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Flexible ceramic membranes via polymer-supported organosilica layered-hybrid structure

Research Project

Project/Area Number 15K14207
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionHiroshima University

Principal Investigator

Tsuru Toshinori  広島大学, 工学研究科, 教授 (20201642)

Co-Investigator(Renkei-kenkyūsha) KANEZASHI MASAKOTO  広島大学, 大学院工学研究科, 准教授 (10467764)
NAGASAWA HIROKI  広島大学, 大学院工学研究科, 助教 (30633937)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsセラミック膜 / シリカ膜 / ゾル-ゲル / layered hybrid / プラズマCVD / 分離 / 分離膜 / プラズマ
Outline of Final Research Achievements

A promising layered-hybrid membrane consisting of a microporous organosilica active layer deposited onto a porous polymer support was prepared and applied for vapor permeation of H2O/isopropanol and reverse osmosis. The VP performance showed water permeance of approximately 1.0×10-6 mol/ (m2 s Pa) and a separation factor of approximately several hundreds~1000. Layered hybrid membranes showed desalination performance, which was increased by hydrochloric acid vapor treatment.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (13 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results) Book (1 results)

  • [Journal Article] Facile and scalable flow-induced deposition of organosilica on porous polymer supports for reverse osmosis desalination2018

    • Author(s)
      Genghao Gong, Hiroki Nagasawa, Masakoto Kanezashi, Toshinori Tsuru
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 16 Pages: 14070-14078

    • DOI

      10.1021/acsami.7b19075

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atmospheric-Pressure Plasma-Enhanced Chemical Vapor Deposition of Microporous Silica Membranes for Gas Separation2017

    • Author(s)
      Hiroki Nagasawa, Yuta Yamamoto, Nobukazu Tsuda, Masakoto Kanezashi, Tomohisa Yoshioka, Toshinori Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 524 Pages: 644-651

    • DOI

      10.1016/j.memsci.2016.11.067

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo-induced sol-gel synthesis of polymer-supported silsesquioxane membranes2017

    • Author(s)
      H. Nagasawa, M. Nishibayashi, M. Kanezashi, T. Yoshioka and T. Tsuru
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 12 Pages: 7150-7157

    • DOI

      10.1039/c6ra21161e

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Plasma-enhanced chemical vapor deposition of amorphous carbon molecular sieve membranes for gas separation2016

    • Author(s)
      Hiroki Nagasawa, Masakoto Kanezashi,Tomohisa Yoshioka, Toshinori Tsuru
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 64 Pages: 59045-59049

    • DOI

      10.1039/c6ra09381g

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tailoring the separation behavior of polymer-supported organosilica layered-hybrid membrane by a post treatment: a detailed comparison of HCl and HN3 vapor treatment2016

    • Author(s)
      Genghao Gong, Hiroki Nagasawa, Masakoto Kanezashi and Toshinori Tsuru
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 8 Issue: 17 Pages: 11060-11069

    • DOI

      10.1021/acsami.6b01986

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Reverse osmosis performance of layered-hybrid membranes consisting of an organosilica separation layer on polymer supports2015

    • Author(s)
      Genghao Gong, Hiroki Nagasawa, Masakoto Kanezashi, and Toshinori Tsuru
    • Journal Title

      Journal of Membrane Science

      Volume: 494 Pages: 104-112

    • DOI

      10.1016/j.memsci.2015.07.039

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] シリカおよびオルガノシリカを用いたナノ/サブナノ多孔膜の開発と環境・エネルギーへの応用2017

    • Author(s)
      都留稔了
    • Organizer
      第24回ヤングセラミスト・ミーティング特別講演
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Silica-Based Membranes with Molecular-Net-Sieving Properties: Applications to Catalytic Membrane Reactors2017

    • Author(s)
      T. Tsuru
    • Organizer
      International Symposium on Environmentally Friendly Smart Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Robust reverse osmosis (RO)/nanofiltration (NF) membranes with thermal stability and chlorine tolerance for expanding applications to various types of water resources2017

    • Author(s)
      T. Tsuru
    • Organizer
      The 3rd Asian Symposium on Water Reuse
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] セラミック多孔膜による高度分離:ナノ~サブナノ細孔の設計,評価と応用2017

    • Author(s)
      都留稔了
    • Organizer
      日本化学会第97春季年会ATPセッション
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] The third Advanced Materials Conference, Nano/subnanoporous ceramic membranes for molecular separation in gas and liquid phase2016

    • Author(s)
      T. Tsuru
    • Organizer
      The third Advanced Materials Conference
    • Place of Presentation
      Malaysia
    • Year and Date
      2016-11-27
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of SiO2-based nano/subnano-porous membranes and pore-size evaluation by nanopermporometry (NPP) and normalized Knudsen-based permeance (NKP2016

    • Author(s)
      T. Tsuru
    • Organizer
      International Zeolite Membrane Meeting (IZMM)
    • Place of Presentation
      Dalian, China
    • Year and Date
      2016-08-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Book] Hybrid Membrane Systems, Emerging Technologies and Applications2017

    • Author(s)
      Genghao Gong, Toshinori Tsuru
    • Total Pages
      12
    • Publisher
      Nova Publishers
    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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