Chemical reactions of transactinide element: Extraction of Rf bromide and sulfate
| Project/Area Number |
16K05815
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Research Collaborator |
KONDO narumi
OUCHI kouki
WATANABE eisuke
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | ラザホージウム（Rf） / 抽出 / 硝酸 / 塩酸 / ラザホージウム / Aliquat 336 / 超重元素 / 超アクチノイド / 硫酸 / 溶媒・固相抽出 |
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| Outline of Final Research Achievements |
Solid-liquid extraction of Zr and Hf (homologues of Rf) and Th (pseudo homologue) in HBr, H2SO4, or HNO3 was carried out toward the extraction of element 104, Rf. Consequently, suitable conditions to investigate the formation of the anionic nitrate complexes of Rf was determined. It is very interesting to know whether the behavior of Rf is similar to that of the homologues having similar electron configuration or to pseudo homologue having larger ionic radius than Zr and Hf (Rf also has larger ionic radius than homologues).
Solvent extraction apparatus for superheavy elements can also be developed in the present study. Therefore, solvent extraction of Rf in HCl was performed at RIKEN. As a result, interestingly, clearly different chloride complex formation of Rf from those of Zr and Hf was observed for the first time.
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| Academic Significance and Societal Importance of the Research Achievements |
超重元素に関しては、実験の難しさからこれまで実験があまり実施されておらず、特に抽出において平衡下の分配比などは取得されてこなかった。このような中であらたに興味深い硝酸系の実験条件を決定できたことは意義深く、実際にRfのデータを得る準備は整っている。
また、溶媒抽出に関してはほとんどデータが得られておらず、装置開発に成功したという時点で大きな成果といえる。また、実際に塩酸系のRfの実験ではこれまでに同族元素と似た挙動しか観測されてこなかった中で、明らかに異なる価数の錯体の形成を確認できたことは非常に興味深い結果である。
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Report
(4 results)
Research Products
(19 results)
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[Journal Article] Observation of the chemical reaction equilibria of element 104, rutherfordium: Solid-liquid extraction of Rf, Zr, Hf and Th with Aliquat 336 resin from HCl2016
Author(s)
T. Yokokita, Y. Kasamatsu, A. Kino, H. Haba, Y. Shigekawa, Y. Yasuda, K. Nakamura, K. Toyomura, Y. Komori, M. Murakami, T. Yoshimura, N. Takahashi, K. Morita, and A. Shinohara
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Journal Title
Dalton Trans.
Volume: 45
Issue: 47
Pages: 18827-18831
DOI
Related Report
Peer Reviewed
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[Journal Article] Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction: A tool for chemical studies with superheavy elements Applied Radiation and Isotopes2016
Author(s)
Y. Kasamatsu, T. Yokokita, K. Toyomura, Y. Shigekawa, H. Haba, J. Kanaya, M. Huang, Y. Ezaki, T. Yoshimura, K. Morita, and A. Shinohara
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Journal Title
Appl. Radiat. Isot.
Volume: 118
Pages: 105-116
DOI
Related Report
Peer Reviewed
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[Presentation] Experimental and Computational Study of Complex Forming Behavior of Zr, Hf, and Th in Nitric Acid - Toward the Chemical Study on Element 104, Rf2019
Author(s)
Eisuke Watanabe, Hidemi Ninomiya, Yudai Shigekawa, Kouki Ouchi, Sho Hayami, Yoshitaka Kasamatsu, Yasutaka Kitagawa, Masayoshi Nakano, Takuya Yokokita, Atsushi Shinohara
Organizer
日本化学会第99春季年会
Related Report
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[Presentation] Anion-exchange Behavior of 88Zr, 175Hf, and 234Th in Nitric Acid for the Experiment of Element 104, Rf2018
Author(s)
Eisuke Watanabe, Hidemi Ninomiya, Narumi Kondo, Yudai Shigekawa, Yuki Yasuda, Kouki Ouchi, Sho Hayami, Yoshitaka Kasamatsu, Takuya Yokokita, Atsushi Shinohara
Organizer
The International Symposium for Materials Scientists III (ISMS III)
Related Report
Int'l Joint Research
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[Presentation] Liquid-liquid extraction of element 104, Rf, in Aliquat 336/HCl system2017
Author(s)
N. Kondo, Y. Kasamatsu, H. Haba, K. Ouchi, M. Nagase, Y. Yasuda, Y. Shigekawa, A. Kanda,Y. Kuboki, Y. Komori, S. Yano, N. Sato, T. Yokokita, A. Shinohara
Organizer
Actinides 2017
Related Report
Int'l Joint Research
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