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Efficient and precise fabrication of photoelectrode of dye-sensitized solar cell by gas-phase deposition of nanoparticles and droplets

Research Project

Project/Area Number 16H04553
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionHiroshima University

Principal Investigator

Shimada Manabu  広島大学, 工学研究科, 教授 (70178953)

Co-Investigator(Kenkyū-buntansha) 久保 優  広島大学, 工学研究科, 助教 (00633752)
Research Collaborator ISOMOTO yoshinori  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2018: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2016: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywordsナノ材料 / 機能性複合薄膜 / 多孔体 / エアロゾル / プラズマ反応合成
Outline of Final Research Achievements

A novel manufacturing method of thin films for electrodes of dye-sensitized solar cells was proposed, and its usefulness was investigated experimentally. In this method, nanoparticles were generated in gas and successively deposited onto a substrate to form a uniform titanium dioxide layer that composed the film. After various properties and deposition conditions for the nanoparticles were tested, the conditions were found under which films with sufficient thickness, flatness, and uniformity could be obtained. It was demonstrated that a battery unit using the films exhibited a power generation performance by the irraditation of sunlight.

Academic Significance and Societal Importance of the Research Achievements

本研究の代表的な学術的意義は、粒子の性状や堆積のさせ方を、粒子の気中での発生と輸送に関するこれまでの学術的知見をふまえて吟味することで、望ましい電極用薄膜を得ようとした点である。社会への波及効果として、色素増感太陽電池の研究開発は日本が世界をリードしており、今後実用化に向けた取り組みが進むなか、本研究の成果は我が国の国際競争力確保の観点から、貢献の大きい技術のひとつになると考える。さらに、ここで開発した複数のナノ物質を同時に堆積させる技術は、電極用の薄膜に留まらず、異物質のシナジー効果を期待する複合材料の製造技術一般にも、新たな選択肢を加えるであろうと考えている。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (46 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (36 results) (of which Int'l Joint Research: 15 results,  Invited: 3 results) Book (2 results)

  • [Int'l Joint Research] Institut Teknologi Sepuluh Nopember(インドネシア)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Institut Teknologi Sepuluh Nopember(インドネシア)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Facile fabrication of HKUST-1 nanocomposites incorporating Fe3O4 and TiO2 nanoparticles by a spray-assisted synthetic process and their dye adsorption performances2019

    • Author(s)
      Kubo Masaru、Moriyama Reina、Shimada Manabu
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 280 Pages: 227-235

    • DOI

      10.1016/j.micromeso.2019.02.010

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Usefulness of myeloperoxidase as a biomarker for the ranking of pulmonary toxicity of nanomaterials2018

    • Author(s)
      Tomonaga Taisuke、Izumi Hiroto、Yoshiura Yukiko、Myojo Toshihiko、Oyabu Takako、Lee Byeong-Woo、Okada Takami、Marui Takashi、Wang Ke-Yong、Kubo Masaru、Shimada Manabu、Noguchi Shingo、Nishida Chinatsu、Yatera Kazuhiro、Morimoto Yasuo
    • Journal Title

      Particle and Fibre Toxicology

      Volume: 15 Issue: 1 Pages: 41-41

    • DOI

      10.1186/s12989-018-0277-x

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of annealing temperature on the photocatalytic activity of Ag-TiO2 nanocomposite films by one-step gas-phase deposition2018

    • Author(s)
      Kusdianto K.、Jiang Dianping、Kubo Masaru、Shimada Manabu
    • Journal Title

      Materials Research Bulletin

      Volume: 97 Pages: 497-505

    • DOI

      10.1016/j.materresbull.2017.08.062

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fabrication of TiO2-Ag nanocomposite thin films via one-step gas-phase deposition2017

    • Author(s)
      Kusdianto K.、Jiang Dianping、Kubo Masaru、Shimada Manabu
    • Journal Title

