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Development of Long Functional Nanofibers for Performance Improvement of Various Energy Storage Devices

Research Project

Project/Area Number 16H04558
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

Mukai Shin  北海道大学, 工学研究院, 教授 (70243045)

Co-Investigator(Kenkyū-buntansha) 荻野 勲  北海道大学, 工学研究院, 准教授 (60625581)
岩村 振一郎  北海道大学, 工学研究院, 助教 (10706873)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2018: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2016: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords反応・分離工学 / 触媒・化学プロセス / ナノ材料 / 電気二重層キャパシター / 燃料電池 / レドックスフロー電池
Outline of Final Research Achievements

Previously, we developed an original method to efficiently produce long carbon nanofibers at extremely high growth rates, the Liquid Pulse Injection Technique. In this study, we expanded this method to incorporate new functions into the nanofibers. Methods to cast the resulting fibers into sheets, and also methods to mold the fibers into monoliths were developed in order to make the use of such nanofibers easier. Sheets and monoliths of functional fibers obtained through the developed methods were used to improve the performance of energy storage devices such as electric double layer capacitors.

Academic Significance and Societal Importance of the Research Achievements

カーボンナノファイバーは高い導電性や機械的強度を有するために非常に着目されている材料であったが、製造コストが高く、長さが不十分である等のために用途が限定されていた。我々は独自の安価な製法によりカーボンナノファイバーの長尺化に成功していたが、本研究でさらに表面積を向上させる等、材料の機能を強化し、種々の用途、特にエネルギーの有効利用には欠かすことができない蓄電デバイスの性能向上に寄与できる材料の開発に成功した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (46 results)

All 2018 2017 2016

All Journal Article (13 results) (of which Peer Reviewed: 12 results,  Open Access: 2 results) Presentation (33 results) (of which Int'l Joint Research: 17 results,  Invited: 9 results)

  • [Journal Article] Efficient preparation of TiO 2 /C nanocomposite for electrode material through the liquid pulse injection technique2018

    • Author(s)
      Iwamura Shinichiroh、Fujita Kazuki、Iwashiro Ryo、Mukai Shin R.
    • Journal Title

      Materials Today Communications

      Volume: 14 Pages: 15-21

    • DOI

      10.1016/j.mtcomm.2017.12.002

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Critical Role of Bulk Density of Graphene Oxide in Tuning Its Defect Concentration through Microwave-driven Annealing2018

    • Author(s)
      Isao Ogino, Go Fukazawa, Shunsuke Kamatari, Shinichiroh Iwamura and Shin R Mukai
    • Journal Title

      Journal of Energy Chemistry

      Volume: 27 Issue: 5 Pages: 1468-1474

    • DOI

      10.1016/j.jechem.2017.09.010

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Esterification of Levulinic Acid with Ethanol Catalyzed by Sulfonated Carbon Catalysts: Promotional Effects of Additional Functional Groups2018

    • Author(s)
      Isao Ogino, Yukei Suzuki Shin R Mukai
    • Journal Title

      Catalysis Today

      Volume: 314 Pages: 62-69

    • DOI

      10.1016/j.cattod.2017.10.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cost-effective synthesis of activated carbons with high surface areas for electrodes of nonaqueous electric double layer capacitors2018

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Journal Title

      Separation and Purification Technology

      Volume: 印刷中 Pages: 174-180

    • DOI

      10.1016/j.seppur.2018.04.022

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Paper with a High Surface Area Prepared from Carbon Nanofibers Obtained through the Liquid Pulse Injection Technique2018

    • Author(s)
      Sakai Kazuki、Iwamura Shinichiroh、Sumida Ryo、Ogino Isao、Mukai Shin R.
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 1 Pages: 691-697

    • DOI

      10.1021/acsomega.7b01822

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Influence of the Porous Structure of the Cathode on the Discharge Capacity of Lithium-Air Batteries2017

    • Author(s)
      Sakai Kazuki、Iwamura Shinichiroh、Mukai Shin R.
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 164 Issue: 13 Pages: A3075-A3080

    • DOI

      10.1149/2.0791713jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PMMA-Templated Carbon Gel Monoliths with Independently Tunable Micro-, Meso-, and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 4 Pages: 315-323

    • DOI

      10.1252/jcej.16we313

    • NAID

      130006837170

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori Takeshi、Iwamura Shinichiroh、Ogino Isao、Mukai Shin R.
    • Journal Title

      Journal of Porous Materials

      Volume: 24 Issue: 6 Pages: 1497-1506

    • DOI

      10.1007/s10934-017-0389-y

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of Practical Activation Depth for Effective CO2 Activation Using PMMA-templated Carbons with a Tailorable Pore System of Meso- and Macropores2017

    • Author(s)
      Mori, Takeshi; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      J. Porous Mater.

