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Programming Spatial Arrangements and Specific Dynamic Function of Metal Complexes using Artificial Ligands with Multi-Binding Sites

Research Project

Project/Area Number 16105001
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

SHIONOYA Mitsuhiko  The University of Tokyo, 大学院・理学系研究科, 教授 (60187333)

Co-Investigator(Kenkyū-buntansha) TANAKA Kentaro  名古屋大学, 大学院・理学研究科, 教授 (40281589)
HIRAOKA Shuichi  東京大学, 大学院・総合文化研究科, 教授 (10322538)
TASHRO Shohei  東京大学, 大学院・理学系研究科, 助教 (80420230)
SHIRO Motoo  , 理学電機・X線研究所, 嘱託研究員
KATO Tatsuhisa  城西大学, 理学部, 教授(現在、京都大学) (80175702)
KIMURA Eiichi  広島大学, 名誉教授 (30034010)
Co-Investigator(Renkei-kenkyūsha) UBE Hitoshi  東京大学, 大学院・理学系研究科, 助教 (00512138)
Project Period (FY) 2004 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥115,960,000 (Direct Cost: ¥89,200,000、Indirect Cost: ¥26,760,000)
Fiscal Year 2008: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Fiscal Year 2007: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2006: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2005: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2004: ¥71,630,000 (Direct Cost: ¥55,100,000、Indirect Cost: ¥16,530,000)
Keywords超分子 / 金属イオン配列 / 動的機能 / 人工DNA / 分子運動素子 / 金属錯体 / プログラミング / 金属配列 / 動的錯体 / 多座配位子 / 人工ペプチド / プログラム分子 / 分子カプセル / 分子ボールベアリング / 環状ペプチド / ヒドロキシピリド / 多核金属錯体 / 二重らせん構造 / 高次構造制御 / 分子電線 / オリゴヌクレオチド
Research Abstract

In this study, we have synthesized a variety of functional metal complexes with the aid of bio-inspired and completely artificial ligands with multi-binding sites which include precisely programmed information on the spatial arrangements of metals, and explored specific properties and dynamic functions based on the modes of metal arrays. As the result, heterologous metal arrays using artificial DNA, nanocapsules with dynamic functions, and molecular motional devices such as molecular ball bearings and a molecular crank mechanism have been successfully constructed.

Report

(5 results)
  • 2008 Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (30 results)

All 2010 2009 2008 2007 2006 2005 2004 Other

All Journal Article (26 results) (of which Peer Reviewed: 2 results) Presentation (2 results) Book (1 results) Remarks (1 results)

  • [Journal Article] A Molecular Double Ball Bearing: An AgI-PtII Dodecanuclear Quadruple-Decker Complex with Three Rotors, Angew.2010

    • Author(s)
      S. Hiraoka, Y. Hisanaga, M. Shiro, M. Shionoya
    • Journal Title

      Chem. Int. Ed. 49

      Pages: 1669-1673

    • Related Report
      2008 Final Research Report
  • [Journal Article] Template-Directed Synthesis of a Covalent Organic Capsule based on a 3 nm-Sized Metallo-Capsule2009

    • Author(s)
      S. Hiraoka, Y. Yamauchi, R. Arakane, M. Shionoya
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 11646-11647

    • Related Report
      2008 Final Research Report
  • [Journal Article] Discrete Self-Assembly of Iron Ions inside Triple-Stranded Artificial DNA, Angew.2009

    • Author(s)
      Y. Takezawa, W. Maeda, K. Tanaka, M. Shionoya
    • Journal Title

      Chem. Int. Ed. 48

      Pages: 1081-1084

    • Related Report
      2008 Final Research Report
  • [Journal Article] A Self-Assembled Organic Capsule Formed from the Union of Six Haxagram-Shaped Amphiphile Molecules2008

    • Author(s)
      S. Hiraoka, K. Harano, M Shiro, M. Shionoya
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 14368-14369

