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Preparation of highly functional porous material by geopolymers based on natural zeolite

Research Project

Project/Area Number 16K06722
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionOkayama University

Principal Investigator

Kameshima Yoshikazu  岡山大学, 環境生命科学研究科, 教授 (50251616)

Co-Investigator(Kenkyū-buntansha) 三宅 通博  岡山大学, 環境生命科学研究科, 特命教授 (30143960)
西本 俊介  岡山大学, 環境生命科学研究科, 准教授 (90435826)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsジオポリマー / 天然ゼオライト / 固化反応 / 気孔率 / マクロ多孔体 / 構造・機能材料 / 無機工業化学 / 環境材料
Outline of Final Research Achievements

In this study, we aimed to preparation of a geopolymer with natural zeolite and improve its functionality. The zeolite was heat-treated at 900 ° C, and cured in wet air in an aqueous solution of NaOH as an activator, and then, a hardened product was obtained. Natural exfoliation during curing was an indicator of geopolymerisation. The obtained hardened product was a geopolymer, and its physical properties were similar with those of previously reported geopolymers. Although the porosity could not be controlled by various additives and degassing, geopolymer with porosity up to about 40% was obtained by controlling the batch composition. From the comparison with clay minerals and glass powder with high silica content like zeolite, the zeolite was found to be suitable for the geopolymer material.

Academic Significance and Societal Importance of the Research Achievements

本研究で扱ったジオポリマーはセメント・コンクリートと異なり耐酸性の基材であることから,酸性雨の影響がある場所でも利用可能な建築材料として利用できる.その様な基材を多孔質化することで,有機物の生分解などで処理水が酸性化した状態でも安定な分離が可能で,既存の多孔体よりも幅広い分野で利用できる新しい分離材料への応用が可能となる.さらに,国内で産出される天然ゼオライトを有効利用できるため,東北地方などでの新たな産業創出に結びつき,震災復興や地方の活性化への一助となることも期待される.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (7 results)

All 2018 2017 2016

All Presentation (7 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] Geopolymeriztion from natural zeolite and its local structure2018

    • Author(s)
      Y. Kameshima, H. Baba, S. Nishimoto, M. Miyake, X. Xue, M. Kanzaki
    • Organizer
      International Symposium on Inorganic and Environmental Materials 2018 (ISIEM2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パイロフィライトのジオポリマー化への熱処理の影響2018

    • Author(s)
      亀島欣一,西本俊介,三宅通博
    • Organizer
      第62回粘土科学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 急冷廃ガラスからのジオポリマーの作製2018

    • Author(s)
      中平拓郎,西本俊介,亀島欣一,三宅通博
    • Organizer
      無機マテリアル学会第137回学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然ゼオライト由来のジオポリマーの局所構造解析2018

    • Author(s)
      亀島欣一,馬場浩樹,西本俊介,三宅通博,薛献宇,神崎正美
    • Organizer
      日本セラミックス協会 2018年年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Preparation of geopolymer from a natural zeolite as a starting material2017

    • Author(s)
      Y. Kameshima,H. Baba, S.Nishimoto,M . Miyake
    • Organizer
      XVI International Clay Conference
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 天然ゼオライト由来のジオポリマーの特性に及ぼすSi/AI比の影響2017

    • Author(s)
      馬場浩樹,亀島欣一,西本俊介,三宅通博
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 天然ゼオライトを原料に用いたジオポリマーの作製2016

    • Author(s)
      馬場浩樹・亀島欣一・西本俊介・三宅通博
    • Organizer
      第29 回秋季シンポジウム
    • Place of Presentation
      広島大学(東広島キャンパス)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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