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Development of Selective Coupling Reactions Using Electrochemically Generated Oeganometallics

Research Project

Project/Area Number 16K05695
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionOkayama University

Principal Investigator

Mitsudo Koichi  岡山大学, 自然科学研究科, 准教授 (40379714)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords有機電解合成 / 有機電気化学 / 電解酸化 / 環化反応 / クロスカップリング反応 / 有機電解 / ジイン / パラジウム / 合成化学 / 有機電子移動化学 / 有機金属化学 / 拡張π電子系分子
Outline of Final Research Achievements

We have developed an electrochemical cross-coupling reaction between alkynylboronic acids and terminal alkynes for the synthesis of diynes. The next challenges are the improvement of the material balance and the improvement of the yields.
During the course of the study, we successfully developed an intramolecular electrochemical cross-coupling reactions via S-H / C-H bond cleavage. The addition of tetrabutylammonium bromide dramatically changed the reaction selectivity, and the target reaction proceeded efficiently.
The transformation, which can be realized by the electrochemical technique, is difficult by conventional chemical methods. The scope of the reaction is wide enough to obtain a variety of derivatives in high yields.

Academic Significance and Societal Importance of the Research Achievements

目的とする分子を無駄なく効率的に合成する手法として、クロスカップリング反応は学術的にも工業的にも非常に重要である。本研究はその新しいアプロートとして、有機電気化学を組み込んだ新しい領域における研究であり、学術的な特色であり、独創的な反応系である。電気化学的に発生させた 活性種は高い触媒活性と特殊な反応性を有する。これを用いることで従来は難しかった反応が進行し、合成困難だった新規分子群の選択的構築が可能となった。今回ターゲットとした拡張π電子系分子は発光材料や半導体材料への応用が期待できるので、材料科学の観点から見ても学術的・社会的に意義ある研究である。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (75 results)

All 2019 2018 2017 2016 Other

All Journal Article (18 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 18 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (55 results) (of which Int'l Joint Research: 23 results,  Invited: 8 results) Remarks (2 results)

  • [Journal Article] Iodide-Mediated or Iodide-Catalyzed Demethylation and Friedel-Crafts C-H Borylative Cyclization Leading to Thiophene-Fused 1,2-Oxaborine Derivatives2019

    • Author(s)
      Shigemori Keisuke、Watanabe Momoka、Kong Julie、Mitsudo Koichi、Wakamiya Atsushi、Mandai Hiroki、Suga Seiji
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 7 Pages: 2171-2175

    • DOI

      10.1021/acs.orglett.9b00485

    • NAID

      120006808071

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 1,10-Phenanthroline- or Electron-Promoted Cyanation of Aryl Iodides2019

    • Author(s)
      Mitsudo Koichi、Yoshioka Kazuki、Hirata Takayuki、Mandai Hiroki、Midorikawa Koji、Suga Seiji
    • Journal Title

      Synlett

      Volume: 印刷中 Issue: 10 Pages: 1209-1214

    • DOI

      10.1055/s-0037-1611793

    • NAID

      120006847071

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoselective nucleophilic addition reactions to cyclic N-acyliminium ions using the indirect cation pool method: Elucidation of stereoselectivity by spectroscopic conformational analysis and DFT calculations2018

    • Author(s)
      Mitsudo Koichi、Yamamoto Junya、Akagi Tomoya、Yamashita Atsuhiro、Haisa Masahiro、Yoshioka Kazuki、Mandai Hiroki、Ueoka Koji、Hempel Christian、Yoshida Jun-ichi、Suga Seiji
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 14 Pages: 1192-1202

    • DOI

      10.3762/bjoc.14.100

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Efficient Synthesis and Properties of [1]Benzothieno[3,2-b]thieno[2,3-d]furans and [1]Benzothieno[3,2-b]thieno[2,3-d]thiophenes2018

