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Diffusion Behavior of Metal Ion Solute in Ionic Liquid Solution ~Beyond the Viscosity Limit~

Research Project

Project/Area Number 16H04096
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionOsaka University

Principal Investigator

Fukui Ken-ichi  大阪大学, 基礎工学研究科, 教授 (60262143)

Research Collaborator Morikawa Yoshitada  
Imanishi Akihito  
Tanabe Ichiro  
Katayama Chiaki  
Takahashi Akihiro  
Suyama Aki  
Sato Taiki  
Yonekawa Masaki  
Mine Toru  
Okaue Daijiro  
Imai Masaya  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2018: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Keywords拡散機構 / イオン液体 / 光電子分光 / 原子間力顕微鏡 / 分子動力学計算 / 界面分光 / 金属イオン / 粘性 / 表面・界面
Outline of Final Research Achievements

Diffusion behavior of metal ions as energy career (e.g. Li+,Na+, Mg2+, Al3+) in the secondary battery in ionic liquids particularly close to the electrode were analyzed. Major question is how the metal ions with rather high solvation affinity behave in the rather complicated electric double layer of the ionic liquid. By using the newly prepared “tailored IL films, which consists of layers with different concentration of the metal ions, it was concluded that the mobility of the metal ions is greatly reduced at the interface region less than 3 nm.

Academic Significance and Societal Importance of the Research Achievements

不揮発・難燃性でかつ広い電位窓をもつため,二次電池等の電気化学デバイスの電解質として期待されているイオン液体の溶液中で,溶液の粘性から予想される以上に溶質金属イオンの速い拡散が起こり得ることが示唆されていた。液体バルク中や界面それぞれで特殊な場を形成するイオン液体内での金属イオンの拡散についてミクロな物理化学的理解を進めた本研究の成果は,粘性というバルク液体の物性だけに囚われず,効率的な金属イオンの拡散を可能とするイオン液体の化学設計,電極材料・構造の設計に新たな指針を与え,高効率二次電池の構築に大きく寄与できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (103 results)

All 2019 2018 2017 2016 Other

All Journal Article (16 results) (of which Peer Reviewed: 15 results,  Open Access: 4 results) Presentation (82 results) (of which Int'l Joint Research: 44 results,  Invited: 16 results) Book (2 results) Remarks (3 results)

  • [Journal Article] 電気化学界面のその場観測技術2019

    • Author(s)
      福井賢一
    • Journal Title

      Denki Kagaku

      Volume: 87 Issue: Spring Pages: 57-63

    • DOI

      10.5796/denkikagaku.19-TE0002

    • NAID

      130007607610

    • ISSN
      2433-3255, 2433-3263
    • Year and Date
      2019-03-05
    • Related Report
      2018 Annual Research Report
  • [Journal Article] Potential Dependence of Electronic Transition Spectra of Interfacial Ionic Liquids Studied by Newly Developed Electrochemical Attenuated Total Reflectance Spectroscopy2019

    • Author(s)
      I. Tanabe, A. Suyama, T. Sato, K. Fukui
    • Journal Title

      Annalytical Chemistry

      Volume: 91(5) Issue: 5 Pages: 3436-3442

    • DOI

      10.1021/acs.analchem.8b04931

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic properties of ionic liquid/organic semiconductor interfaces revealed by molecular dynamics simulations2018

    • Author(s)
      Yokota Yasuyuki、Miyamoto Hiroo、Imanishi Akihito、Takeya Jun、Inagaki Kouji、Morikawa Yoshitada、Fukui Ken-ichi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 18 Pages: 13075-13083

    • DOI

      10.1039/c8cp01043a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Development of Local Analysis Technique of Electric Double Layer at Electrode Interfaces and its Application to Ionic Liquid Interfaces2018

    • Author(s)
      K. Fukui
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91(8) Issue: 8 Pages: 1210-1219

    • DOI

      10.1246/bcsj.20180086

    • NAID

      130007435128

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic analysis of various ionic liquids by attenuated total reflectance spectroscopy (145?450 nm) and quantum chemical calculations2018

    • Author(s)
      Tanabe Ichiro、Suyama Aki、Sato Taiki、Fukui Ken-ichi
    • Journal Title