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption of Phenol in Flow Systems by a Monolithic Carbon Cryogel with a Microhoneycomb Structure2016

    • Author(s)
      Yoshida, Seiichiro; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Adsorption

      Volume: 22 Issue: 8 Pages: 1051-1058

    • DOI

      10.1007/s10450-016-9799-4

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Method for Introducing Mesopores into Carbon Microhoneycombs Using Dextran2016

    • Author(s)
      Iwamura, Shinichiroh; Kitano, Kohei; Ogino, Isao; Mukai, Shin R.
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 231 Pages: 171-177

    • DOI

      10.1016/j.micromeso.2016.05.031

    • NAID

      120006502477

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the Mesopores of Carbon Supports on the CO Tolerance of Pt2Ru3 Polymer Electrolyte Fuel Cell Anode Catalyst2016

    • Author(s)
      Narischat, Napan; Takeguchi, Tatsuya; Mori, Takeshi; Iwamura, Shinichiroh; Ogino, Isao; Mukai, Shin R.; Ueda, Wataru
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 41 Issue: 31 Pages: 13697-13704

    • DOI

      10.1016/j.ijhydene.2016.05.272

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化グラフェン由来の多孔質炭素の合成2016

    • Author(s)
      荻野 勲,向井 紳
    • Journal Title

      ケミカルエンジニアリング

      Volume: 61 Pages: 327-331

    • Related Report
      2016 Annual Research Report
  • [Presentation] Rapid CO2 Activation of Carbon Gels Using Microwave Heating2018

    • Author(s)
      Shin R. Mukai, Daisuke Fukumitu, Shinicchiroh Iwamura, Masaaki Yoshikawa
    • Organizer
      Carbon 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Capacitor Performance Dependence on Substrate Pore Size of MnO2/Porous-carbon Nanocomposites2018

    • Author(s)
      Ryotaro Umedu, Shinichiroh Iwamura, Katsunobu Itsuki, K. Onishi, Isao Ogino, Shin R. Mukai
    • Organizer
      PBAST-8
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TiO2/Porous Carbon Nanocomposites Produced through the Vacuum Liquid Pulse CVD Technique for Supercapacitor Electrodes2018

    • Author(s)
      Shota Motohashi, Shinichiroh Iwamura, S. R. Mukai
    • Organizer
      PBAST-8
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Efficient Graphitization of Carbons Using Microwaves2018

    • Author(s)
      Shin R. Mukai
    • Organizer
      The 12th International Conference on Multi-functional Materials and Applications
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] LPI-CNFを用いたリチウム空気電池正極用シート状電極の開発2018

    • Author(s)
      住田 稜、牛島 啓太、坂井 一樹、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      化学工学会室蘭大会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] VLP-CVDを用いた種々の多孔体へのTiO2ナノ粒子の均一担持2018

    • Author(s)
      岩村 振一郎、本橋 翔大、向井 紳
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] リチウム空気電池正極における炭素構造と表面特性が電極特性へ与える影響2018

    • Author(s)
      岩村 振一郎、藤田 和樹、荻野 勲、向井 紳
    • Organizer
      第59回電池討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of Efficient CVD Techniques for Producing Carbon/Metal-oxide Nanocomposites2018

    • Author(s)
      岩村 振一郎、本橋 翔大、藤田 和樹、向井 紳
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] SiC/Cナノ複合体を原料とした新規多孔質炭素材料の開発2018

    • Author(s)
      楠 脩平、岩村 振一郎、向井 紳
    • Organizer
      第28回化学工学・粉体研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] リチウム空気電池正極用カーボンゲルの構造と表面特性の検討2018

    • Author(s)
      永石 新太郎、藤田 和樹、岩村 振一郎、向井 紳
    • Organizer
      第28回化学工学・粉体研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多孔質炭素内部へのTiO2ナノ粒子の均一担持に向けた新規CVD手法の開発2018

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 炭素ナノ複合材料の効率的製造プロセスの開発2018

    • Author(s)
      岩村 振一郎
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Addition of Micropores and Macropores into Carbon Gels by CO2 Activation and Polymer Templating2017

    • Author(s)
      Kazuki Sakai, Takeshi Mori, Takanori Tsuchiya, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Organizer
      Nagoya Univ. Tsinghua Univ. Toyota Motor Corp. Hokkaido Univ. Joint Symposium 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Simple and Inexpensive Method to Produce Activated Carbons with Ultra-high Surface Areas2017

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino and Shin R Mukai
    • Organizer
      Nagoya Univ. Tsinghua Univ. Toyota Motor Corp. Hokkaido Univ. Joint Symposium 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Efficient Graphitization of LPI-CNFs Using Microwaves2017

    • Author(s)
      Shunsuke Kamatari, Shinichiroh Iwamura, Isao Ogino, Shin R. Mukai
    • Organizer
      Carbon 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Esterification of Levulinic Acid with Ethanol Catalyzed by Sulfonated Carbon Catalysts: Promotional Effects of Additional Functional Groups2017

    • Author(s)
      Yukei Suzuki, Isao Ogino, Shin R. Mukai
    • Organizer
      APCChE2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Activated Carbons with Ultra-High Surface Areas from Phenolic Resins Using Conventional Physical Activation2017

    • Author(s)
      Takeshi Mori, Shinichiroh Iwamura, Isao Ogino and Shin R Mukai
    • Organizer
      APCChE2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 液パルスインジェクション法による繊維状炭素の高効率製造2017

    • Author(s)
      向井 紳
    • Organizer
      第55回炭素材料夏季セミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 減圧液パルスCVD法による多孔質炭素内部へのTiO2ナノ粒子の均一担持2017

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      化学工学会 第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Efficient Production of TiO2/C Nanoparticles through the Liquid Pulse Injection Technique2017

    • Author(s)
      Shinichiroh Iwamura, Kazuki Fujita, Isao Ogino, Shin R. Mukai
    • Organizer
      13th National Meeting on New Carbon Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Efficient Production of Filamentous Carbons Using the Liquid Pulse Injection Technique2017

    • Author(s)
      Shin R. Mukai
    • Organizer
      The 2017 International Conference on Functional Carbons
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マイクロ波加熱を用いたカーボンゲルの高速賦活2017

    • Author(s)
      福満 大介、岩村 振一郎、向井 紳
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カーボンゲルの細孔構造がPt担持に及ぼす影響2017

    • Author(s)
      相原 拓哉、佐藤 耕大、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 炭素材料の構造と表面特性のリチウム空気電池充放電特性への影響2017

    • Author(s)
      藤田 和樹、岩村 振一郎、荻野 勲、向井 紳
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 減圧液パルスCVD法による炭素細孔内へのTiO2ナノ粒子の均一担持とリチウムイオンキャパタへの応用2017

    • Author(s)
      岩村 振一郎、本橋 翔太、向井 紳
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Adsorption of Water Contaminants in Continuous Flow Systems Using Carbon Cryogels with a Microhoneycomb Structure2016

    • Author(s)
      Yoshida, Seiichiro; Iwamura, Shinichiro ; Ogino, Isao ; Mukai, Shin R.
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] On the Influence of Mass Transport in Sulfonated Carbon Catalysts Derived from Various Carbon Sources on Liquid-Phase Esterification Reactions2016

    • Author(s)
      Suzuki, Yukei; Ogino, Isao; Mukai, Shin R.
    • Organizer
      2016 AIChE Annual Meeting
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 炭素系固体酸触媒の液相反応への利用:表面の親疎水性と細孔特性が触媒活性へ与える影響2016

    • Author(s)
      鈴木 佑啓、荻野 勲、向井 紳
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Enhancing the Performance of Anode Catalysts for PEFCs Using Carbon Gels as the Support2016

    • Author(s)
      Satoh, Kodai; Tsuchiya, Takanori; Iwamura, Shinichiro; Ogino, Isao; Mukai, Shin R.
    • Organizer
      11th Conference on Sustainable Development of Energy, Water and Environment Systems
    • Place of Presentation
      Lisbon (Portugal)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon Gel Based Pt/C Catalysts with a High Sintering Tolerance2016

    • Author(s)
      Satoh, Kodai; Tsuchiya, Takanori; Iwamura, Shinichiro; Ogino, Isao; Mukai, Shin R.
    • Organizer
      Carbon 2016
    • Place of Presentation
      Pennsylvania (USA)
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Sulfonated Carbon Catalysts Synthesized from Various Carbon Sources2016

    • Author(s)
      Ogino, Isao ; Suzuki, Yukei; Mukai, Shin R.
    • Organizer
      16th International Congress on Catalysis
    • Place of Presentation
      Beijing (China)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カーボンゲルの構造制御と触媒反応への応用2016

    • Author(s)
      向井 紳
    • Organizer
      触媒学会千葉地区講演会
    • Place of Presentation
      千葉大学(千葉市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Unique Monolithic Porous Carbons with a Tunable Hierarchical Pore System of Micro-, Meso- and Macropores2016

    • Author(s)
      Mukai, Shin R.
    • Organizer
      HU-NTU-CERMAV Joint Symposium on Functional Materials 2016
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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