| Project/Area Number |
16K13954
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
Abe Manabu 広島大学, 理学研究科, 教授 (30273577)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | curved molecule / pai electron / アルケン / π軌道 / 局面π電子系 / ビシクロ[1.1.0]ブト－１(3)－エン / 局面π電子構造 / 量子化学計算 / カルベン / スピン多重度 / π結合 / 歪化合物 |
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| Outline of Final Research Achievements |
Alkenes usually have a planar structure, π orbitals are extended in the direction perpendicular to the molecular plane, which are involved in absorption and emission of light energy, electron transfer. In recent years, a carbon material having a π-conjugated electron system as represented by fullerenes and carbon nanotubes has drawn attention as a next-generation functional material. The reason is the unique electron transfer ability and low excitation energy generated from the π electron system. However, the understanding of the electronic properties generated by the π-electron system is inexperienced, and the effects of the π-electron system are not clearly understood. In this research, the electronic property of bicyclo [1.1.0] but- -1 (3) -ene was examined as an example of the distorted π-electron compound.
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