      The Analyst

      Volume: 143 Issue: 11 Pages: 2539-2545

    • DOI

      10.1039/c8an00563j

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Potential dependent changes of structural and dynamical properties of 1-butyl-3- methylimidazolium bis (trifluoromethanesulfonyl)imide on graphite electrode revealed by molecular dynamics simulation2018

    • Author(s)
      H. Miyamoto, Y. Yokota, A. Imanishi, K. Inagaki, Y. Morikawa, K. Fukui
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 20 Issue: 29 Pages: 19408-19415

    • DOI

      10.1039/c8cp02733a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and dynamic properties of 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide/mica and graphite interfaces revealed by molecular dynamics simulation2018

    • Author(s)
      Yokota Yasuyuki、Miyamoto Hiroo、Imanishi Akihito、Inagaki Kouji、Morikawa Yoshitada、Fukui Ken-ichi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 9 Pages: 6668-6676

    • DOI

      10.1039/c7cp07313e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Potential Dependent Structure of Electric Double Layer Faced to Solid Electrode Surfaces Analyzed by Electrochemical Frequency Modulation Atomic Force Microscopy2017

    • Author(s)
      Ken-ichi Fukui, Toru Utsunomiya, Yasuyuki Yokota
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 8S1 Pages: 08LA03-08LA03

    • DOI

      10.7567/jjap.56.08la03

    • NAID

      210000148174

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A relationship between the force curve measured by atomic force microscopy in an ionic liquid and its density distribution on a substrate2017

    • Author(s)
      Amano Ken-ichi、Yokota Yasuyuki、Ichii Takashi、Yoshida Norio、Nishi Naoya、Katakura Seiji、Imanishi Akihito、Fukui Ken-ichi、Sakka Tetsuo
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 45 Pages: 30504-30512

    • DOI

      10.1039/c7cp06948k

    • NAID

      120006545210

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Computational investigations of electronic structure modifications of ferrocene-terminated self-assembled monolayers: effects of electron donating/withdrawing functional groups attached on the ferrocene moiety2017

    • Author(s)
      Yokota Yasuyuki、Akiyama Sumito、Kaneda Yukio、Imanishi Akihito、Inagaki Kouji、Morikawa Yoshitada、Fukui Ken-ichi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 48 Pages: 32715-32722

    • DOI

      10.1039/c7cp07279a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interfacial Structural Investigations of Electric Double Layer Transistors Using Ionic Liquid: Relation between Microscopic Structures and Device Performances2017

    • Author(s)
      YOKOTA Yasuyuki、IMANISHI Akihito、UEMURA Takafumi、TAKEYA Jun、FUKUI Ken-ichi
    • Journal Title

      Hyomen Kagaku

      Volume: 38 Issue: 8 Pages: 419-424

    • DOI

      10.1380/jsssj.38.419

    • NAID

      130005997151

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電気二重層の分子スケールでの実像に迫る2017

    • Author(s)
      福井 賢一
    • Journal Title

      Accounts of Materials & Surface Research

      Volume: 2 Pages: 110-117

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Density Functional Theory Investigations of Ferrocene-Terminated Self-Assembled Monolayers: Electronic State Changes Induced by Electric Dipole Field of Coadsorbed Species2016

    • Author(s)
      Y. Yokota, S. Akiyama, Y. Kaneda, A. Imanishi, K. Inagaki, Y. Morikawa, and K. Fukui
    • Journal Title

      J. Phys. Chem. C, in press.

      Volume: in press. Issue: 16 Pages: 8684-8692

    • DOI

      10.1021/acs.jpcc.6b00812

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] グラファイト電極の電位および電解質に依存した電気二重層界面の水和ネットワークと界面エネルギーの局所評価2016

    • Author(s)
      福井 賢一
    • Journal Title

      生産と技術

      Volume: 68 Pages: 61-63

    • NAID

      40020702628

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電気化学界面の高分解能画像化と電位に応じた電気二重層の変化2016

