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Relationship between structural change and volume change of C-S-H during drying process

Research Project

Project/Area Number 16H06105
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Building structures/Materials
Research InstitutionThe University of Tokyo (2019)
Tohoku University (2016-2018)

Principal Investigator

Igarashi Go  東京大学, 大学院工学系研究科(工学部), 特任講師 (10733107)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥24,570,000 (Direct Cost: ¥18,900,000、Indirect Cost: ¥5,670,000)
Fiscal Year 2019: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2018: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2016: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
KeywordsC-S-H / 乾燥収縮 / 水分特性 / 層間水 / ゲル水 / 吸着理論 / スリット空隙 / 処女乾燥 / セメント化学 / 層状構造 / 収縮低減 / 1H-NMR / 混和材 / 収縮提言
Outline of Final Research Achievements

The first desorption isotherms (relationship between humidity and water content) of the cement paste, which cured under water at various temperatures were obtained and they were analysed based on the adsorption theory, which is called the extended BET theory. As a result, assuming that the void shape of the cement paste is a slit, the slit width is only 6 layers of water molecules. Furthermore, the saturation degree in the slit void is almost the same at high humidity regardless of temperature, but it is lower as the temperature decrease at low humidity.

Academic Significance and Societal Importance of the Research Achievements

本研究の学術的意義は,これまでのセメント化学において定説化しつつあった毛管張力による乾燥収縮メカニズムではなく,新たにC-S-Hの層状構造の層間に生じる分離圧による乾燥収縮メカニズムによる可能性を示したことにある。これは,社会的意義からとらえると,無収縮コンクリートといった新材料開発への基礎的な知見となったことや,現在すでにストックとして存在する高経年化したコンクリートの性能評価手法の構築への基礎的な知見となったと考えられる。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (10 results)

All 2020 2019 2018 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Microstructural changes in white Portland cement paste under the first drying process evaluated by WAXS, SAXS, and USAXS2017

    • Author(s)
      Maruyama, I., Sakamoto, N., Matsui, K., Igarashi, G.
    • Journal Title

      Cement and Concrete Research

      Volume: 91 Pages: 24-32

    • DOI

      10.1016/j.cemconres.2016.10.002

    • NAID

      120005981225

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 合成エトリンガイトの体積変化メカニズムに関する基礎的研究2016

    • Author(s)
      赤羽根駿之介,五十嵐豪,西脇智哉,丸山一平
    • Journal Title

      コンクリート工学年次論文集

      Volume: 38 Pages: 579-585

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 拡張BET理論から得られる異なる温度における処女脱着性状に関する一考察2020

    • Author(s)
      五十嵐豪,丸山一平,石田哲也
    • Organizer
      セメント技術大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 拡張BET理論から得られる処女脱着性状に関する一考察2019

    • Author(s)
      五十嵐豪,丸山一平
    • Organizer
      セメント技術大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Interpretation Water Vapour Sorption Curve of Hardened Cement Paste by Modified BET Theory2018

    • Author(s)
      Go Igarashi, Ippei Maruyama
    • Organizer
      Conference in honor of Centennial LMC and Karen Scrivener 60th birthday
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interpretation water vapour sorption curve of hardened cement paste by modified BET theory2018

    • Author(s)
      Go IGARASHI, Ippei MARUYAMA
    • Organizer
      Conference to celebrate the centennial of LMC and Karen Scrivener's 60th birthday
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 合成エトリンガイトの水蒸気吸脱着性状と体積変化の関係に関する一考察2016

    • Author(s)
      赤羽根駿之介,五十嵐豪,西脇智哉,丸山一平
    • Organizer
      日本建築学会大会学術講演会
    • Place of Presentation
      福岡大学(福岡)
    • Year and Date
      2016-08-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] 合成エトリンガイトの体積変化メカニズムに関する基礎的研究2016

    • Author(s)
      赤羽根駿之介,五十嵐豪,西脇智哉,丸山一平
    • Organizer
      コンクリート工学年次大会
    • Place of Presentation
      福岡国際会議場(福岡)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水蒸気吸脱着による合成エトリンガイトの体積変化挙動に関する一考察2016

    • Author(s)
      赤羽根駿之介,五十嵐豪,西脇智哉,丸山一平
    • Organizer
      日本建築学会東北支部研究報告会
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2016-06-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] 合成エトリンガイトの体積変化と水蒸気吸着性状に関する一考察2016

    • Author(s)
      赤羽根駿之介,五十嵐豪,西脇智哉,丸山一平
    • Organizer
      セメント技術大会
    • Place of Presentation
      ホテルメトロポリタン東京池袋(東京都)
    • Year and Date
      2016-05-10
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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