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Visualization of surface and interface in functional polymer thin films using GISAXS-CT

Research Project

Project/Area Number 15K17489
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Quantum beam science
Research InstitutionKyoto University

Principal Investigator

Hiroki Ogawa  京都大学, 化学研究所, 助教 (00535180)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords表面・界面 / 高分子薄膜 / 小角X線散乱 / 斜入射小角X線散乱 / 表面界面 / コンピュータトモグラフィー / 斜入射小角散乱 / コンピュータートモグラフィー
Outline of Final Research Achievements

Using grazing-incidence small-angle scattering (GISAXS) with computed tomography (CT), we have reconstructed the spatial distribution of a thin gold (Au) layer buried under a thin poly(styrene-b-2-vinylpyridine) (PS-b-P2VP) layer. Owing to the difference between total reflection angles of Au and PS-b-P2VP, the scattering profiles for Au nanoparticles and self-assembled nanostructures of PS-b-P2VP could be independently obtained by changing the X-ray angle of incidence. Reconstruction of scattering profiles allows to separately characterize spatial distributions in Au and PS-b-P2VP nanostructures.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (7 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results)

  • [Journal Article] Visualizing patterned thin films by grazing-incidence small-angle X-ray scattering coupled with computed tomography2015

    • Author(s)
      Hiroki Ogawa, Yukihiro Nishikawa, Akihiko Fujiwara, Mikihito Takenaka, Yi-Chin Wang, Toshiji Kanaya and Masaki Takata
    • Journal Title

      Journal of applied crystallography

      Volume: 48 Issue: 6 Pages: 1645-1650

    • DOI

      10.1107/s1600576715016684

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 放射光小角X線散乱-コンピュータトモグラフィ法による高分子表面・界面構造の可視化2017

    • Author(s)
      小川紘樹、西川幸宏、竹中幹人、藤原明比古、高田昌樹、金谷利治
    • Organizer
      第66会高分子学会年次大会
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2017-05-29
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] GISAXS-CTによる高分子-金微粒子パターン薄膜の可視化2017

    • Author(s)
      小川紘樹、西川幸宏、竹中幹人、藤原明比古、高田昌樹、金谷利治
    • Organizer
      第30回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      神戸芸術センター
    • Year and Date
      2017-01-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] GISAXS-CTによる金ナノ粒子とブロック共重合体パターン薄膜の可視化2016

    • Author(s)
      小川紘樹、西川幸宏、竹中幹人、藤原明比古、高田昌樹、金谷利治
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] GISAXS-CT法によるブロック共重合体薄膜におけるナノ界面の可視化2015

    • Author(s)
      小川紘樹、西川幸宏、竹中幹人、藤原明比古、高田昌樹
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 川内キャンパス, 仙台市
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Spin-coating process of block copolymer thin films through the in-situ fast GISAXS measurements2015

    • Author(s)
      Hiroki Ogawa
    • Organizer
      GISAS2015
    • Place of Presentation
      Centre Universitaire Mediterraneen, Nice, France
    • Year and Date
      2015-09-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] GISAXS-CTを用いた高分子表面・界面の可視化2015

    • Author(s)
      小川紘樹、西川幸宏、竹中幹人、藤原明比古、高田昌樹
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター, 札幌市
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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