    • Author(s)
      福井 賢一
    • Journal Title

      顕微鏡

      Volume: 51 Pages: 83-87

    • NAID

      130007695976

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Resolution Imaging of Electrode and Analyses of Potential-Dependent Structuring of Interfacial Liquid Forming Electric Double Layer2016

    • Author(s)
      福井賢一
    • Journal Title

      Hyomen Kagaku

      Volume: 37 Issue: 10 Pages: 488-493

    • DOI

      10.1380/jsssj.37.488

    • NAID

      130005432714

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 減衰全反射遠紫外分光法を用いた金属イオンを含むイオン液体の電子状態解析2019

    • Author(s)
      今井雅也,田邉一郎,福井賢一
    • Organizer
      日本分光学会紫外フロンティア分光部会第1回講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気化学環境下におけるイオン液体の電子励起スペクトル2019

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 今井雅也, 福井賢一
    • Organizer
      2019年第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 減衰全反射法を利用した電極界面イオン液体の電子励起スペクトル測定2019

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 今井雅也, 福井賢一
    • Organizer
      第99回日本化学会春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 遠紫外表面プラズモン共鳴センサーの表面選択性2018

    • Author(s)
      田邉一郎, 清水武蔵, 福井賢一
    • Organizer
      平成30年度 日本分光学会年次講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Diffusion of Mg2+ Ions at Interfacial Ionic Liquid on Au Electrode Analyzed by AR-XPS and EC-XPS2018

    • Author(s)
      Akihiro Takahashi, Chiaki Katayama, Taiki Sato, Saeyun Kim, Akihito Imanishi, Ken-ichi Fukui
    • Organizer
      69th Annual Meeting of the International Sociery of Electrochemistry (ISE 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 遠紫外プラズモン共鳴センサーの表面敏感性の検討2018

    • Author(s)
      田邉一郎, 清水武蔵, 川端陸斗, 福井賢一
    • Organizer
      第12回分子化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Potential-Dependent Electric Double Layer Structures at Liquid / Electrode Interfaces by Electrochemical Frequency Modulation AFM2018

    • Author(s)
      Potential-Dependent Electric Double Layer Structures at Liquid / Electrode Interfaces by Electrochemical Frequency Modulation AFM
    • Organizer
      The 21st International Conference on Non-contact Atomic Force Microscopy (NC-AFM2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diffusion Behavior of Mg2+ Ions at Interfacial Ionic Liquid on Metal Electrode Analyzed by Electrochemical XPS2018

    • Author(s)
      Akihiro Takahashi, Chiaki Katayama, Taiki Sato, Saeyun Kim, Ichiro Tanabe, Akihito Imanishi, Ken-ichi Fukui
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local analysis on structuring of interfacial IL close to sub-μm holes on graphite electrode by FM-AFM2018

    • Author(s)
      Ryotaro Namba , Ichiro Tanabe, Ken-ichi Fukui
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 周波数変調 AFM によるグラファイト電極上に作製したサブμm穴構造付近における界面イオン液体の構造化の評価2018

    • Author(s)
      難波亮太郎,田邊一郎,福井賢一
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 角度分解 XPS測定による Mg 2+ の濃度勾配をもつ イオン液体薄膜中での拡散挙動評価2018

    • Author(s)
      片山千滉,中条文哉,田邉一郎, 今西哲士, 福井賢一
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光電子分光による金属電極上のイオン液体中の金属イオン拡散挙動の新規解析手法2018

    • Author(s)
      高橋尭広,片山千滉,佐藤大輝,田邉一郎,今西哲士,福井賢一
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光電子分光によるイオン液体/電極界面での溶質イオン挙動の解析2018

    • Author(s)
      福井賢一
    • Organizer
      第10回 岩澤コンファレンス~サステイナブル社会のための最先端触媒化学・表面科学~
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Structuring of interfacial liquid relevant for electrochemical devices2018

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      International Joint Symposium: "Interfacial Science for Green Innovation"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Analysis on diffusion behavior of Mg2+ solute in ionic liquid thin film on Au(111) using angle-resolved XPS2018

    • Author(s)
      Chiaki Katayama, Fumiya Chujo, Akihito Imanishi, Ken-ichi Fukui
    • Organizer
      5th Kansai Nanoscience and Nanotechnology International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potential-dependent structure and dynamics of ionic liquids at C60 electrode interface analyzed by MD simulation2018