      Ceramics International

      Volume: 43 Issue: 6 Pages: 5351-5355

    • DOI

      10.1016/j.ceramint.2017.01.009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preparation of nanoparticle-embedded thin films by simultaneous feeding of gaseous and solid raw materials in plasma-enhanced chemical vapor deposition process2017

    • Author(s)
      Kubo Masaru、Taguchi Tomoya、Shimada Manabu
    • Journal Title

      Thin Solid Films

      Volume: 632 Pages: 55-65

    • DOI

      10.1016/j.tsf.2017.04.042

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biopersistence of NiO and TiO2 Nanoparticles Following Intratracheal Instillation and Inhalation2017

    • Author(s)
      Oyabu Takako、Myojo Toshihiko、Lee Byeong-Woo、Okada Takami、Izumi Hiroto、Yoshiura Yukiko、Tomonaga Taisuke、Li Yun-Shan、Kawai Kazuaki、Shimada Manabu、Kubo Masaru、Yamamoto Kazuhiro、Kawaguchi Kenji、Sasaki Takeshi、Morimoto Yasuo
    • Journal Title

      Int J Mol Sci

      Volume: 18 Issue: 12 Pages: 2757-2757

    • DOI

      10.3390/ijms18122757

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Development of Polymer Nanocoating Process for CNTs Using In-flight PECVD2019

    • Author(s)
      Hemanth Lakshmipura_R.、Fukumoto Yoshihiko、Kubo Masaru、Shimada Manabu
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 噴霧合成プロセスにおけるHKUST-1MOFの生成効率の向上2019

    • Author(s)
      久保 優、石村 元義、島田 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] エアロゾル粒子堆積法による色素増感太陽電池の光電極膜の作製と評価2018

    • Author(s)
      淵 恭彦、姜 殿平、久保 優、島田 学
    • Organizer
      第35回エアロゾル科学・技術研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 気固原料同時供給PECVD法による3成分系複合薄膜の作製2018

    • Author(s)
      島田一雲、久保 優、島田 学
    • Organizer
      第35回エアロゾル科学・技術研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高効率な多孔性配位高分子HKUST-1の噴霧合成プロセスの開発2018

    • Author(s)
      久保 優、石村元義、島田 学
    • Organizer
      第35回エアロゾル科学・技術研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ粒子懸濁液の噴霧乾燥で調製したナノポーラス凝集体の構造に及ぼす粒子性状の影響2018

    • Author(s)
      林戸洋人、久保 優、島田 学
    • Organizer
      第35回エアロゾル科学・技術研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of Nanoparticle-embedded Composite Films by Plasma-enhanced CVD Process Using Gaseous and Particulate Raw Materials2018

    • Author(s)
      Shimada M., M. Kubo, Y. Shigematsu, I. Shimada
    • Organizer
      10th International Aerosol Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Loading Concentration on the Photocatalytic Activity of Ag-TiO2 Nanocomposite Films Fabricated by One-Step Gas-Phase Deposition2018

    • Author(s)
      Jiang, D., K. Kusdianto, M. Kubo, M. Shimada
    • Organizer
      10th International Aerosol Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polymer and Metal Oxides Coating of Multiwalled Carbon Nanotubes by Spray-Assisted Plasma-Enhanced Chemical Vapor Deposition2018

    • Author(s)
      Hemanth, L. R., K. Nishihara, M. Kubo, M. Shimada, K. Kusdianto
    • Organizer
      10th International Aerosol Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Facile Synthesis of Magnetic Metal-Organic Framework Nanocomposites by Spray-Assisted Synthesis2018

    • Author(s)
      Kubo, M. M. Shimada
    • Organizer
      10th International Aerosol Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ag粒子とTiO2粒子の堆積で作製した複合薄膜の可視光照射下での光触媒活性2018

    • Author(s)
      正木 佑弥、姜 殿平、久保 優、島田 学
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 噴霧乾燥法により調製したゼオライト凝集体のSr2+吸着2018

    • Author(s)
      松谷 史矢、久保 優、島田 学
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 噴霧合成プロセスを用いた多孔性配位高分子UiO-66の合成2018

