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Thermal properties of polymer composite analyzed with multi-spectrum thermal imaging method

Research Project

Project/Area Number 16K06768
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Morikawa Junko  東京工業大学, 物質理工学院, 教授 (20262298)

Research Collaborator Ryu Meguya  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高分子 / 熱イメージング / 赤外線カメラ / 赤外線サーモグラフィー / 相転移 / 輻射率温度校正 / 赤外分光イメージング / サーモスペクトロスコピー / サーモスペクトルスコピー / 熱輻射イメージング / がん細胞 / 赤外吸収スペクトル / 熱拡散 / マイクロ流路 / nアルカン / 結晶化 / 熱収縮 / 機能性高分子材料 / 熱伝導率
Outline of Final Research Achievements

The measurement system of thermo-spectroscopy has been developed to obtain infrared thermographical image and Infrared spectroscopic image in microscale simultaneously. In order to estimate the absolute temperature, the thermal emission signal intensity at each temperature and each concentration need to be measured prior to the experiments as a calibration procedure, since the emissivity is directly depending on the concentration and temperature of each component. The developed system was applied to analyze the temperature distribution in the kinetic thermal phenomena such as the phase transition of the heat storage materials and the chemical reaction system such as the styrene radical polymerization. The anisotropic thermal diffusivity in the in-plane direction of polymer composite was also estimated using the photo-thermal method.

Academic Significance and Societal Importance of the Research Achievements

本研究では、赤外分光型熱イメージング同時測定法の開発を行い、サーモスペクトロスコピーと称する新しい分野を世界に先駆けて切り開いた。熱伝導のミクロスケールの可視化のみでなく、 化学反応や相転移を伴う動的な過程の分光情報も同時に取得することで、熱伝導に及ぼす化学構造の変化の寄与を正確に見積もることを可能とした。従来困難であった、化学組成あるいは状態の変化する系での輻射率温度変換による2次元の温度校正を実験的に可能にした。高分子複合系やバイオメディカル分野のサーモスペクトルスコピーによる応用展開では、赤外分光における熱輻射の見積もりの重要性を指摘し、本方法論の有用性を示した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (32 results)

All 2019 2018 2017 2016 Other

All Journal Article (13 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 13 results,  Open Access: 13 results,  Acknowledgement Compliant: 3 results) Presentation (15 results) (of which Int'l Joint Research: 9 results,  Invited: 8 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Analysis of molecular orientation in polymeric spherulite using polarized micro attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopic imaging2019

    • Author(s)
      Hikima Yuta、Morikawa Junko、Kazarian Sergei G.
    • Journal Title

      Analytica Chimica Acta

      Volume: 1065 Pages: 79-89

    • DOI

      10.1016/j.aca.2019.02.017

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High-speed dynamics of temperature distribution in ultrafast (up to 10^8K/s) chip-nanocalorimeters, measured by infrared thermography of high resolution2019

    • Author(s)
      Minakov A.、Morikawa J.、Zhuravlev E.、Ryu M.、van Herwaarden A. W.、Schick C.
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 5 Pages: 054501-054501

    • DOI

      10.1063/1.5066384

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Calibration Procedure for Attenuation Coefficient Measurements in Highly Opaque Media Using Infrared Focal Plane Array (IRFPA) Spectroscopy2018

    • Author(s)
      Kirchner Sara、Narinsamy Sebastien、Sommier Alain、Romano Marta、Ryu Meguya、Morikawa Junko、Leng Jacques、Batsale Jean-Christophe、Pradere Christophe
    • Journal Title

      Applied Spectroscopy

      Volume: 72 Issue: 2 Pages: 177-187

    • DOI

      10.1177/0003702817736320

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microscopic infrared thermography for fast estimation of the thermal properties of thin films2018

    • Author(s)
      Godin A.、Palomo del Barrio E.、Morikawa J.、Duquesne M.
    • Journal Title

      Journal of Applied Physics

      Volume: 124 Issue: 8 Pages: 085111-085111

    • DOI

      10.1063/1.5037931

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Thermal effect on dispersive infrared spectroscopic imaging of prostate cancer tissue2018

    • Author(s)
      Song Cai L.、Ryu Meguya、Morikawa Junko、Kothari Archana、Kazarian Sergei G.
    • Journal Title