    • Author(s)
      Taiki Sato, Hiroo Miyamoto, Ichiro Tanabe, Kouji Inagaki, Yoshitada Morikawa, Ken-ichi Fukui
    • Organizer
      5th Kansai Nanoscience and Nanotechnology International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Structure of Ionic Liquid at Organic Semiconductor Interfaces Analyzed by Electrochemical Frequency Modulation AFM2018

    • Author(s)
      Hiroaki Nato, Taiki Sato, Hiroo Miyamoto, Ken-ichi Bando, Ichiro Tanabe, Junichi Takeya, Ken-ichi Fukui
    • Organizer
      5th Kansai Nanoscience and Nanotechnology International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reversible Potential Response of Imidazolium-based Ionic Liquid at IL/metal Electrode Interface Observed by ATR Far-UV Spectroscopy2018

    • Author(s)
      Aki Suyama, Ichiro Tanabe, Ken-ichi Fukui
    • Organizer
      5th Kansai Nanoscience and Nanotechnology International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 減衰全反射遠紫外分光法を利用したイオン液体の電子励起スペクトル測定と電位依存性2018

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 福井賢一
    • Organizer
      第65回応用物学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電気二重層有機FETの界面に生じるキャリア - イオン液体間相互作用の解析2018

    • Author(s)
      岡上大二朗, 大野桜子,阪本康太,名藤広晃,佐藤大輝,田邉一郎,今西哲士,竹谷純一,福井賢一
    • Organizer
      第65回応用物学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Structuring, Dynamics, Electric Double Layer Formation of Interfacial Ionic Liquid Faced to Electrode Surfaces2017

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      Osaka University-Strasbourg University Joint Symposium on “Diverse Facets of Chemistry”
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] How the Electrolyte Responds to the Electrode Potential ? ~EC-FM-AFM and MD Analyses~2017

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      Electrochemical Materials Workshop
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 減衰全反射紫外分光法による電極界面でのイオン液体の電子状態研究2017

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 福井賢一
    • Organizer
      平成29年度 日本分光学会年次講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local Structure of Electric Double Layer of Electrolytes Analyzed by Electrochemical Frequency Modulation AFM and MD Calculation2017

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      Probing Solid-liquid Interfaces at the Atomic Scale (PSINAS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Attenuated Total Reflectance Far Ultraviolet (EC-ATR-FUV) Spectroscopy Applied for Interfacial Ionic Liquids2017

    • Author(s)
      Ichiro Tanabe, Aki Suyama, Ken-ichi Fukui
    • Organizer
      Probing Solid-liquid Interfaces at the Atomic Scale (PSINAS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlation between Interfacial Career Mobility and Local Structure of Ionic Liquid / Rubrene Interface in Organic FET device2017

    • Author(s)
      Daijiro Okaue, Sakurako Ono, Hiroaki Nato, Kouta Sakamoto, Ichiro Tanabe, Jun Takeya, Ken-ichi Fukui
    • Organizer
      Probing Solid-liquid Interfaces at the Atomic Scale (PSINAS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potential Dependent Structure of Interfacial Ionic Liquids at Organic Semiconductor Surfaces Analyzed by MD Calculations2017

    • Author(s)
      Taiki Sato, Hiroo Miyamoto, Ichiro Tanabe, Koji Inagaki, Yoshitada Morikawa, Ken-ichi Fukui
    • Organizer
      Probing Solid-liquid Interfaces at the Atomic Scale (PSINAS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrode Potential Dependence of ATR-FUV Spectra of Imidazolium-Based Ionic Liquids at the Interface2017

    • Author(s)
      Aki Suyama, Ichiro Tanabe, Ken-ichi Fukui
    • Organizer
      Probing Solid-liquid Interfaces at the Atomic Scale (PSINAS)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フラーレン単結晶電極と接する界面イオン液体の分子動力学法による局所構造解析と電位応答2017

    • Author(s)
      佐藤大輝,宮本洋雄,田邉一郎,稲垣耕司,森川良忠,福井賢一
    • Organizer
      第37回表面科学学術講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] イオン液体を用いた電気二重層FETのキャリア移動度と界面構造との相関2017