    • Author(s)
      三好 祐資、久保 優、島田 学
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Generation and Processing of Fine Particles in Gas-phase Environment2018

    • Author(s)
      Shimada M.
    • Organizer
      1st International Symposium of Indonesian Chemical Engineering (ISIChem) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photocatalytic Activity of ZnO-Ag Nanocomposites Prepared by a One-Step Process Using Flame Pyrolysis2018

    • Author(s)
      Kusdianto, K., W. Widiyastuti, M. Shimada, T. Nurtono, S. Machmudah, S. Winardi
    • Organizer
      1st International Symposium of Indonesian Chemical Engineering (ISIChem) 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of Tungsten Oxide on Lungs Following Inhalation2018

    • Author(s)
      Marui, T., Y. Yoshiura, T. Tomonaga, H. Izumi, Y. Fujisawa, C. Nishida, K. Yatera, M. Kubo, M. Shimada, Y. Morimoto
    • Organizer
      23rd Congress of the Asian Pacific Society of Respirology (APSR 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and Evaluation of Photocatalytic Ag-TiO2 Nanoparticulate Films2018

    • Author(s)
      Dianping Jiang, K. Kusdianto, Masaru Kubo, Manabu Shimada
    • Organizer
      International Workshop on Nanodevice Technologies 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Polymer Coated Multiwalled Carbon Nanotubes by Spray-Assisted Plasma-Enhanced Chemical Vapor Deposition2018

    • Author(s)
      Lakshmipura R. Hemanth, Keita Nishihara, Masaru Kubo, Manabu Shimada
    • Organizer
      International Workshop on Nanodevice Technologies 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PECVD法による色素増感太陽電池の光電極膜の作製と評価2018

    • Author(s)
      淵 恭彦、田井悠介、石原萌実、久保 優、島田 学
    • Organizer
      第20回化学工学会学生発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 気相堆積で作製したAg-TiO2薄膜の可視光下における光触媒活性の評価2018

    • Author(s)
      正木 佑弥、姜 殿平、石原萌実、久保 優、島田 学、K. Kusdianto
    • Organizer
      第20回化学工学会学生発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 気相浮遊コーティングプロセスによるポリマー被覆カーボンナノチューブの調製2018

    • Author(s)
      島田 学、西原 啓太、Hemanth L. R.、久保 優、K. Kusdianto
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Surface coating of carbon nanotubes by aerosol process with plasma enhanced chemical vapor deposition2017

    • Author(s)
      M. Shimada, M. Kubo, K. Kusdianto
    • Organizer
      化学工学会第82年会 [International Symposium] Reaction Engineering of CVD: iCVD and Emerging Processes, Applications, and Fundamental Understanding
    • Place of Presentation
      芝浦工業大学(東京都江東区)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Ag-TiO2 nanocomposite films via one-step gas-phase deposition and their characterizations after heat treatment processes2017

    • Author(s)
      K. Kusdianto, D. Jiang, M. Kubo, M. Shimada
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都江東区)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Controlling the Structure of Metal Oxide Layers Grown on Carbon Nanotubes Surface by In-flight Coating2017

    • Author(s)
      Kusdianto, K., M. Shimada, M. Kubo and H. Masuda
    • Organizer
      Asian Aerosol Conference AAC2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced Photocatalytic Activity of TiO2-Ag Nanocomposite Films Prepared via One-step Gas-phase Deposition by Heat Treatment2017

    • Author(s)
      Jiang, D., K. Kusdianto, M. Kubo and M. Shimada
    • Organizer
      Asian Aerosol Conference AAC2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エアロゾル粒子の堆積によるAg/TiO2光触媒薄膜の作製と熱処理の影響評価2017

    • Author(s)
      姜 殿平、K. クスディアント、久保 優、島田 学
    • Organizer
      第34回エアロゾル科学・技術研究討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 浮遊コーティングプロセスでMWCNT上に形成したTiO2層の形態に及ぼす反応条件の影響2017