      Journal of Biophotonics

      Volume: 11 Issue: 12

    • DOI

      10.1002/jbio.201800187

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Infrared thermo-spectroscopic imaging of styrene radical polymerization in microfluidics2017

    • Author(s)
      Ryu M.、Kimber J.A.、Sato T.、Nakatani R.、Hayakawa T.、Romano M.、Pradere C.、Hovhannisyan A.A.、Kazarian S.G.、Morikawa J.
    • Journal Title

      Chemical Engineering Journal

      Volume: 324 Pages: 259-265

    • DOI

      10.1016/j.cej.2017.05.001

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Orientational Mapping Augmented Sub-Wavelength Hyper-Spectral Imaging of Silk2017

    • Author(s)
      Ryu Meguya、Balcytis Armandas、Wang Xuewen、Vongsvivut Jitraporn、Hikima Yuta、Li Jingliang、Tobin Mark J.、Juodkazis Saulius、Morikawa Junko
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 1-10

    • DOI

      10.1038/s41598-017-07502-3

    • NAID

      120006366663

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Silk: Optical Properties over 12.6 Octaves THz-IR-Visible-UV Range2017

    • Author(s)
      Balcytis Armandas、Ryu Meguya、Wang Xuewen、Novelli Fabio、Seniutinas Gediminas、Du Shan、Wang Xungai、Li Jingliang、Davis Jeffrey、Appadoo Dominique、Morikawa Junko、Juodkazis Saulius
    • Journal Title

      Materials

      Volume: 10 Issue: 4 Pages: 356-356

    • DOI

      10.3390/ma10040356

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Nanoscale chemical mapping of laser-solubilized silk2017

    • Author(s)
      Ryu Meguya、Kobayashi Hanae、Balcytis Armandas、Wang Xuewen、Vongsvivut Jitraporn、Li Jingliang、Urayama Norio、Mizeikis Vygantas、Tobin Mark、Juodkazis Saulius、Morikawa Junko
    • Journal Title

      Materials Research Express

      Volume: 4 Issue: 11 Pages: 115028-115028

    • DOI

      10.1088/2053-1591/aa98a9

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Non-contact temperature field measurement of solids by infrared multispectral thermotransmittance2017

    • Author(s)
      C. Pradere, M. Ryu, A. Sommier, M. Romano, A. Kusiak, J. L. Battaglia, J. C. Batsale, J. Morikawa
    • Journal Title

      Journal of Applied Physics

      Volume: 121 Issue: 8

    • DOI

      10.1063/1.4976209

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Nano-rescaling of gold films on polystyrene: thermal management for SERS2017

    • Author(s)
      A. Balcytis, M. Ryu, G. Seniutinas, P. R. Stoddart, M. A. A. Mamun, J. Morikawa and S. Juodkazis
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 2 Pages: 690-695

    • DOI

      10.1039/c6nr06904e

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Silk fibroin as a water-soluble bio-resist and its thermal properties2016

    • Author(s)
      J. Morikawa, M. Ryu, K. Maximova, A. Balcytis, G. Seniutinas, L. Fan, V. Mizeikis, J. Li, X. Wang, M. Zamengo, X. Wang and S. Juodkazisc
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 14 Pages: 11863-11869

    • DOI

      10.1039/c5ra20201a

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microscale spectroscopic thermal imaging of n-alkanes2016

    • Author(s)
      M. Ryu, M. Romano, J.C. Batsale, C. Pradere, J. Morikawa
    • Journal Title

      Quantitative InfraRed Thermography Journal

      Volume: 2016 Issue: 2 Pages: 1-10

    • DOI

      10.1080/17686733.2016.1234672

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Advanced approaches for micro and nanoscale characterization of thermal tranasport properties in soft materials2019

    • Author(s)
      Morikawa Junko
    • Organizer
      the 6th Thermal Probe Workshop
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ・マイクロスケール熱物性測定:最新の測定技術とソフトマテリアルでの実用事例2019

    • Author(s)
      森川淳子
    • Organizer
      第1回熱エネルギー利用・変換・制御に関わる革新的材料研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Micro-scale Infrared Thermography and its Application to Thermo-Spectroscopy2018