    • Author(s)
      阪本康太, 大野桜子, 岡上大二 朗, 名藤広晃, 佐藤大輝, 今西哲士, 田邊一郎, 竹谷純一, 福井賢一
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電解質イオンと電位に依存した電極界面の水分子ダイナミクスの分子動力学計算による解析2017

    • Author(s)
      今井 雅也,橫田 泰之,田邉 一郎,稲垣 耕司,森川 良忠,福井 賢一
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 遠紫外-深紫外分光法による電極界面イオン液体の電子状態研究2017

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 福井賢一
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フラーレン単結晶電極の電位に依存した界面イオン液体の局所構造と運動性のMD計算による解析2017

    • Author(s)
      佐藤大輝, 宮本洋雄, 田邉一郎, 稲垣耕司, 森川良忠, 福井賢一
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Potential-Dependent Local Structure and Dynamics of Electric Double Layer at Ionic Liquid / Electrode Interfaces Analyzed by Electrochemical FM-AFM and MD calculation2017

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      International Functional Nanomaterials and Nanodevice Conference 2017 (Nanomat2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Influence of Nano-structuring of Electrode on Solvation layer of Ionic Liquid Studied by Impedance Spectroscopy2017

    • Author(s)
      Akihito Imanishi, Nao Miyaguchi, Koji Takagi, Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical far- and deep-ultraviolet spectroscopy applied for interfacial ionic liquids2017

    • Author(s)
      Ichiro Tanabe, Aki Suyama, Taiki Sato and Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlation between Interfacial Career Mobility and Local Structure of Ionic Liquid / Rubrene Interface in Organic FET Device2017

    • Author(s)
      Daijiro Okaue, Sakurako Ono, Kota Sakamoto, Hiroaki Nato, Taiki Sato, Ichiro Tanabe, Akihito Imanishi, Jun Takeya, Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Diffusion of magnesium ion in ionic liquid thin film on Au(111) analyzed by angle resolved X-ray photoelectron spectroscopy2017

    • Author(s)
      Chiaki Katayama, Fumiya Chujo, Akihito Imanishi and Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potential Dependent Structure of Interfacial Ionic Liquid at C60 Electrode and its Response Analyzed by MD Simulation2017

    • Author(s)
      Taiki Sato, Hiroo Miyamoto, Ichiro Tanabe, Koji Inagaki, Yoshitada Morikawa and Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reversible behavior of interfacial ionic liquid depending on the potential of Pt electrode observed by ATR-far UV spectroscopy2017

    • Author(s)
      Aki Suyama, Ichiro Tanabe and Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Structure Analysis of Ionic Liquid / Organic Semiconductor Interfaces Using Electrocgemical Frequency Modulation AFM2017

    • Author(s)
      Hiroaki Nato, Taiki Sato, Hiroo Miyamoto, Ken Ken-ichi Bando, Ichiro Tanabe, Junichi Takeya, Ken-ichi Fukui
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electronic States of Interfacial Ionic Liquids Investigated by Electrochemical Far- and Deep-Ultraviolet Spectroscopy2017

    • Author(s)
      I. Tanabe, A. Suyama, T. Sato and K. Fukui
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Correlation between the Interfacial Structure and Hole Mobility for Electric Double Layer FET using Ionic Liquid2017

    • Author(s)
      Daijiro Okaue, Sakuroko Ono, Ken-ichi Bando, Kouta Sakamoto, Hiroaki Nato, Hiroo Miyamoto, Taiki Sato, Yasuyuki Yokota, Jun Takeya, and Ken-ichi Fukui
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノ細孔内イオン液体中における金属イオンの挙動とX線還元による金属微粒子形成2017

    • Author(s)
      小田奈緒子, 紀本千智, 有村孝, 津田哲哉, 桑畑進, 福井賢一, 今西哲士
    • Organizer
      第8回イオン液体討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 減衰全反射法を利用した電極界面イオン液体の遠紫外分光研究2017