    • Author(s)
      Kurimoto Yuji、Mitsudo Koichi、Mandai Hiroki、Wakamiya Atsushi、Murata Yasujiro、Mori Hiroki、 Nishihara Yasushi、Suga Seiji
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 7 Issue: 8 Pages: 1635-1641

    • DOI

      10.1002/ajoc.201800270

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cu/Fe/O=PPh3-Catalyzed Etherification for the Synthesis of Aryl 3-Benzo[b]thienyl Ethers2018

    • Author(s)
      Mitsudo Koichi、Asada Takuya、Inada Tomohiro、Kurimoto Yuji、Mandai Hiroki、Suga Seiji
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 8 Pages: 1044-1047

    • DOI

      10.1246/cl.180425

    • NAID

      130007430998

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic Kinetic Resolution of Azlactones by a Chiral N,N-Dimethyl-4-aminopyridine Derivative Containing a 1,1′-Binaphthyl Unit: Importance of Amide Groups2018

    • Author(s)
      Mandai Hiroki、Hongo Kohei、Fujiwara Takuma、Fujii Kazuki、Mitsudo Koichi、Suga Seiji
    • Journal Title

      Organic Letters

      Volume: 20 Issue: 16 Pages: 4811-4814

    • DOI

      10.1021/acs.orglett.8b01960

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Desymmetrization of 1,3-Diols by a Chiral DMAP Derivative2018

    • Author(s)
      Mandai Hiroki、Ashihara Kosuke、Mitsudo Koichi、Suga Seiji
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 11 Pages: 1360-1363

    • DOI

      10.1246/cl.180697

    • NAID

      130007504936

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives2018

    • Author(s)
      Mitsudo Koichi、Shigemori Keisuke、Mandai Hiroki、Wakamiya Atsushi、Suga Seiji
    • Journal Title

      Organic Letters

      Volume: 20 Issue: 22 Pages: 7336-7340

    • DOI

      10.1021/acs.orglett.8b03316

    • NAID

      120006765098

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Acyl Migration Reactions of Furanyl Carbonates with Chiral DMAP Derivatives2018

    • Author(s)
      Fujii Kazuki、Mitsudo Koichi、Mandai Hiroki、Korenaga Toshinobu、Suga Seiji
    • Journal Title

      Chemistry - A European Journal

      Volume: 26 Issue: 9 Pages: 2208-2212

    • DOI

      10.1002/chem.201806050

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Bonding-Assisted Enhancement of the Reaction Rate and Selectivity in the Kinetic Resolution of d,l-1,2-Diols with Chiral Nucleophilic Catalysts2017

    • Author(s)
      Fujii Kazuki、Mitsudo Koichi、Mandai Hiroki、Suga Seiji
    • Journal Title

      Advanced Synthesis & Catalysis

      Volume: 359 Issue: 16 Pages: 2778-2788

    • DOI

      10.1002/adsc.201700057

    • Related Report
      2017 Research-status Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rh-Catalyzed Dehydrogenative Cyclization Leading to Benzosilolothiophene Derivatives via Si-H/C-H Bond Cleavage2017

    • Author(s)
      Mitsudo Koichi、Tanaka Seiichi、Isobuchi Ryota、Inada Tomohiro、Mandai Hiroki、Korenaga Toshinobu、Wakamiya Atsushi、Murata Yasujiro、Suga Seiji
    • Journal Title

      Organic Letters

      Volume: 19 Issue: 10 Pages: 2564-2567

    • DOI

      10.1021/acs.orglett.7b00878

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives2017

    • Author(s)
      Mitsudo Koichi、Kurimoto Yuji、Mandai Hiroki、Suga Seiji
    • Journal Title

      Organic Letters

      Volume: 19 Issue: 11 Pages: 2821-2824

    • DOI

      10.1021/acs.orglett.7b00969

    • NAID

      120006765097

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Desymmetrization of meso-1,2-Diols by a Chiral N,N-4-Dimethylaminopyridine Derivative Containing a 1,1′-Binaphthyl Unit: Importance of the Hydroxy Groups2017

