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Structural control of flexible macroporous monoliths and their applications

Research Project

Project/Area Number 15K17909
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

Hayase Gen  東北大学, 学際科学フロンティア研究所, 助教 (70750454)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords材料化学 / 無機化学 / ゾル―ゲル / 多孔体 / シリコーン / ナノファイバー / 力学特性 / エアロゲル / 液相合成 / 有機-無機ハイブリッド / ゾル-ゲル / 相分離 / 撥液性
Outline of Final Research Achievements

For the purpose of broad control of microstructure, we tried to prepare porous macroporous with starting compositions under various conditions. In particular, we focused on the fabrication of boehmite nanofiber-silsesquioxane "core-shell" porous monoliths. This material can be expected to be applied to heat insulating materials under special conditions and light weight composite materials with resins. In addition, we succeeded in fablicating a ultralow-density transparent porous materials by using boehmite nanofibers via a new process. These results can be expected to lead to the future development of composite materials.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (10 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Remarks (2 results)

  • [Journal Article] Fabrication of hydrophobic polymethylsilsesquioxane aerogels by a surfactant-free method using alkoxysilane with ionic group2017

    • Author(s)
      Gen Hayase, Shuya Nagayama, Kazuya Nonomura, Kazuyoshi Kanamori, Ayaka Maeno, Hironori Kaji, Kazuki Nakanishi
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 印刷中 Issue: 2 Pages: 104-108

    • DOI

      10.1016/j.jascer.2017.02.003

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Facile fabrication of ultralow-density transparent boehmite nanofiber cryogel beads and their application to a nanoglue2017

    • Author(s)
      Gen Hayase
    • Journal Title

      ChemNanoMat

      Volume: 3 Issue: 3 Pages: 168-171

    • DOI

      10.1002/cnma.201600360

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Boehmite Nanofiber-Polymethylsilsesquioxane Core-Shell Porous Monoliths for a Thermal Insulator under Low Vacuum Conditions2016

    • Author(s)
      Gen Hayase, Kazuya Nonomura, Kazuyoshi Kanamori, Ayaka Maeno, Hironori Kaji, Kazuki Nakanishi
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 10 Pages: 3237-3240

    • DOI

      10.1021/acs.chemmater.6b01010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ベーマイトナノファイバーを用いたモノリス型低密度多孔体の簡易作製2017

    • Author(s)
      早瀬 元
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス(東京都千代田区)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ultralow-density transparent boehmite aerogels/cryogels and their application to a nanoglue2017

    • Author(s)
      Gen Hayase
    • Organizer
      5th International Conference on Multifunctional, Hybrid and Nanomaterials
    • Place of Presentation
      リスボン(ポルトガル)
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Facile Synthesis of Boehmite Nanofiber-Polysilsesquioxane Core-Shell Porous Monoliths via Evaporative Drying2016

    • Author(s)
      Gen Hayase, Kazuya Nonomura, Kazuyoshi Kanamori, Kazuki Nakanishi
    • Organizer
      AsiaNANO 2016
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Year and Date
      2016-10-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Boehmite nanofiber-polymethylsilsesquioxane core-shell porous monoliths and their applications2016

    • Author(s)
      Gen Hayase, Kazuya Nonomura, Kazuyoshi Kanamori, Kazuki Nakanishi
    • Organizer
      6th International Congress on Ceramics
    • Place of Presentation
      ドレスデン(ドイツ)
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ベーマイトナノファイバー複合材料作製手法の探索と機能化2016

    • Author(s)
      早瀬 元
    • Organizer
      日本ゾル-ゲル学会 第14回討論会
    • Place of Presentation
      早稲田大学西早稲田キャンパス(東京都新宿区)
    • Year and Date
      2016-08-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 界面活性剤フリーのモノリス型マクロ・メソ多孔体作製2015

    • Author(s)
      早瀬 元, 野々村 和也, 永山 修也, 金森 主祥, 中西 和樹
    • Organizer
      日本ゾル-ゲル学会 第13回討論会
    • Place of Presentation
      北海道札幌市・北海道大学
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 濡れ転移を利用したモノリス型マクロ多孔体の合成2015

    • Author(s)
      早瀬 元, 野々村 和也, 金森 主祥, 中西 和樹
    • Organizer
      平成27年度繊維学会秋季研究発表会
    • Place of Presentation
      京都府京都市・京都工芸繊維大学
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] 柔軟多孔体「マシュマロゲル」の合成と複合化2015

    • Author(s)
      早瀬 元
    • Organizer
      ゲルワークショップ イン 仙台
    • Place of Presentation
      宮城県仙台市・La楽リゾートホテル グリーングリーン
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Ultralow-Density, Transparent Boehmite Nanofiber Aerogels and Their Alumina Derivatives2015

    • Author(s)
      Gen Hayase, Kazuya Nonomura, Kazuyoshi Kanamori, George Hasegawa, Kazuki Nakanishi
    • Organizer
      The XVIII International Sol-Gel Conference (Sol-Gel 2015)
    • Place of Presentation
      京都府京都市・メルパルク京都
    • Year and Date
      2015-09-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] ベーマイトナノファイバーを構造に用いた有機-無機ハイブリッドエアロゲル2015

    • Author(s)
      早瀬 元, 野々村 和也, 金森 主祥, 中西 和樹
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      東京都江戸川区・タワーホール船堀
    • Year and Date
      2015-06-11
    • Related Report
      2015 Research-status Report
  • [Remarks] Aerogel.jp

    • URL

      http://www.aerogel.jp/

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
  • [Remarks] Marshmallowgel.com

    • URL

      http://www.marshmallowgel.com/

    • Related Report
      2016 Annual Research Report 2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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