| Project/Area Number |
15K13695
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
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| Keywords | 鉄触媒 / CH官能基化 / アミノ化 / 含窒素多環芳香族化合物 / 有機電子材料 / 正孔輸送材料 |
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| Outline of Final Research Achievements |
We have developed noble inter- and intramolecular C-H amination reactions and synthesized a variety of substituted 5,10-dihydrophenazines by short-step and concise synthetic route based on the newly developed lamination reactions. The synthesis utilized industrially attractive iron-catalysts and can convert easily accessible diarylamines to the corresponding ortho-phenylenediamines and consequently dihydrophenazines in the presence of versatile oxidants and the iron catalysts. This new method enables high-yielding preparation of various dihydrophenazines which have not been easily synthesized by the existing method due to the difficulties in prefunctionalization of substrates.
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