    • Author(s)
      Mandai Hiroki、Yasuhara Hiroshi、Fujii Kazuki、Shimomura Yukihito、Mitsudo Koichi、Suga Seiji
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 82 Issue: 13 Pages: 6846-6856

    • DOI

      10.1021/acs.joc.7b00992

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Regioselective DMAD-Insertion Reaction of Silyl Dienol Ether of γ-Pyrone under Catalyst- and Heating-Free Conditions2017

    • Author(s)
      Hayakawa Ichiro、Sakakura Akira、Yamanaka Yuji、Ota Hiromi、Mitsudo Koichi
    • Journal Title

      HETEROCYCLES

      Volume: 94 Issue: 12 Pages: 2299-2299

    • DOI

      10.3987/com-17-13820

    • NAID

      40021421566

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rh-Catalyzed Dehydrogenative Cyclization Leading to Benzosilolothiophene Derivatives via Si-H/C-H Bond Cleavage2017

    • Author(s)
      Mitsudo, K.; Tanaka, S.; Isobuchi, R.; Inada, T.; Mandai, H.; Korenaga, T.; Wakamiya, A.; Murata, Y.; Suga, S.
    • Journal Title

      Org. Lett.

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Facile Synthesis of Naphthothiophenone Derivatives and Anthradithiophenedione via Friedel-Crafts Acylation and Their Fundamental Properties2016

    • Author(s)
      Koichi Mitsudo, Takashi Murakami, Takuya Shibasaki, Tomohiro Inada, Hiroki Mandai, Hiromi Ota, Seiji Suga
    • Journal Title

      Synlett

      Volume: 27 Issue: 16 Pages: 2327-2332

    • DOI

      10.1055/s-0035-1562470

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Kinetic Resolution of Secondary Carbinols by a Chiral <i>N</i>,<i>N</i>-4-Dimethylaminopyridine Derivative Containing a 1,1′-Binaphthyl Unit: Hydrogen Bonding Affects Catalytic Activity and Enantioselectivity2016

    • Author(s)
      Kazuki Fujii, Koichi Mitsudo, Hiroki Mandai, and Seiji Suga
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 89 Issue: 9 Pages: 1081-1092

    • DOI

      10.1246/bcsj.20160135

    • NAID

      130006770702

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enantioselective acyl transfer catalysis by a combination of common catalytic motifs and electrostatic interactions2016

    • Author(s)
      Hiroki Mandai, Kazuki Fujii, Hiroshi Yasuhara, Kenko Abe, Koichi Mitsudo, Toshinobu Korenaga, Seiji Suga
    • Journal Title

      Nature Commun.

      Volume: 7 Issue: 1 Pages: 11297-11297

    • DOI

      10.1038/ncomms11297

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Synthesis of Heterothienoacenes via Construction and Cyclization of Chalcogen-Bridged Thiophene Derivatives and Their Properties2019

    • Author(s)
      Koichi Mitsudo
    • Organizer
      日本化学会 第99春季年会, Asian International Symposium - Electrochemistry -
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] エテン架橋ターチオフェン酸化物の合成とその電気化学的特性2019

    • Author(s)
      高畑正利・光藤耕一・菅誠治
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気化学的な脱水素型環化反応によるチエノアセンの合成2019

    • Author(s)
      米澤時希・光藤耕一・菅誠治
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] チエニルチオエーテルの効率的ワンポット合成2019

    • Author(s)
      羽原奈々江・光藤耕一・菅誠治
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フルベン誘導体の新規合成法の開発2019

    • Author(s)
      栗本悠司・光藤耕一・菅誠治
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Reactions Using Organo-Dications As Redox-Switchable Catalysts in Batch and Flow Systems2018

    • Author(s)
      Seiji Suga, Yusuke Kurihara, Takayuki Hirata, Hiroki Tanaka, Koichi Mitsudo
    • Organizer
      233rd ECS Annual Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸素および硫黄架橋ビチオフェン骨格の形成と縮環反応によるチエノアセン誘導体の新規合成法2018

