| Project/Area Number |
16K14049
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
Ogawa Akiya 大阪府立大学, 工学(系)研究科(研究院), 教授 (30183031)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 環境化学 / グリーンケミストリー / リン / フルオラス / 再利用 / リン資源 / リサイクル触媒 / 有機典型元素化学 / 有機化学 / 環境技術 / 触媒・化学プロセス |
|---|
| Outline of Final Research Achievements |
Radical substitution on phosphine atom and catalytic reusability of recyclable fluorous phosphine compounds were investigated. By using commercially available phosphine carbonyl reagents, simple synthetic method of fluorous phosphine compounds was established. Controlling of reaction temperature led to moderate yields of the corresponding fluorous phosphine compounds. In addition, these fluorous phosphine compounds were easily recovered by Fluorous Biphasic System. The fluorous phosphine compounds were used reusable and metal complexes were also investigated.
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