    • Related Report
      2008 Final Research Report
  • [Journal Article] Ranging Correlated Motion (1. 5 nm) of Two Coaxially Arranged Rotors Mediated by Helix Inversion of a Supramolecular Transmitter2008

    • Author(s)
      S. Hiraoka, E. Okuno, T. Tanaka, M. Shiro, M. Shionoya
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 9089-9098

    • Related Report
      2008 Final Research Report
  • [Journal Article] 3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage2007

    • Author(s)
      K. Harano, S. Hiraoka, M. Shionoya
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 5300-5301

    • Related Report
      2008 Final Research Report
  • [Journal Article] 3 nm-Scale Molecular Switching between Fluorescent Coordination Casule and Nonfluorescent Cage2007

    • Author(s)
      K. Harano, S. Hiraoka, and M. Shionoya
    • Journal Title

      Journal of the American Chemical Society 129

      Pages: 5300-5301

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Template-Directed Synthetic Approach to Halogen-Bridged Mixed-Valence Platinum Comlexes on Anificial Petides in Solution2007

    • Author(s)
      K. Tanaka, K. Kaneko, Y. Watanabe, and M. Shionoya
    • Journal Title

      Dalton Transaction

      Pages: 5369-5371

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Programmable Self-Assembly of Metal Ions in Artificial DNA2006

    • Author(s)
      K. Tanaka, G.H. Clever, Y. Takezawa, Y, Yamada, C. Kaul, M. Shionoya, T Carell
    • Journal Title

      Nat. Nanotech 1

      Pages: 190-194

    • Related Report
      2008 Final Research Report
  • [Journal Article] Programmable Self-Assembly of Metal Inos in Artificial DNA2006

    • Author(s)
      K.Tanaka, G.H.Clever, Y.Takazawa, Y.Yamada, C.Kaul, M.Shionoya, T.Carell
    • Journal Title

      Nature Nanotechnology 1

      Pages: 190-194

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrostatically Controlled Hierarchical Arrangement of Monocationic Silver(I) and Dicationic Merucury(II) Ions between Disk-Shaped Template Ligands2006

    • Author(s)
      S.Hiraoka, T.Tanaka, M.Shionoya
    • Journal Title

      Journal of American Chemical Society 128

      Pages: 13038-13039

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Isostructural Coordination Capsules for a Series of 10 Different d^5 to d^<10> Transition-Metal Ions2006

    • Author(s)
      S.Hiraoka, K.Harano, M.Shiro, Y.Ozawa, N.Yasuda, K.Toriumi, M.Shionoya
    • Journal Title

      Angewandte Chemic International Edition 45

      Pages: 6488-6491

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Supramolecular Approach to Metal Array Programming Using Artificial DNA2006

    • Author(s)
      M.Shionoya
    • Journal Title

      Nanotechnology : Science and Computation, Part IV Elctronics, Nanowire and DNA(Springer-Verlag)

      Pages: 191-198

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Programmed Metal Arrays by Means of Designable Biological Macromolecules2006

    • Author(s)
      K.Tanaka, M.Shionoya
    • Journal Title

      Nano Redox Sites - Nano-Space Control and Its Applications(Springer-Verlag)

      Pages: 155-165

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Quantitative Dynamic Interconversion between Ag(I)-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release2005

    • Author(s)
      S. Hiraoka, K. Harano, M. Shiro, M. Shionoya
    • Journal Title

      Angew. Chem. Int. Ed. 44

      Pages: 2727-2731

    • Related Report
      2008 Final Research Report
  • [Journal Article] Quantitative Dynamic Interconversion between Ag (I)-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release2005

    • Author(s)
      S.Hiraoka, K.Harano, M.Shiro, M.Shionoya
    • Journal Title

      Angew.Chem.,Int.Ed. 44

      Pages: 2727-2731

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Heterogeneous Assembly of Silver(I) and Calcium(II) Ions Accompanying a Dimer Formation of cyclo(L-Ala-L-Met)32005

    • Author(s)
      T.Okada, K.Tanaka, M.Shiro, M.Shionoya
    • Journal Title

      Chem.Commun.

