• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Elucidation of Photosynthetic Functions Based on Controlled Size of Cyclic Light-Harvesting Antenna Model

Research Project

Project/Area Number 16K05749
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionKyoto Institute of Technology

Principal Investigator

Morisue Mitsuhiko  京都工芸繊維大学, 分子化学系, 助教 (40403357)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsポルフィリン / 配位結合 / 超分子 / 近赤外発光 / 二重鎖形成 / 発光 / ナノテクノロジー / 人工光合成
Outline of Final Research Achievements

The excellent functions of the primary photosynthetic events are considered to arise from the characteristic phenomena in the nanometer-to-micrometer intermediate size region. Synthetic chemistry has involved difficulty in controlling the structures and/or shape in such intermediate size region. This study tackled the synthesis of mesoscopic size molecules by employing a double-strand-forming porphyrin array, and achieved the shape control of the porphyrin array beyond micrometer-scale in solution. Additionally, it was unexpectedly found that amorphous porphyrins formed excimer and exhibited a solid-state near-infrared luminescence.

Academic Significance and Societal Importance of the Research Achievements

合成分子が構造・形状制御できるサイズ領域をマイクロメートルサイズまで拡張することができた。
従来結晶性が高いとかんがえられてきたポルフィリン金属錯体が、アモルファス状態では極めてユニークな物性を示すことが明らかとなった。とくに一般的に材料も非常に限定される、固体近赤外発光特性は特筆するべき特徴である。また、バルク状態において、巨大な吸収が異常分散を誘起し、バルク状態では屈折率が非常に大きいことが明らかとなった。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (28 results)

All 2019 2018 2017 2016

All Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 10 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results) Book (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Perfluorophenyl‐Directed Giant Porphyrin J‐Aggregates2019

    • Author(s)
      Morisue Mitsuhiko、Ueno Ikuya、Muraoka Kunihiko、Omagari Shun、Nakanishi Takayuki、Hasegawa Yasuchika、Hikima Takaaki、Sasaki Sono
    • Journal Title

      Chemistry ? A European Journal

      Volume: - Issue: 30 Pages: 7322-7329

    • DOI

      10.1002/chem.201901017

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preferential Solvation Unveiled by Anomalous Conformational Equilibration of Porphyrin Dimers: Nucleation Growth of Solvent?Solvent Segregation2018

    • Author(s)
      Morisue Mitsuhiko、Ueno Ikuya
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 122 Issue: 20 Pages: 5251-5259

    • DOI

      10.1021/acs.jpcb.8b02558

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fully Conjugated Porphyrin Glass: Collective Light-Harvesting Antenna for Near-Infrared Fluorescence beyond 1 μm2018

    • Author(s)
      Morisue Mitsuhiko、Omagari Shun、Ueno Ikuya、Nakanishi Takayuki、Hasegawa Yasuchika、Yamamoto Shunsuke、Matsui Jun、Sasaki Sono、Hikima Takaaki、Sakurai Shinichi
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 4 Pages: 4466-4474

    • DOI

      10.1021/acsomega.8b00566

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] An antiparallel double-stranded BODIPY?porphyrin dyad assembled via a self-complementary B?F?Zn interaction2018

    • Author(s)
      Morisue Mitsuhiko、Nakano Shinya、Shimizu Masaki、Yumura Takashi
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 2 Pages: 144-147

    • DOI

      10.1039/c7cc07049g

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] A metal-lustrous porphyrin foil2017

    • Author(s)
      Morisue Mitsuhiko、Hoshino Yuki、Shimizu Masaki、Tomita Shogo、Sasaki Sono、Sakurai Shinichi、Hikima Takaaki、Kawamura Ayaka、Kohri Michinari、Matsui Jun、Yamao Takeshi
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 77 Pages: 10703-10706

    • DOI

      10.1039/c7cc06159e

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Porphyrins Sheathed in Quadrupolar Solvation Spheres of Hexafluorobenzene: Solvation-Induced Fluorescence Enhancement and Conformational Confinement2017

    • Author(s)
      Morisue Mitsuhiko、Ueno Ikuya、Shimizu Masaki、Yumura Takashi、Ikeda Noriaki
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 35 Pages: 19407-19413

    • DOI

      10.1021/acs.jpcc.7b04083

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Amorphous Porphyrin Glasses Exhibit Near-Infrared Excimer Luminescence2017

    • Author(s)
      Mitsuhiko Morisue,* Ikuya Ueno, Takayuki Nakanishil, Takafumi Matsui, Sono Sasaki, Masaki Shimizu, Jun Matsui, Yasuchika Hasegawa
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 37 Pages: 22679-22683

    • DOI

      10.1039/c7ra02752d

    • NAID

      120006309134

    • Related Report
      2017 Research-status Report 2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Supramolecular Polymer of Near-Infrared Luminescent Porphyrin Glass2017

    • Author(s)
      Mitsuhiko Morisue,* Yuki Hoshino, Masaki Shimizu, Takayuki Nakanishi, Yasuchika Hasegawa, Md. Amran Hossain, Shinichi Sakurai, Sono Sasaki, Shinobu Uemura, Jun Matsui
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 8 Pages: 3186-3192

    • DOI

      10.1021/acs.macromol.7b00316

    • Related Report
      2017 Research-status Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Tightly Stretched Ultralong Supramolecular Multiporphyrin Array Propagated by Double-Strand Formation2016