    • Author(s)
      田邉一郎, 寿山安紀, 佐藤大輝, 福井賢一
    • Organizer
      第8回イオン液体討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local Structure and Dynamics of Electric Double Layer at Ionic Liquid / Electrode Interfaces Analyzed by Electrochemical FM-AFM and MD calculation2017

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      655. WE-Heraeus-Seminar on Surfaces and Interfaces of Ionic Liquids
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Far- and Deep-Ultraviolet Spectroscopy of Ionic Liquids under Electrochemical Environments2017

    • Author(s)
      Ichiro Tanabe, Aki Suyama, Ken-ichi Fukui
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai- (SSSN-Kansai)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microscopic Analysis of Electric Double Layer Formed at Aqueous Solution / Graphite Electrode Interfaces by Molecular Dynamics Simulation2017

    • Author(s)
      Masaya Imai, Yasuyuki Yokota, Ichiro Tanabe, Koji Inagaki, Yoshitada Morikawa, Ken-ichi Fukui
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai- (SSSN-Kansai)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Ionic Liquid Ultrathin Films and Their Interfacial Structure Analyses, Akihiro Takahashi, Fumiya Chujo2017

    • Author(s)
      Ichiro Tanabe, Akihito Imanishi and Ken-ichi Fukui
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai- (SSSN-Kansai)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical FM-AFM Analysis of Local Structural Change of Ionic Liquid / Organic Semiconductor Interfaces2017

    • Author(s)
      Sakamoto Kota, Imanishi Akihito, Tanabe Ichiro, Takeya Jun, Fukui Ken-ichi
    • Organizer
      Symposium on Surface Science & Nanotechnology -25th Anniversary of SSSJ Kansai- (SSSN-Kansai)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン液体種に強く依存した界面構造形成と電気二重層FETのキャリア移動度の相関2017

    • Author(s)
      大野 桜子,名藤 広晃,阪本 康太,今西 哲士,田邉 一郎,竹谷 純一,福井 賢一
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気化学-減衰全反射-紫外分光測定系による電極と界面を形成するイオン液体の電子状態研究2017

    • Author(s)
      田邉 一郎, 寿山 安紀, 福井 賢一
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電極界面に生じる電気二重層の局所解析手法の開拓とイオン液体界面への応用2017

    • Author(s)
      福井 賢一
    • Organizer
      日本化学会第97春季年会 学術賞受賞記念講演
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ナノ細孔内のイオン液体を反応場としたX線還元金属微粒子形成の金属イオン種依存性2017

    • Author(s)
      小田 奈緒子, 紀本 千智, 有村 孝, 津田 哲哉, 桑畑 進, 福井 賢一, 今西 哲士
    • Organizer
      日本化学会第97春季年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 減衰全反射型紫外分光法による電極界面イオン液体の電子状態解析2017

    • Author(s)
      田邉 一郎, 寿山 安紀, 福井 賢一
    • Organizer
      電気化学会第84回大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Au電極表面上の規則的ナノ構造が界面イオン液体の分子挙動に与える影響2017

    • Author(s)
      宮口 奈穂, 高木 康司, 福井 賢一, 今西 哲士
    • Organizer
      電気化学会第84回大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structuring, Dynamics, Electric Double Layer Formation at Ionic Liquid / Electrode Interfaces Analyzed by Electrochemical Frequency Modulation AFM and MD Calculation2016

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      Japan-Finland Research Exchange Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electronic Absorption Spectra of Imidazolium-Based Ionic Liquids studied by Far- Ultraviolet Spectroscopy and Quantum Chemical Calculation2016

    • Author(s)
      Ichiro Tanabe, Yukihiro Ozaki, Ken-ichi Fukui
    • Organizer
      Japan-Finland Research Exchange Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Analysis of Electric Double Layer Formed at Aqueous Solution / Graphite Electrode Interface by Molecular Dynamics Simulation2016

    • Author(s)
      Masaya Imai, Yasuyuki Yokota, Koji Inagaki, Yoshitada Morikawa, Ken-ichi Fukui
    • Organizer
      Japan-Finland Research Exchange Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Potential-dependent Hydration Structures at Aqueous Solution/Graphite Interfaces Observed by EC-FM-AFM2016