    • Author(s)
      Morikawa Junko
    • Organizer
      Micro-scale Infrared Thermography and its Application to Thermo-Spectroscopy
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermo-spectroscopy in IR waveband and application to a micro-scale heat transfer2018

    • Author(s)
      Morikawa Junko
    • Organizer
      Progress in photoacoustic and photothermal phenomena: focus on biomedical and nanoscale imaging and NDE
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Non-Contact Thermal Analysis with Fast and Micro-Scale Thermographical Imaging2018

    • Author(s)
      Morikawa Junko
    • Organizer
      MRS2018 Fall Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Super-cooling of single micron-sized liquid drops in ultra-fast scanning calorimetry measured by micro-scale thermography2018

    • Author(s)
      Morikawa Junko, Ryu Meguya, Zhuravlev Evgeny, Schick Christoph
    • Organizer
      14th Quantitative InfraRed Thermography Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel instrumentation of thermo-spectroscopy; combination of reflectance and transmittance mode applied to the crystallization process on the nano-membrane2018

    • Author(s)
      Ryu Meguya, Morikawa Junko
    • Organizer
      14th Quantitative InfraRed Thermography Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Micro-scale temperature measurement at the co-flow interface in the micro-fluidics device2018

    • Author(s)
      Ryu Meguya, Morikawa Junko
    • Organizer
      14th Quantitative InfraRed Thermography Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高放熱性コンポジットの熱物性測定2018

    • Author(s)
      森川淳子
    • Organizer
      第65回応用物理学会春季学術講演会 分科企画シンポジウム 無機・有機複合材料で放熱問題に挑む ~物理と応用の最前線~
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Recent Advances in Measurement Technique of Micro-scale Thermography2017

    • Author(s)
      Junko Morikawa
    • Organizer
      QIRT ASIA 2017 (2nd Asian Conference on Quantitative InfraRed Thermography
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ソフトマテリアルの熱物性計測と熱・分光イメージング2017

    • Author(s)
      森川淳子
    • Organizer
      応用物理学会フォノンエンジニアリング研究グループ JST「微小エネ」領域合同研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 温度波ならびに熱イメージングによる熱測定法 の開発2017

    • Author(s)
      森川淳子
    • Organizer
      第53回熱測定討論会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] マイクロ流路中でのスチレン重合反応の熱・赤外分光同時イメージング2016

    • Author(s)
      佐藤 泰斗, 劉 芽久哉, 森川 淳子
    • Organizer
      第52回熱測定討論会
    • Place of Presentation
      徳島大学 常三島キャンパス
    • Year and Date
      2016-09-28
    • Related Report
      2016 Research-status Report
  • [Presentation] 赤外線カメラを用いた、ミクロスケール熱・赤外分光 同時イメージングシステムの構築2016

    • Author(s)
      劉 芽久哉, 佐藤 泰斗, 森川 淳子
    • Organizer
      第52回熱測定討論会
    • Place of Presentation
      徳島大学 常三島キャンパス
    • Year and Date
      2016-09-28
    • Related Report
      2016 Research-status Report
  • [Presentation] Superimpose signal processing method for micro-scale thermal imaging of solar salt at high temperatures2016

    • Author(s)
      J. Morikawa, M. Zamengo, Y. Kato
    • Organizer
      SPIE2016 DEFENCE+ COMMERCIAL SENSEING
    • Place of Presentation
      アメリカ合衆国,メリーランド州バルチモア国際会議場
    • Year and Date
      2016-04-17
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] サーマルデバイス~新素材・新技術による熱の高度制御と高効率利用~2018

    • Author(s)
      森川淳子
    • Total Pages
      448
    • Publisher
      (株)エヌ・ティー・エス
    • Related Report
      2018 Annual Research Report
  • [Book] 熱分析(第4版)2017

    • Author(s)
      森川淳子(分担)
    • Total Pages
      436
    • Publisher
      講談社
    • Related Report
      2016 Research-status Report
  • [Remarks] ナノ薄膜上に高速応答の温度センサーを製作

    • URL

      https://www.titech.ac.jp/news/2018/041484.html

    • Related Report
      2017 Research-status Report
  • [Remarks] A micro-thermometer to record tiny temperature

    • URL

      https://www.titech.ac.jp/english/news/2018/041483.html

    • Related Report
      2017 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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