    • Author(s)
      福本 善彦、久保 優、K. Kusdianto、島田 学
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Estimation of Pulmonary Toxicity of Nanomaterials Following Subacute Inhalation2017

    • Author(s)
      Morimoto, Y., H. Izumi, Y. Yoshiura, Y. Fujisawa, T. Tomonaga, T. Oyabu, T. Okada, T. Myojo, M. Shimada and M. Kubo
    • Organizer
      European Aerosol Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 気相浮遊被覆法によるカーボンナノチューブのポリメタクリル酸メチルコーティング2017

    • Author(s)
      西原 啓太、Hemanth L. R.、久保 優、島田 学、K. Kusdianto
    • Organizer
      化学工学会中国四国支部大会 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Preparation of Photocatalytic TiO2-Ag Nanocomposite Thin Films by One-step Gas-phase Deposition2017

    • Author(s)
      D. Jiang, K. Kusdianto, M. Kubo, M. Shimada
    • Organizer
      International Workshop on Nanodevice Technologies 2017
    • Place of Presentation
      広島大学(広島県東広島市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Metal Oxide Layer on Multi-walled Carbon Nanotubes by in-flight Coating2017

    • Author(s)
      M. Kubo, K. Kusdianto, H. Masuda, and M. Shimada
    • Organizer
      International Workshop on Nanodevice Technologies 2017
    • Place of Presentation
      広島大学(広島県東広島市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エアロゾルナノ粒子堆積によって作製した多孔質TiO2薄膜の形態と空隙率に焼成が与える影響2016

    • Author(s)
      久保 優,萬谷 勇樹,島田 学
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 気固原料PECVD法による高アスペクト比粒子包埋膜の合成2016

    • Author(s)
      重松 祐紀,久保 優,島田 学
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Effect of heat treatments on the photocatalytic activity of Ag-TiO2 nanocomposite films prepared by a one-step gas-phase deposition process2016

    • Author(s)
      K. Kusdianto, D. Jiang, M. Kubo, M. Shimada
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 気固原料PECVD法で作製したナノ粒子複合薄膜の構造評価2016

    • Author(s)
      島田 学,久保 優,K. Kusdianto,田口 智也
    • Organizer
      第33回エアロゾル科学・技術研究討論会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2016-08-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] 噴霧乾燥法で調製したエアロゾル粒子の粒子径・気中質量濃度に与える一次粒子径の影響2016

    • Author(s)
      久保 優, 小紫 真友子,島田 学
    • Organizer
      第33回エアロゾル科学・技術研究討論会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2016-08-31
    • Related Report
      2016 Annual Research Report
  • [Book] プラズマCVDにおける成膜条件の最適化に向けた反応機構の理解とプロセス制御・成膜事例2018

    • Author(s)
      白藤立、松田彰久、市川幸美、林康明、加藤俊顕、鈴木弘郎、金子俊郎、篠原正典、猪原武士、柳生義人、大島多美子、川崎仁晴、山田英明、尾関和秀、山内智、髙洋志、村上彰一、東和文、寅丸雅光、牟田浩司、小島洋治、島田学、久保優
    • Total Pages
      328
    • Publisher
      サイエンス&テクノロジー株式会社
    • ISBN
      9784864281706
    • Related Report
      2018 Annual Research Report
  • [Book] 製品含有化学物質の リスク管理、情報伝達の効率化2017

    • Author(s)
      島田学、伊藤功、宇和川賢、永宮卓也、丸山裕子、吉川治彦、宮地繁樹、玉虫完次、栗原勇、光崎純、高平賢、高木正勝、腰越功、三浦伸彦、山本恒雄、緒方規矩也、小林史朗、松浦徹也、松山重倫、植松宏彰、新谷良英、森本泰夫、菅原秀一、西秀樹ほか31名
    • Total Pages
      654
    • Publisher
      技術情報協会
    • ISBN
      9784861046728
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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