| Budget Amount *help |
¥186,550,000 (Direct Cost: ¥143,500,000、Indirect Cost: ¥43,050,000)
Fiscal Year 2020: ¥28,470,000 (Direct Cost: ¥21,900,000、Indirect Cost: ¥6,570,000)
Fiscal Year 2019: ¥30,940,000 (Direct Cost: ¥23,800,000、Indirect Cost: ¥7,140,000)
Fiscal Year 2018: ¥26,780,000 (Direct Cost: ¥20,600,000、Indirect Cost: ¥6,180,000)
Fiscal Year 2017: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2016: ¥74,360,000 (Direct Cost: ¥57,200,000、Indirect Cost: ¥17,160,000)
|
|---|
| Outline of Final Research Achievements |
Brønsted bases have been extensively employed for activation of reactants having an acidic proton. Among these, organobases were commonly utilized as a reagent for molecular transformations, however applicable transformations have been quite limited because of these less basic properties. In recent years, intensive interest has been devoted to the development of organosuperbases, although little attention has been devoted to the catalytic use of these fascinating molecules. We focused on the utilization of these organosuperbase as a catalyst and the development of functional organosuperbase catalysts enabling molecular recognition, namely, chiral organosuperbases. The purpose of this research is that the design and synthesis of chiral organosuperbases, which have unprecedent and remarkable catalytic activity, high selectivity, and construction of catalyst-recycling system. As the result, we have successfully developed a new type of chiral organosuperbase catalysts.
|