    • Author(s)
      Kosuke Suzuki, Toru Utsunomiya, Yasuyuki Yokota, Ken-ichi Fukui
    • Organizer
      Japan-Finland Research Exchange Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Li Ion Addition on the Local Structure of Interfacial Ionic Liquid by Combined AFM Measurement2016

    • Author(s)
      Toru Mine, Noriki Osaka, Yasuyuki Yokota, Ken-ichi Fukui
    • Organizer
      Japan-Finland Research Exchange Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 規則的にナノ構造化されたAu電極との界面におけるイオン液体の分子挙動2016

    • Author(s)
      宮口 奈穂,高木 康司,福井 賢一,今西 哲士
    • Organizer
      第5回JACI / GSCシンポジウム
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気化学FM-AFMの開発と電気二重層界面解析への応用2016

    • Author(s)
      福井賢一,橫田泰之
    • Organizer
      本学術振興会ナノプローブテクノロジー第167委員会 第83回研究会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Structuring, Dynamics, Electric Double Layer Formation at Ionic Liquid / Electrode Interfaces Analyzed by Electrochemical Frequency Modulation AFM and MD Calculation2016

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      20th International Vacuum Congress (IVC-20)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電極との界面でイオン液体が形成する電気二重層の実験および計算科学的解析2016

    • Author(s)
      福井賢一
    • Organizer
      応用物理学会M&BE 新分野開拓研究会2016「有機イオントロニクスの進展」
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Combined AFM and MD Simulation Studies of Electric Double Layer OFET Based on Ionic Liquid / Rubrene Single Crystal Interface2016

    • Author(s)
      Yasuyuki Yokota, Hisaya Hara, Yusuke Morino, Ken-ichi Bando, Sakurako Ono, Hiroo Miyamoto, Akihito Imanishi, Kouji Inagaki, Yoshitada Morikawa, Yugo Okada, Hiroyuki Matsui, Takafumi Uemura, Jun Takeya, and Ken-ichi Fukui
    • Organizer
      KJF-ICOMEP 2016
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電解質水溶液/グラファイト電極界面に形成される電位および電解質に依存した電気二重層構造のMD 計算による解析2016

    • Author(s)
      今井 雅也, 横田 泰之, 田邉一郎, 稲垣 耕司, 森川 良忠, 福井 賢一
    • Organizer
      第10回分子科学討論会2016
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナノ細孔内イオン液体を反応場としたX線還元による金属ナノ粒子形成2016

    • Author(s)
      小田 奈緒子, 紀本 千智, 有村 孝, 津田 哲哉, 桑畑 進, 福井 賢一, 今西 哲士
    • Organizer
      第10回分子科学討論会2016
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気二重層トランジスタの微視的理解に向けた周波数変調AFM及び古典MD計算によるイオン液体/有機半導体界面の構造評価2016

    • Author(s)
      横田 泰之, 原 援又, 森野 裕介, 坂東 賢一, 大野 桜子, 宮本 洋雄, 今西 哲士, 稲垣 耕司, 森川 良忠, 岡田 悠悟, 松井 弘之, 植村 隆文, 竹谷 純一, 福井 賢一
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] グラファイト電極との界面でイオン液体が形成する電気二重層の構造およびダイナミクスのMD計算による解析2016

    • Author(s)
      宮本 洋雄、横田 泰之、今西 哲士、稲垣 耕司、森川 良忠、福井 賢一
    • Organizer
      第118回触媒討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気化学FM-AFMおよびMD計算による電気二重層を形成する液体側の局所構造解析2016

    • Author(s)
      福井賢一
    • Organizer
      16-1高分子表面研究会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 規則的ナノ構造をもつAu電極と界面を造るイオン液体の電気化学挙動解析, 宮口奈穂2016

    • Author(s)
      高木康司,福井賢一,今西哲士
    • Organizer
      第7回イオン液体討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気化学FM-AFMおよび分子動力学計算を用いた電気二重層を形成する液体の電位に依存した構造化の解析2016

    • Author(s)
      福井賢一
    • Organizer
      日本顕微鏡学会走査型プローブ顕微鏡分科会「液中SPMの新展開 - 広がる応用分野と新技術 -」
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 電気化学周波数変調AFMおよび分子動力学計算による電気二重層を形成する液体側の局所構造解析2016