    • Author(s)
      栗本悠司、光藤耕一、菅誠治
    • Organizer
      第113回有機合成シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 環状N-アシルイミニウムイオンと求核剤との反応における立体化学の逆転現象2018

    • Author(s)
      吉岡和紀・光藤耕一・菅 誠治
    • Organizer
      第42回有機電子移動化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] エテン架橋ターチオフェン(EBTT)を骨格に含むD-Aポリマーの合成とその電気化学的特性2018

    • Author(s)
      高畑正利・山崎新・光藤耕一・菅 誠治
    • Organizer
      第42回有機電子移動化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気化学的な脱水素型環化反応によるπ拡張チエノアセンの合成2018

    • Author(s)
      米澤時希・松尾連・光藤耕一・菅 誠治
    • Organizer
      第42回有機電子移動化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives2018

    • Author(s)
      Koichi Mitsudo, Yuji Kurimoto, and Seiji Suga
    • Organizer
      28th International Conference on Organometallic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Efficient Synthesis and Properties of Benzodithienofurans and Benzodithienothiophenes2018

    • Author(s)
      Koichi Mitsudo, Yuji Kurimoto, and Seiji Suga
    • Organizer
      The Fourth International Symposium on C-H Activation
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸素及び硫黄原子架橋を経る新規チエノアセン誘導体の効率的合成法の開発と物性評価2018

    • Author(s)
      栗本悠司・光藤耕一・菅誠治
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 鉄/銅共触媒系を用いたエーテル化反応によるアリールベンゾ[b]チエニルエーテルの合成2018

    • Author(s)
      浅田拓哉・光藤耕一・菅 誠治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 銅触媒を用いる脱水素型環化によるチエノフラン誘導体の合成2018

    • Author(s)
      小橋祥晃・光藤耕一・菅 誠治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気化学的脱水素環化反応によるπ拡張チエノアセンの合成2018

    • Author(s)
      光藤耕一,松尾恋,米澤時希,菅 誠治
    • Organizer
      2018年電気化学秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Properties of Dithieno-fused 1,4-Azaborines2018

    • Author(s)
      Koichi Mitsudo, Keisuke Shigemori, Seiji Suga
    • Organizer
      The Fourteenth International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ynthesis of Thiophene-fused 1,2-Oxaborines via Iodide-Catalyzed Demethylation and Intramolecular C-H Borylation2018

    • Author(s)
      Keisuke Shigemori, Koichi Mitsudo, Seiji Suga
    • Organizer
      The Fourteenth International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Efficient Synthesis of Thienoacene Derivatives via Construction of Oxygen or Sulfur-Bridged Bithiophene Skeletons and the following Cyclization2018

    • Author(s)
      Yuji Kurimoto, Koichi Mitsudo, Seiji Suga
    • Organizer
      The Fourteenth International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機金属化学と有機電気化学を両輪とする拡張π電子系分子の合成2018

    • Author(s)
      光藤耕一
    • Organizer
      有機合成化学協会九州山口支部平成30年度第2回有機合成化学講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Efficient and Straightforward Synthesis of Heterothienoacenes2018

    • Author(s)
      Koichi Mitsudo, Seiji Suga
    • Organizer
      The 13th International Symposium on Organic Reactions
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 鉄・銅共触媒を用いたアリールチエニルエーテルの合成およびチエノベンゾフラン誘導体への変換2018

    • Author(s)
      浅田拓哉・稲田智大・光藤耕一・菅 誠治
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Friedel-Crafts C-Hボリル化反応を用いたチエノアザボリン誘導体の合成とその物性評価2018

    • Author(s)
      重森圭介・光藤耕一・菅 誠治
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 電気化学的な脱水素型環化反応によるπ拡張チエノフランの合成2018

    • Author(s)
      松尾恋・光藤耕一・菅 誠治
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 環状N-アシルイミニウムイオンのアリル化における立体化学の逆転現象2018

    • Author(s)
      吉岡和紀・光藤耕一・菅 誠治
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] ベンゾジチエノフランおよびベンゾジチエノチオフェン誘導体の効率的合成と物性評価2018

    • Author(s)
      栗本悠司・光藤耕一・菅 誠治
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 有機電解と有機金属の協奏的レドックス化学に基づく分子構築2017

    • Author(s)
      光藤耕一
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] SNAr 反応によるエーテル合成および脱水素環化反応を経るジチエノフラン誘導体の合成2017

    • Author(s)
      栗本悠司・光藤耕一・菅誠治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] レドックス応答型有機触媒を用いた反応制御2017

    • Author(s)
      平田敬之・栗原悠輔・光藤耕一・菅誠治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] インダイレクトカチオンプール法を応用したピペリジン誘導体の不斉合成2017

    • Author(s)
      灰佐将弘・光藤耕一・菅誠治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Efficient Synthesis of π-Extended Ladder-type Thiophene Derivatives2017

    • Author(s)
      Koichi Mitsudo
    • Organizer
      International Symposium on Pure & Applied Chemistry 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] インダイレクトカチオンプール法を応用したピペリジン誘導体の不斉合成2017

    • Author(s)
      吉岡和紀・灰佐将弘・光藤耕一・菅誠治
    • Organizer
      第41回有機電子移動化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 鉄・銅共触媒によるエーテル化反応を経るチエノベンゾフランの効率的合成と電気化学的性質2017

    • Author(s)
      浅田拓哉・稲田智大・光藤耕一・菅誠治
    • Organizer
      第41回有機電子移動化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] エーテル合成および脱水素環化反応を経るヘテロ環が縮環したチエノフラン誘導体の合成2017

    • Author(s)
      栗本悠司・光藤耕一・菅誠治
    • Organizer
      第41回有機電子移動化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Rh-Catalyzed Dehydrogenative Cyclization Leading to Benzosilolothiophene Derivatives2017

    • Author(s)
      Koichi Mitsudo, Seiichi Tanaka, and Seiji Suga
    • Organizer
      19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Butadiynes by Electro-oxidative Coupling Reactions2017

    • Author(s)
      Ren Matsuo, Natsuyo Kamimoto, Koichi Mitsudo, and Seiji Suga
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives2017

    • Author(s)
      Yuji Kurimoto, Koichi Mitsudo, and Seiji Suga
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Dehydrative or Dehydrogenative Cyclization Leading to Benzothienofurans2017

    • Author(s)
      Yoshiaki Kobashi, Tomohiro Inada, Yuji Kurimoto, Koichi Mitsudo, and Seiji Suga
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Pd-Catalyzed Cyclization for the Synthesis of Dithienofuran Derivatives2017

    • Author(s)
      Yumi Hosogi, Koichi Mitsudo, and Seiji Suga
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fe/Cu-Cocatalyzed Etherification for the Synthesis of 3-Benzo[b]thienyl Ethers and Their Transformation to Benzothienofurans2017

    • Author(s)
      Takuya Asada, Tomohiro Inada, Koichi Mitsudo, and Seiji Suga
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Facile Syntheses of Heterothienoacenes and Their Properties2017

    • Author(s)
      Koichi Mitsudo
    • Organizer
      International Symposium on JST ACT-C Project
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] エーテル合成および脱水素環化を経るベンゾジチエノフラン誘導体の合成と物性評価2017

    • Author(s)
      栗本悠司・光藤耕一・菅誠治
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 多様なチエノアセン系分子の効率的合成法の探索とそのレドックス特性2017

    • Author(s)
      光藤耕一
    • Organizer
      2017年日本化学会中国四国支部大会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Synthesis of Butadiynes by Electro-oxidative Coupling Reactions2017

