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CO2 cross coupling

Research Project

Project/Area Number 16K14050
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Green/Environmental chemistry
Research InstitutionTokyo University of Science

Principal Investigator

Sugimoto Hiroshi  東京理科大学, 工学部工業化学科, 教授 (20271330)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords二酸化炭素 / 炭酸エステル / クロスカップリング / 二酸化炭素化学固定 / 有機合成化学 / 二酸化炭素排出削減 / 触媒・化学プロセス / 有機工業化学
Outline of Final Research Achievements

In order to develop a new method for synthesis of organic carbonates, various metal complexes were investigated in the cross-coupling type carbon-dioxide transformation. In the present study has been focused the selection of transition metal complex which enables fixation of carbon dioxide in gas phase.
As the results of investigations by using sodium salts of cobalt(I) ate complex having salen-type or porphyrin-type ligand as a key nucleophilic reagent, sodium cobalt(I) porphyrin complex bearing bulky peripheral groups, such as 2,4,6-trimethylphenyl group, was found to the best complex to catch carbon dioxide in high efficiency to give a long-lived sodium carbonate species.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (19 results)

All 2018 2017 2016

All Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 1 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis of CO2-derived polycarbonates with high glass transition temperatures2018

    • Author(s)
      Rie Arai, Keitaro Seto, Andrew A. Bell, Hiroshi Sugimoto
    • Journal Title

      Polymer Journal

      Volume: 50 Issue: 4 Pages: 301-307

    • DOI

      10.1038/s41428-017-0020-8

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Alternative Copolymerization of Carbon Dioxide and Epichlorohydrin, and Successive Quaternization of Obtained Aliphatic Polycarbonate2017

    • Author(s)
      早野 重孝,新井 理恵,杉本 裕
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 74 Issue: 6 Pages: 534-541

    • DOI

      10.1295/koron.2017-0041

    • NAID

      130006218914

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Copolymerization of CO2 and Diols2016

    • Author(s)
      M. Tamura, K. Ito, M. Honda, Y. Nakagawa, H. Sugimoto, and K. Tomishige*
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1

    • DOI

      10.1038/srep24038

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of four- and six-armed star-shaped polycarbonates by immortal alternating copolymerization of CO2 and propylene oxide2016

    • Author(s)
      H. Sugimoto,* H. Goto, S. Honda, R. Yamada, Y. Manabe, and S. Handa
    • Journal Title

      Polymer Chemistry

      Volume: 7 Issue: 23 Pages: 3906-3912

    • DOI

      10.1039/c6py00558f

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polymer cyclization inhibits thermal decomposition of carbon-dioxide-derived poly(propylene carbonate)s2016

    • Author(s)
      S. Honda* and H. Sugimoto*
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 54 Issue: 20 Pages: 3336-3342

    • DOI

      10.1002/pola.28222

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Carbon Dioxide-Derived Immortal Brush Macromolecules with Poly(propylene carbonate) Side Chains2016

    • Author(s)
      S. Honda* and H. Sugimoto*
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 18 Pages: 6810-6816

    • DOI

      10.1021/acs.macromol.6b01505

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2とジオールからポリカーボネートを直接合成! 安全かつ環境にやさしい夢の合成法2016

    • Author(s)
      田村 正純,中川 善直,杉本 裕,冨重 圭一
    • Journal Title

      化学

      Volume: 71 Pages: 19-24

    • Related Report
      2016 Research-status Report
  • [Presentation] 金属塩触媒による二酸化炭素とオキセタンからの六員環カルボナート合成2018

    • Author(s)
      中村 亮,杉本 裕
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属錯体による共重合反応の制御 [80] アルミニウムポルフィリン錯体-第四級アンモニウム塩系触媒による二酸化炭素とオキセタンの共重合2017

    • Author(s)
      中村 亮,杉本 裕
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 二酸化炭素を直接原料とする高分子合成 [21] アルミニウムポルフィリン錯体による二酸化炭素とオキセタンの共重合2017

    • Author(s)
      中村 亮,江刺家 勇,杉本 裕
    • Organizer
      第6回JACI/GSCシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属錯体による共重合反応の制御 [79] 金属ポルフィリン錯体による二酸化炭素とオキセタンの共重合2017

    • Author(s)
      中村 亮,江刺家 勇,杉本 裕
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属錯体による共重合反応の制御 [78] 側鎖に複数のヒドロキシ基を有する新規二酸化炭素由来ポリカルボナートの合成と物性2017

    • Author(s)
      齊藤 遼,有留 瑛美,杉本 裕
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属錯体による共重合反応の制御 [77] 金属ポルフィリン錯体による二酸化炭素とエポキシドの交互共重合における可視光効果2017

    • Author(s)
      川路 穣照,杉本 裕
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of Polycarbonates by Alternating Copolymerization of Carbon Dioxide and Epoxides with High Glass Transition Temperature2016

    • Author(s)
      R. Arai, H. Sugimoto, and K. Seto
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      福岡国際会議場(福岡県福岡市)
    • Year and Date
      2016-12-16
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属錯体による共重合反応の制御 [76] 高いガラス転移温度を示す二酸化炭素由来ポリカルボナートの合成2016

    • Author(s)
      新井 理恵,杉本 裕
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 二酸化炭素を直接原料とする高分子合成 [20] コバルトポルフィリン錯体-N-ヘテロ環状カルベン触媒系によるポリカルボナートの合成2016

    • Author(s)
      川路 穣照,杉本 裕
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      ANAクラウンプラザホテル神戸(兵庫県神戸市)
    • Year and Date
      2016-06-03
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属錯体による共重合反応の制御 [75] コバルトポルフィリン-N-ヘテロ環状カルベン触媒系による二酸化炭素とエポキシドの交互共重合2016

    • Author(s)
      川路 穣照,杉本 裕
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Book] 二酸化炭素を用いた化学品製造技術2016

    • Author(s)
      杉本 裕(監修)
    • Total Pages
      310
    • Publisher
      S&T出版
    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] 脂肪族ポリカルボナートの製造方法2017

    • Inventor(s)
      杉本 裕
    • Industrial Property Rights Holder
      杉本 裕
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2021-01-27  

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