Development of catalytic hydrogenation using thiolate iron complexes stabilized by metallacycles
| Project/Area Number |
16K05729
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanagawa University (2018)
Osaka City University (2016-2017) |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | チオラート / 鉄錯体 / メタラサイクル / チオフェン誘導体 / 光反応 / 一酸化炭素放出 / ヒドリド錯体 / 水素分子活性化 / 水素化 / イソシアニド錯体 / 触媒 |
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| Outline of Final Research Achievements |
N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands were synthesized, and the CO releasing properties induced by visible to near-IR light were investigated. Iron complexes of S,N,C,S-tetradentate ligands were synthesized by introducing a pendant thioether arm, which is reversibly replaced by CO. Hydride iron complexes were detected in the reaction of diphosphine-bridged diiron thiolate complexes with dihydrogen. Iron carbonyl complexes stabilized by metallacycles were synthesized from quinolyl-substituted thiophene derivatives.
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| Academic Significance and Societal Importance of the Research Achievements |
地球上に豊富に存在し、環境適合性の高い鉄を利用した機能性物質の開発は、持続可能な社会を築くうえで有用である。自然界の酸化還元酵素では鉄－硫黄骨格が重要な役割を果たしているが、その仕組みを人工触媒に組み込むことは非常に難しい。本研究では、メタラサイクルで安定化したチオラート鉄錯体を多く開発しており、酵素に見られる鉄－硫黄骨格の特徴を生かした触媒開発への展開が期待できる。
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Report
(4 results)
Research Products
(38 results)