    • Author(s)
      Ren Matsuo, Natsuyo Kamimoto, Koichi Mitsudo, and Seiji Suga
    • Organizer
      The 11th International Symposium on Integrated Synthesis & The 3rd Symposium on Middle Molecular Strategy
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 有機半導体材料を指向した七環式チエノフラン誘導体の合成と物性評価2016

    • Author(s)
      稲田智大・塩津辰真・中村成明・森裕樹・西原康師・光藤耕一・菅 誠治
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] ロジウム触媒を用いた Si-H/C-H 結合切断を経る 脱水素型環化反応によるベンゾシロロチオフェン誘導体の合成2016

    • Author(s)
      光藤耕一・田中聖一・礒淵僚太・是永敏伸・菅 誠治
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] ベンゾチエノフラン誘導体の高効率的合成と物性評価2016

    • Author(s)
      稲田智大・塩津辰真・ 光藤耕一・菅 誠治
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機電子移動化学と有機金属化学を両輪とする有機合成2016

    • Author(s)
      光藤耕一
    • Organizer
      第12回有機電子移動化学若手の会
    • Place of Presentation
      新潟
    • Year and Date
      2016-06-24
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 酸性ゼオライトを利用した脱水環化反応を経る新規π拡張チエノフランの効率的合成および電子的特性の評価2016

    • Author(s)
      稲田智大・塩津辰真・中村成明・光藤耕一・菅 誠治
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟大学
    • Year and Date
      2016-06-23
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気化学的手法により発生させた有機ジカチオン種のレドックス応答性及び触媒活性評価2016

    • Author(s)
      平田敬之・藤原郁美・光藤耕一・菅 誠治
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟大学
    • Year and Date
      2016-06-23
    • Related Report
      2016 Research-status Report
  • [Presentation] Stereoselective Nucleophilic Additions to the N-Acyliminium Ions: Elucidation of Stereoselectivity By Spectroscopic Conformational Analysis2016

    • Author(s)
      Seiji Suga, Junya Yamamoto, Tomoya Akagi, Masahiro Haisa, Koichi Mitsudo
    • Organizer
      ECS 229th Annual Meeting
    • Place of Presentation
      San Diego
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Properties, and Theoretical Study of π-Extended Diynes and Their Analogs Bearing Two Amino Moieties2016

    • Author(s)
      Koichi Mitsudo, Natsuyo Kamimoto, Nariaki Nakamura, Akina Tsutsumi, Seiji Suga
    • Organizer
      ECS 229th Annual Meeting
    • Place of Presentation
      San Diego
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Properties, and Theoretical Studies of π-Extended Diynes Bearing Two Amino Moieties2016

    • Author(s)
      Koichi Mitsudo, Natsuyo Kamimoto, Seiji Suga
    • Organizer
      The 12th International Symposium on Organic Reactions
    • Place of Presentation
      京都
    • Year and Date
      2016-04-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthetic Studies for π-Extended Thienofurans via Zeolite-Promoted Dehydrative Cyclization2016

    • Author(s)
      Tomohiro Inada, Tatsuma Shiotsu, Nariaki Nakamura, Koichi Mitsudo, Seiji Suga
    • Organizer
      The 12th International Symposium on Organic Reactions
    • Place of Presentation
      京都
    • Year and Date
      2016-04-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Facile Access to π-Extended Thienofurans via Zeolite-Promoted Dehydrative Cyclization and Their Electrochemical Propertie2016

    • Author(s)
      Tomohiro Inada, Tatsuma Shiotsu, Nariaki Nakamura, Koichi Mitsudo, Seiji Suga
    • Organizer
      The 6th German-Japanese Symposium on Electrosynthesis
    • Place of Presentation
      京都大学
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] 合成プロセス化学研究室:菅研究室

    • URL

      http://achem.okayama-u.ac.jp/reacteng/

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
  • [Remarks] 合成プロセス化学研究室 : 菅研究室

    • URL

      http://achem.okayama-u.ac.jp/reacteng/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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