    • Author(s)
      Mitsuhiko Morisue,* Yuki Hoshino, Masaki Shimizu, Shinobu Uemura, Shinichi Sakurai
    • Journal Title

      Chemistry A European Journal

      Volume: 22 Issue: 37 Pages: 13019-13022

    • DOI

      10.1002/chem.201602968

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Group 14 Dithienometallole-Linked Ethynylene-Conjugated Porphyrin Dimers2016

    • Author(s)
      Mitsuhiko Morisue,* Yuki Hoshino, Masashi Nakamura, Takashi Yumura, Shinjiro Machida, Yousuke Ooyama, Masaki Shimizu, Joji Ohshita
    • Journal Title

      Inorganic Chemistry

      Volume: 55 Issue: 15 Pages: 7432-7441

    • DOI

      10.1021/acs.inorgchem.6b00667

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 亜鉛ポルフィリン-BODIPY連結化合物の超分子錯体形成とその発光特性2018

    • Author(s)
      中野慎也, 森末光彦, 湯村尚史, 池田憲昭
    • Organizer
      第37回無機高分子研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Near-infrared luminescent excimer formation of porphyrin glasses2018

    • Author(s)
      森末光彦
    • Organizer
      The 10th International Conference on Porphyrin and Phthalocyanine (ICPP10)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Near-infrared luminescent porphyrin glasses2018

    • Author(s)
      森末光彦
    • Organizer
      The 4th International Workshop on Chromogenic Materials and Devices
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Near-infrared luminescent porphyrin glasses2018

    • Author(s)
      Mitsuhiko Morisue
    • Organizer
      The 4th International Workshop on Chromogenic Materials and Devices
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Porphyrin Glasses That Form Near-Infrared Luminescent Excimer2017

    • Author(s)
      Mitsuhiko Morisue
    • Organizer
      The 2nd International Symposium on Polymeric Materials Based on Element-Block
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2017-01-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポルフィリンガラスを基盤とする固体近赤外発光材料の創製2017

    • Author(s)
      森末光彦, 上野郁也, 清水正毅, 佐々木園, 松井淳, 大曲駿, 中西貴之, 長谷川靖哉
    • Organizer
      第15回無機高分子研究討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] アモルファス状態で近赤外エキシマー発光するポルフィリンガラス2017

    • Author(s)
      森末光彦, 上野郁也, 清水正毅, 佐々木園, 松井淳, 大曲駿, 中西貴之, 長谷川靖哉
    • Organizer
      第15回光化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] BODIPYから亜鉛ポルフィリンへの相補的配位結合に基づくBODIPY -ポルフィリン超分子錯体の構築2017

    • Author(s)
      中野慎也, 清水正毅, 湯村尚史, 森末光彦
    • Organizer
      第15回ホスト・ゲスト超分子化学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] ポルフィリン-BODIPY連結分子の自己組織化2017

    • Author(s)
      中野慎也, 清水正毅, 森末光彦
    • Organizer
      第66回高分子年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 生体の構造を模倣したポルフィリン積層構造の構築とその多彩な機能2017

    • Author(s)
      森末光彦
    • Organizer
      日本技術士会近畿本部化学部会例会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 二重鎖ポルフィリンアレー精密組織体の構築と機能化2017

    • Author(s)
      森末光彦
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 二重鎖形成による巨大ポルフィリン超分子アレーの構築2016

    • Author(s)
      森末光彦, 星野佑紀, 清水正毅, 上村忍, 櫻井伸一
    • Organizer
      第28回配位化合物の光化学討論会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2016-09-15
    • Related Report
      2016 Research-status Report
  • [Presentation] 近赤外エキシマー発光を示す共役ポルフィリンガラス2016

    • Author(s)
      森末光彦, 上野郁也, 清水正毅, 佐々木園, 櫻井伸一, 松井淳, 中西貴之, 長谷川靖哉
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 四極子相互作用によるポルフィリンダイマーの構造制御2016

    • Author(s)
      上野郁也, 清水正毅, 大下浄治, 森末光彦
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] ポルフィリンが示す新規物性2016

    • Author(s)
      森末光彦
    • Organizer
      西日本ナノシート研究会サマーキャンプ2016
    • Place of Presentation
      屋久島
    • Year and Date
      2016-07-22
    • Related Report
      2016 Research-status Report
  • [Book] 元素ブロック材料の創出と応用展開; 中條善樹監修2016

    • Author(s)
      森末光彦
    • Total Pages
      7
    • Publisher
      シーエムシー
    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] 固体凝集状態で近赤外線発光を示すポルフィリンガラス2017

    • Inventor(s)
      森末光彦、佐々木園、中西貴之、長谷川靖哉
    • Industrial Property Rights Holder
      森末光彦、佐々木園、中西貴之、長谷川靖哉
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Acquisition Date
      2018
    • Related Report
      2017 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 固体凝集状態で近赤外線発光を示すポルフィリンガラス2016

    • Inventor(s)
      森末光彦, 佐々木園, 中西貴之, 長谷川靖哉
    • Industrial Property Rights Holder
      森末光彦, 佐々木園, 中西貴之, 長谷川靖哉
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-161750
    • Filing Date
      2016-08-22
    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi