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Development of a new method for metal deposition based on dynamic equilibria

Research Project

Project/Area Number 16K13627
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionKyoto Institute of Technology

Principal Investigator

Nakanishi Hideyuki  京都工芸繊維大学, 材料化学系, 准教授 (20619655)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsオストワルド熟成 / 過飽和 / 双晶 / 配位子 / トンネル障壁 / 分子吸着 / 塑性変形 / ギブス・トムソン効果 / 曲率 / ラプラス圧 / 界面張力 / 動的平衡 / 金属ナノ粒子 / 自己組織化単分子膜
Outline of Final Research Achievements

Metal nanoparticles have drawn great interest owing to their intriguing properties that are unique to metal confined in nanometer sizes. In the present study, we examined the binding properties of metal nanoparticles and capping molecules, and developed a new methods for the fabrication of electronic conductors using dispersions of metals nanoparticles. Many efforts have been made to transform metal nanoparticles into electrical conductors but most methods required heat treatment at high temperature. In contrast, our method does not require such treatment and allow for the transformation into conductors near room temperature.

Academic Significance and Societal Importance of the Research Achievements

ナノスケールに独自の特性を利用すると、溶媒を介して簡単に金属を成膜することが可能になり、幅広い分野に波及効果が期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (25 results)

All 2018 2017 2016 Other

All Int'l Joint Research (5 results) Journal Article (10 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Hungarian Academy of Sciences/BUTE(ハンガリー)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] National University of Singapore(Singapore)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] BUTE(Hungary)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] BUTE/Sun Yat-Sen University/Hungary Academy of Sciences(ハンガリー)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Correlating material transfer and charge transfer in contact electrification2018

    • Author(s)
      Pandey, R. K., Kakehashi, H., Nakanishi, H. & Soh, S.
    • Journal Title

      J. Phys. Chem. C

      Volume: 122 Issue: 28 Pages: 16154-16160

    • DOI

      10.1021/acs.jpcc.8b04357

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interaction of positively charged gold nanoparticles with cancer cells monitored by in situ label-free optical biosensor and transmission electron microscopy2018

    • Author(s)
      Peter, B., Lagzi, I., Teraji, S., Nakanishi, H., Cervenak, L., Zambo, D., Deak, A., Molnar, K., Truszka, M., Szekacs, I. & Horvath, R.
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 10 Issue: 32 Pages: 26841-26850

    • DOI

      10.1021/acsami.8b01546

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Existence of a precipitation threshold in the electrostatic precipitation of oppositely charged nanoparticles2018

    • Author(s)
      Nakanishi, H., Deak, A., Hollo, G. & Lagzi, I.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 49 Pages: 16062-16066

    • DOI

      10.1002/anie.201809779

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of nanowire length on charge transport in vertically aligned gold nanowire array electrodes2018

    • Author(s)
      Nakanishi, H., Kikuta, I., Teraji, S., Norisuye, T. & Tran-Cong-Miyata, Q.
    • Journal Title

      Langmuir

      Volume: 34 Issue: 51 Pages: 15674-15680

    • DOI

      10.1021/acs.langmuir.8b03089

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] pH mediated kinetics of assembly and disassembly of molecular and nanoscopic building blocks.2018

    • Author(s)
      Toth-Szeles, E., Medveczky, Z., Hollo, G., Horvath, J., Szucs, R., Nakanishi, H. & Lagzi, I.
    • Journal Title

      React. Kinet., Mech. Catal.

      Volume: 123 Issue: 2 Pages: 323-333

    • DOI

      10.1007/s11144-017-1312-x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Reversible and continuously tunable control of charge of close surfaces.2017

    • Author(s)
      Pandey, R. K., Sun, Y., Nakanishi, H. & Soh, S.
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 8 Issue: 24 Pages: 6142-6147

    • DOI

      10.1021/acs.jpclett.7b02763

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Metal nanowire-based hybrid electrodes exhibiting high charge/discharge rates and long-lived electrocatalysis.2017

    • Author(s)
      Pandey, R. K., Kawabata, Y., Teraji, S., Norisuye, T., Tran-Cong-Miayta, Q., Soh, S. & Nakanishi H.
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 41 Pages: 36350-36357

    • DOI

      10.1021/acsami.7b07794

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Metal-Organic Coaxial Nanowire Array Electrodes Combining Large Energy Capacity and High Rate Capability2017

    • Author(s)
      Nakanishi, H., Kikuta, I., Segawa, H., Kawabata, Y., Kishida, R., Norisuye, T. and Tran-Cong-Miyata, Q.
    • Journal Title

      ChemSusChem

      Volume: 10 Issue: 4 Pages: 701-710

    • DOI

      10.1002/cssc.201601310

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Self-assembly of like-charged nanoparticles into Voronoi diagram2016

    • Author(s)
      Zambo, D., Suzuno, K., Pothorszky, S., Bardfalvy, D., Hollo, G., Nakanishi, H., Wang, D., Ueyama, D., Deak, A. and Lagzi, I.
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 36 Pages: 25735-25740

    • DOI

      10.1039/c6cp04297j

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Nanowire electrodes for electrochemical capacitors and nanoparticles for current conduction2016

    • Author(s)
      Nakanishi, H., Kikuta, I., Kawabata, Y., Matsumoto, I., Naitoh, Y., Segawa, H., Norisuye, T. and Q. Tran-Cong-Miyata
    • Journal Title

      ECS Transactions

      Volume: 75 Issue: 11 Pages: 11-15

    • DOI

      10.1149/07511.0011ecst

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 階層的な細孔構造を有するパラジウム多孔体の電極触媒特性2018

    • Author(s)
      寺地智司・中西英行・則末智久・宮田貴章
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 流体を通すパラジウム触媒膜2018

    • Author(s)
      荒木俊哉・中西英行・則末智久・宮田貴章
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノ粒子から成長したパラジウム電極触媒2018

    • Author(s)
      南洋樹・中西英行・則末智久・宮田貴章
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 室温で液体のように流動する金属ナノ粒子2018

    • Author(s)
      中西英行・則末智久・宮田貴章
    • Organizer
      第2回NEXT高分子(関西)交流会第3回企画会議
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Nanowire Electrodes for Electrochemical Capacitors and Nanoparticles for Current Conduction2016

    • Author(s)
      Nakanishi, H.
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Monolithic Nanowire Array Electrodes for Electrochemical Energy Storage2016

    • Author(s)
      Nakanishi, H.
    • Organizer
      ISMAI2016
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Gold/Polypyrrole Coaxial Nanowire Electrodes for Electrochemical Energy Storage2016

    • Author(s)
      Nakanishi, H.
    • Organizer
      EMN meeting
    • Place of Presentation
      Dubrovnik, Croatia
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 金ナノ粒子における分子/金属結合の平衡反応を利用した新しい成膜法の創出2016

    • Author(s)
      内藤康彬・松本郁子・中西英行・則末智久・宮田貴章
    • Organizer
      第65回高分子年次大会
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2016 Research-status Report
  • [Presentation] 銀ナノ粒子の表面設計2016

    • Author(s)
      梯大翔・中西英行・則末智久・宮田貴章
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] 金属ナノ粒子を液状化する方法2018

    • Inventor(s)
      中西英行
    • Industrial Property Rights Holder
      京都工芸繊維大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-089380
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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