near-infrared emission from LnIII(bis-oxazoline)[MoV(CN)8] (Ln=Ce-Yb) magnetic coordination polymers showing unusual lanthanide dependent sliding of cyanido-bridged layers2015

    • Author(s)
      S. Chorazy, M. Arczynski, K. Nakabayashi, B. Sieklucka, S. Ohkoshi
    • Journal Title

      Inorg. Chem.

      Volume: 54 Issue: 10 Pages: 4724-4736

    • DOI

      10.1021/acs.inorgchem.5b00040

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Construction of Magnetic Metal Assemblies with Various Dimensions2018

    • Author(s)
      Koji Nakabayashi, Szymon Chorazy, Yasuto Miyamoto, Masaya Komine, Barbara Sieklucka, Shin-ichi Ohkoshi
    • Organizer
      The Third STEPS Symposium on Photon Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dual functionalities of color-tunable photoluminescence and single ion magnet behavior embedded in cyanido-bridged bimetallic framework2018

    • Author(s)
      Junhao Wang, Szymon Chorazy, Koji Nakabayashi, Barbara Sieklucka, Shin-ichi Ohkoshi
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Tunable Multicolored Emission and Slow Magnetic Relaxation in the series of EuxTb1-x[Co(CN)6] complexes2018

    • Author(s)
      Kunal Kumar, Szymon Chorazy, Koji Nakabyashi, Barbara Sieklucka, Shin-ichi Ohkoshi
    • Organizer
      The 98th CSJ Annual Meeting
    • Related Report
      2017 Annual Research Report
  • [Presentation] Functionalities and structures of cyanido-bridged Co-W bimetal assemblies2017

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, M. Komine, B. Sieklucka, S. Ohkoshi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 (神奈川県横浜市)
    • Year and Date
      2017-03-18
    • Related Report
      2016 Research-status Report
  • [Presentation] Characteristic Structures and Magnetic Properties of Cyanido-Bridged Co-W Metal Assemblies2017

    • Author(s)
      Koji Nakabayashi, Szymon Chorazy, Yasuto Miyamoto, Masaya Komine, Barbara Sieklucka, Shin-ichi Ohkoshi
    • Organizer
      3rd International Conference on Functional Molecular Materials FUNMAT2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structural Diversity and Magnetic Properties of Cyanido-bridged Co-W Metal Assemblies2017

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, M. Komine, K. Imoto, B. Sieklucka, S. Ohkoshi
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Chiral magnetic materials based on trivalent metal complexes and octacyanidotungstate(V)2017

    • Author(s)
      O. Stefanczyk, K. Imoto, K. Nakabayashi, S. Ohkoshi
    • Organizer
      The 3rd International Conference on Functional Molecular Materials - FUNMAT2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic Properties and Functionalities of Cyanido-bridged Co-W metal assemblies2016

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, M. Komine, K. Imoto, B. Sieklucka, S. Ohkoshi
    • Organizer
      The 10th Russian-Japanese Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      ノボシビルスク (ロシア)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] High-temperature structure of a thermal durable magnet revealed by single-crystal X-ray diffraction and NMR2016

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, K. Yazawa, D. Takahashi, B. Sieklucka, S. Ohkoshi
    • Organizer
      The 15th International Conference on Molecule-Based Magnets (ICMM2016)
    • Place of Presentation
      仙台国際センター (宮城県仙台市)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Observation of magnetization-induced second harmonic generation in a pentacyanidenitrosylmolybdate-based metal assembly2016

    • Author(s)
      Masaya Komine, Kenta Imoto, Yasuto Miyamoto, Koji Nakabayashi, Shi-ichi Ohkoshi
    • Organizer
      The 15th International Conference on Molecule-Based Magnets (ICMM2016)
    • Place of Presentation
      仙台国際センター (宮城県仙台市)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Two-dimensional octacyanidemetalate-based magnets2016

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, B. Sieklucka, S. Ohkoshi
    • Organizer
      The 4th Awaji International Workshop on Electron Spin Science & Technology: Biological and Materials Science Oriented Applications(AWEST2016)
    • Place of Presentation
      淡路夢舞台 (兵庫県淡路市)
    • Year and Date
      2016-06-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis, crystal structure and magnetic property of pentacyanidonitrosylmolybdate-based 1-D chain like compounds2016

    • Author(s)
      Masaya Komine, Kenta Imoto, Koji Nakabayashi, Shin-ichi Ohkoshi
    • Organizer
      The 4th Awaji International Workshop on Electron Spin Science & Technology: Biological and Materials Science Oriented Applications (AWEST2016)
    • Place of Presentation
      淡路夢舞台 (兵庫県淡路市)
    • Year and Date
      2016-06-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of a noncentrosymmetric pentacyanidonitrosylmolybdate-based metal assembly showing a nonlinear optical effect2016

    • Author(s)
      M. Komine, K. Imoto, Y. Miyamoto, K. Nakabayashi, S. Ohkoshi
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] Functional magnets based on cyanido-bridged metal assemblies2016

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, D. Takahashi, T. Kinoshita, S. Ohkoshi
    • Organizer
      The 2nd STEPS Symposium on Photon Science (STEPS2)
    • Place of Presentation
      サンクトペテルブルク (ロシア)
    • Year and Date
      2016-03-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Cyanide-bridged Co–W bimetal assembly exhibiting photo-induced charge transfer phase transition at room temperature2015

    • Author(s)
      Y. Miyamoto, N. Ozaki, Y. Umeta, K. Imoto, H. Tokoro, K. Nakabayashi, S. Ohkoshi
    • Organizer
      The Internatonal Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic property and optical property of cesium manganese pentacyanidonitrosylmolybdate assembly2015

    • Author(s)
      M. Komine, K. Imoto, Y. Miyamoto, K. Nakabayashi, S. Ohkoshi
    • Organizer
      The Internatonal Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic and electric properties of thermal-durable cyanido-bridged metal assembly2015

    • Author(s)
      K. Nakabayashi, S. Chorazy, Y. Miyamoto, D. Takahashi, T. Kinoshita, S. Ohkoshi
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Magnetic and luminescent bifunctionality of octacyanido-bridged d-f coordination polymers2015

    • Author(s)
      S. Chorazy, K. Nakabayashi, M. Arczynski, B. Sieklucka, S. Ohkoshi
    • Organizer
      The 9th International Conference on f-Elements 2015
    • Place of Presentation
      オックスフォード (英国)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Optical activity and switchable luminescence in octacyanido-based bimetallic layered magnets2015

    • Author(s)
      S. Chorazy, R. Podgajny, K. Nakabayashi, W. Nitek, E. Görlich, M. Rams, Z. Tomkowicz, B. Sieklucka, S. Ohkoshi
    • Organizer
      Multiscale phenomena in molecular matter
    • Place of Presentation
      クラクフ(ポーランド)
    • Year and Date
      2015-07-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Charge Transfer and Spin Transition Phenomena in Cyanido-Bridged {M9[M’(CN)8]6} (M=3d metal ion, M’=W,Re) Molecules2015

    • Author(s)
      S. Chorazy, R. Podgajny, K. Nakabayashi, W. Nogas, M. Rams, J. Stanek, W. Nitek, B. Sieklucka, S. Ohkoshi
    • Organizer
      XXV. International Conference on Coordination and Bioinorganic Chemistry
    • Place of Presentation
      スモレニツェ (スロバキア)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 所属研究室ホームページ

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/ssphys/thesis.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 所属研究室HP

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/ssphys/index.html

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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