    • Author(s)
      福井賢一
    • Organizer
      第36回表面科学学術講演会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] グラファイト電極の電位,電解質イオン種に応じた水溶液電気二重層の局所構造とダイナミクスの分子動力学解析2016

    • Author(s)
      今井雅也, 横田泰之, 田邉一郎, 稲垣耕司, 森川良忠, 福井賢一
    • Organizer
      第36回表面科学学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 実験および計算科学的解析によるイオン液体電気二重層界面の描像2016

    • Author(s)
      福井賢一
    • Organizer
      第8回岩澤コンファレンス-サステイナブル社会のための最先端触媒化学・表面化学-
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Structuring, Dynamics, and Electric Double Layer Formation of Interfacial Ionic Liquid Faced to Various Electrode Analyzed by Electrochemical Frequency Modulation AFM and MD Calculation2016

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      9th Singapole International Chemistry Conference
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Potential Dependent Local Structure of Electric Double Layer at Ionic Liquid / Electrode Interfaces Analyzed by Electrochemical FM-AFM and MD calculation2016

    • Author(s)
      Ken-ichi Fukui
    • Organizer
      24th International Colloquium on Scanning Probe Microscopy (ICSPM24)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Local Structure Analysis of Ionic Liquid / Organic Semiconductor interfaces by Electrochemical FM-AFM2016

    • Author(s)
      Kota Sakamoto, Akihito Imanishi, Ichiro Tanabe, Jun Takeya, Ken-ichi Fukui
    • Organizer
      4th Kansai Nanoscience and Nanotechnology and 12th Handai Nanoscience and nanotechnology International Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Metal Nanoparticle Formation in Mesopore Material filled with Ionic Liquid by X-ray Induced Reduction2016

    • Author(s)
      Naoko Oda, Chisato Kimoto, Takashi Arimura, Tetsuya Tsuda, Susumu Kuwabata, Ken-ichi Fukui, Akihito Imanishi
    • Organizer
      4th Kansai Nanoscience and Nanotechnology and 12th Handai Nanoscience and nanotechnology International Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Ionic Liquid Ultrathin Film by Sequential Deposition Method and Analyses of the Interfacial Structure2016

    • Author(s)
      Akihiro Takahashi, Fumiya Chujo, Ichiro Tanabe , Akihito Imanishi and Ken-ichi Fukui
    • Organizer
      4th Kansai Nanoscience and Nanotechnology and 12th Handai Nanoscience and nanotechnology International Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation into Ionic Liquids-Charged Electrode Interfacial Structure by Atomic Force Microscopy2016

    • Author(s)
      Toru Mine, Norio Osaka, Yasuyuki Yokota, Ken-ichi Fukui
    • Organizer
      4th Kansai Nanoscience and Nanotechnology and 12th Handai Nanoscience and nanotechnology International Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] Compendium of Surface and Interface Analysis2018

    • Author(s)
      Toru Utsunomiya, Yasuyuki Yokota, Ken-ichi Fukui
    • Total Pages
      853
    • Publisher
      Springer
    • ISBN
      9789811061561
    • Related Report
      2018 Annual Research Report
  • [Book] “Electrochemical Atomic Force Microscopy” in “Compendium of Surface and Interface Analysis”2018

    • Author(s)
      Toru Utsunomiya, Yasuyuki Yokota, Ken-ichi Fukui
    • Total Pages
      6
    • Publisher
      Springer
    • ISBN
      9789811061554
    • Related Report
      2017 Annual Research Report
  • [Remarks] Publication list of Fukui Lab.

    • URL

      http://www.chem.es.osaka-u.ac.jp/surf/fukui_pub.html#Review

    • Related Report
      2018 Annual Research Report
  • [Remarks] Recent Achievements of Fukui Lab.

    • URL

      https://www.facebook.com/Recent-Achievements-of-Fukui-Lab-SurfInterface-Chem-Group-in-Osaka-Univ-792442370830639/

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 大阪大学基礎工 福井研究室

    • URL

      http://www.chem.es.osaka-u.ac.jp/surf/

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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