      Pages: 1484-1486

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Analysis of Hydrogen-Terminated Si(111) Surface by Infrared Multiple-Angle Incidence Resolution Spectroscopy2005

    • Author(s)
      H.Kakuda, T.Hasegawa, T.Tanaka, K.Tanaka, M.Shionoya
    • Journal Title

      Chem.Phys.Lett. 415

      Pages: 172-175

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 人工DNAを用いて金属イオンを並べる2005

    • Author(s)
      塩谷光彦
    • Journal Title

      化学と教育 53・No,1

      Pages: 4-7

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Heterogeneous Assembly of Silver(I) and Calcium(II) Ions Accompanying a Dimer Formation of cyclo(L-Ala-L-Met)_32005

    • Author(s)
      T.Okada, K.Tanaka, M.Shiro, M.Shionoya
    • Journal Title

      Chemical communications

      Pages: 1484-1486

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Quantitative Dynamic Interconversion between Ag(I)-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release2005

    • Author(s)
      S.Hiraoka, K.Hamno, M.Shiro, M.Shionoya
    • Journal Title

      Angewandte Chemie, Int Ed. (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Molecular Ball Bearing Mediated by Multi-Ligand Exchange in Concert2004

    • Author(s)
      S. Hiraoka, K. Hirata, M. Shionoya
    • Journal Title

      Angew. Chem. Int. Ed. 43

      Pages: 3814-3818

    • Related Report
      2008 Final Research Report
  • [Journal Article] Heterotopic Assemblage of Two Different Disk-Shaped Ligands through Trinuclear Silver(I) Complexation: Ligand Exchange-Driven Molecular Motion2004

    • Author(s)
      S. Hiraoka, M. Shiro, M. Shionoya
    • Journal Title

      J. Am. Chem. Soc. 126

      Pages: 1214-1218

    • Related Report
      2008 Final Research Report
  • [Journal Article] Artificial Metallo-DNA : A Bio-Inspired Approach to Metal Array Programming2004

    • Author(s)
      M.Shionoya, K.Tanaka
    • Journal Title

      Current opinion in chemical biology 8

      Pages: 592-597

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Heterotopic Assemblage of Two Different Disk-Shaped Ligands through Trinuclear Silver(I) Complexation : Ligand Exchange-Driven Molecular Motion2004

    • Author(s)
      S.Hiraoka, M.Shiro, M.Shionoya
    • Journal Title

      Journal of American Chemical Society 126

      Pages: 1214-1218

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Molecular Ball Bearing Mediated by Multi-Ligand Exchange in Concert2004

    • Author(s)
      S.Hiraoka, K.Hirata, M.Shionoya
    • Journal Title

      Angewandte Chemie, Int. Ed. 43

      Pages: 3814-3818

    • Related Report
      2004 Annual Research Report
  • [Presentation] Supramolecular Nanoarchitecture for Array, Space, and Motion2008

    • Author(s)
      M. Shionoya (Plenary Lecture)
    • Organizer
      4th EuCheMS Conference on NITROGEN LIGANDS in Coordination Chemistry, Metal-Organic Chemistry, Bioinorganic Chemistry & Homogeneous Catalysis
    • Place of Presentation
      Garmisch-Partenkirchen, Germany
    • Related Report
      2008 Final Research Report
  • [Presentation] Nanoscopic Self-Assembled ArchitectUre:Programmable Metal Arrays and Molecular Motions2007

    • Author(s)
      Mitsuhiko Shionoya
    • Organizer
      Japan-USA Joint Symposium
    • Place of Presentation
      Northwestern University,USA
    • Related Report
      2007 Annual Research Report
  • [Book] 超分子金属錯体(塩谷光彦, 田中健太郎, 平岡秀一)2009

    • Author(s)
      藤田誠, 塩谷光彦
    • Related Report
      2008 Final Research Report
  • [Remarks] 研究室ホームページアドレス:

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/bioinorg/index.html

    • Related Report
      2008 Final Research Report

URL: 

Published: 2004-04-01   Modified: 2016-04-21  

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