| Project/Area Number |
16K05749
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kyoto Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | ポルフィリン / 配位結合 / 超分子 / 近赤外発光 / 二重鎖形成 / 発光 / ナノテクノロジー / 人工光合成 |
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| Outline of Final Research Achievements |
The excellent functions of the primary photosynthetic events are considered to arise from the characteristic phenomena in the nanometer-to-micrometer intermediate size region. Synthetic chemistry has involved difficulty in controlling the structures and/or shape in such intermediate size region. This study tackled the synthesis of mesoscopic size molecules by employing a double-strand-forming porphyrin array, and achieved the shape control of the porphyrin array beyond micrometer-scale in solution. Additionally, it was unexpectedly found that amorphous porphyrins formed excimer and exhibited a solid-state near-infrared luminescence.
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| Academic Significance and Societal Importance of the Research Achievements |
合成分子が構造・形状制御できるサイズ領域をマイクロメートルサイズまで拡張することができた。
従来結晶性が高いとかんがえられてきたポルフィリン金属錯体が、アモルファス状態では極めてユニークな物性を示すことが明らかとなった。とくに一般的に材料も非常に限定される、固体近赤外発光特性は特筆するべき特徴である。また、バルク状態において、巨大な吸収が異常分散を誘起し、バルク状態では屈折率が非常に大きいことが明らかとなった。
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