Photogeneration of amorphous metal-organic frameworks from metal-containing ionic liquids

Research Project

Project/Area Number	16K13965
Research Category	Grant-in-Aid for Challenging Exploratory Research
Allocation Type	Multi-year Fund
Research Field	Inorganic chemistry
Research Institution	Kobe University
Principal Investigator	Mochida Tomoyuki 神戸大学, 理学研究科, 教授 (30280580)
Co-Investigator(Kenkyū-buntansha)	桑原大介電気通信大学, 研究設備センター, 准教授 (50270468)
Project Period (FY)	2016-04-01 – 2018-03-31
Project Status	Completed (Fiscal Year 2017)
Budget Amount *help	¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000) Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000) Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords	イオン液体 / 配位高分子 / 光反応 / ガス吸脱着 / ルテニウム錯体 / 有機金属錯体
Outline of Final Research Achievements	Ionic liquids were developed that generate amorphous coordination polymers upon UV irradiation. The ionic liquids are composed of cationic ruthenium sandwich complexes and polycyano anions. Upon photoirradiation, the arene ligand in the cation is eliminated and coordination polymer is formed by coordination of the anion to the ruthenium ion. The photogenerated solids exhibited gas adsorption properties due to their microporous structures.

Report

(3 results)