Creation and evaluation of new cyclophane triads with potential gradient control ability for molecular diodes
| Project/Area Number |
16K05693
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
Sako Katsuya 名古屋工業大学, 工学(系)研究科(研究院), 准教授 (90235234)
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| Research Collaborator |
KIGUCHI Manabu
IWANAGA Tetsuo
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | シクロファン / 電位勾配 / 分子ダイオード / 三元系 / ドナー・アクセプター系 / 分子エレクロトにクス / π電子系 / 分子デバイス / TTF / ドナー / ドナー・アクセプター / 有機導体 / 合成化学 / ナノ材料 / 先端機能デバイス / 電子・電気材料 |
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| Outline of Final Research Achievements |
In order to development of the molecular diodes in the single-molecular devices, we studied for the purpose of the creation of novel cyclophane triads. We have designed and synthesized novel donor-cyclophane and donor-acceptor-cyclophane triads that incorporated electron-donating groups or electron-withdrawing groups into the cyclophane structure. By number of the substituents incorporated in bridge structure, we succeeded in the control of the redox potentials of donor and acceptor units. These results are significant information in the development of the molecular diodes using potential gradient control function.
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| Academic Significance and Societal Importance of the Research Achievements |
今回開発した新奇な三元系シクロファン分子は、現在の固体エレクトロニクスに代わる分子エレクトロニクスセットの１つである分子ダイオードに分子設計指針を与えるという学術的意義に加え、分子デバイスによって実現される分子コンピュータなどの研究分野への展開が計られると考える。また、分子エレクトロニクスの開発研究は、機能性、省エネルギー、低環境負荷の面から持続可能な社会の実現に寄与し、その点で本研究成果は社会的意義を有している。
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Report
(4 results)
Research Products
(16 results)
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[Journal Article] Donor-Donor’-Acceptor Triads Based on [3.3]Paracyclophane with a 1,4-Dithiafulvene Donor and a Cyanomethylene Acceptor :Synthesis, Structure, and Electrochemical and Photophysical Properties2018
Author(s)
K. Sako, T. Hasegawa, H. Onda, M. Shiotsuka, M. Watanabe, T. Shinmyozu, S. Tojo, M. Fujitsuka, T. Majima, Y. Hirao, T. Kubo, T. Iwanaga, S. Toyota, H. Takemura
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Journal Title
Chemistry - A European Journal
Volume: 24
Issue: 44
Pages: 11407-11416
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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