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Quasi-quantitative characterization of defect density in SiC substrate after thermal oxidation by photo-assited capacitance measurement

Research Project

Project/Area Number 16K14227
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionThe University of Tokyo

Principal Investigator

Kita Koji  東京大学, 大学院工学系研究科(工学部), 准教授 (00343145)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords電子・電気材料 / 表面・界面物性 / 半導体物性 / 電子デバイス・機器 / 光照射 / 炭化ケイ素 / 界面準位密度 / インピーダンス解析 / 欠陥準位 / 光吸収
Outline of Final Research Achievements

Reduction of defect state density in the energy range corresponding to semiconductor’s bandgap is inevitable for the operation of MOS devices, however, for the wide-bandgap semiconductors including SiC, the defect states locating in near-interface oxide, and those with the energy level near the middle of the bandgap often overlooked in conventional characterization techniques using MOS capacitors, due to a significantly long time constant of the electron emission from those states. We proposed an alternative method to estimate the profiles of such defect states at SiC MOS interfaces, based on the analysis of the carrier capturing process by voltage bias sweep just after the removal of the trapped carriers by irradiation of monochromatic ultraviolet or visible light. Using this method, we also clarified the difference of deep defect level profiles at SiC MOS interface formed by different oxidation processes of SiC.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (34 results)

All 2018 2017 2016 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 3 results) Presentation (26 results) (of which Int'l Joint Research: 12 results,  Invited: 3 results) Remarks (2 results)

  • [Journal Article] Demonstration of Large Flatband Voltage Shift by Designing Al2O3/SiO2 Laminated Structures with Multiple Interface Dipole Layers2017

    • Author(s)
      Koji Kita and Hironobu Kamata
    • Journal Title

      ECS Transactions

      Volume: 80 (1) Issue: 1 Pages: 379-385

    • DOI

      10.1149/08001.0379ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of origins of the critically different MOS interface characteristics between dry-oxidized and wet-oxidized silicon carbide2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, Hiroyuki Kajifusa, Kohei Kuroyama, Kei Ishinoda
    • Journal Title

      Microelectronic Engineering

      Volume: 178 Pages: 186-189

    • DOI

      10.1016/j.mee.2017.05.042

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Opportunity of dipole layer formation at non-SiO 2 dielectric interfaces in two cases: Multi-cation systems and multi-anion systems2017

    • Author(s)
      Fei Jiayang、Kita Koji
    • Journal Title

      Microelectronic Engineering

      Volume: 178 Pages: 225-229

    • DOI

      10.1016/j.mee.2017.05.035

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anomalous flatband voltage shift of AlFxOy/Al2O3 MOS capacitors: A consideration on dipole layer formation at dielectric interfaces with different anions2017

    • Author(s)
      Jiayang Fei, Ryota Kunugi, Takanobu Watanabe, and Koji Kita
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 16 Pages: 1629071-6

    • DOI

      10.1063/1.4980059

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of Al2O3/SiO2 laminated stacks with multiple interface dipole layers to achieve large flatband voltage shifts of MOS capacitors2017

    • Author(s)
      Hironobu Kamata and Koji Kita
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 10

    • DOI

      10.1063/1.4978223

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Estimation of near-interface oxide trap density at SiO2/SiC metal-oxide-semiconductor interfaces by transient capacitance measurements at various temperatures2016

    • Author(s)
      Yuki Fujino and Koji Kita
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 8

    • DOI

      10.1063/1.4961871

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Photo-assisted CV測定で評価するNITにみるNO-POAとwet-POA界面特性の違い2018

    • Author(s)
      西田水輝,作田良太,平井悠久,喜多浩之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al2O3/SiO2, MgO/SiO2, MgO/Al2O3各界面におけるダイポール起因のVFBシフトの温度依存性の違い2018

    • Author(s)
      濱口高志,喜多浩之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al2O3/SiO2界面のダイポール層の発現と抑制を決定づける因子の実験的検討2017

    • Author(s)
      鎌田啓伸,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜,神奈川県横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Opportunity for dipole layer formation at an non-SiO2 dielectric interface - MgO/Al2O32017

    • Author(s)
      Jiayang Fei and Koji Kita
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜,神奈川県横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 4H-SiC MOS界面特性の制御のための熱酸化プロセスの設計2017

    • Author(s)
      喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜,神奈川県横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 4H-SiC m面上にドライ+ウェット酸化プロセスにより形成されたMOS界面の界面準位密度および電気的ストレスに対する安定性のウェット酸化条件による変化2017

    • Author(s)
      黒山滉平,平井悠久,山本建策,林 真理子,細川 徳一,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜,神奈川県横浜市
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] ダイポール層の選択的発現を利用したAl2O3/SiO2の繰り返し構造における大きなフラットバンド電圧シフト2017

    • Author(s)
      鎌田啓伸,喜多浩之
    • Organizer
      電子デバイス界面テクノロジー研究会 ―材料・プロセス・デバイス特性の物理― 第22回研究会
    • Place of Presentation
      東レ総合研修センター,静岡県三島市
    • Year and Date
      2017-01-19
    • Related Report
      2016 Research-status Report
  • [Presentation] Demonstration of a large Vfb shift induced by selectively formed multiple dipole layers in Al2O3/SiO2 laminated dielectric stacks2017

    • Author(s)
      Hironobu Kamata and Koji Kita
    • Organizer
      48th IEEE Semiconductor Interface Specialists Conference (SISC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Deep Trap and Near-interface Oxide Trap Density at SiO2/SiC Interface by Photo-assisted CV Measurement2017

    • Author(s)
      Mizuki Nishida, Hirohisa Hirai and Koji Kita
    • Organizer
      2017 International Workshop on Dielectric Thin Films for Future Electron Devices (2017 IWDTF)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Temperatures Induced Anomalous Change in Effective Charges of Al2O3/SiO2 Interface Dipole Layer2017

    • Author(s)
      Siri Nittayakasetwat and Koji Kita
    • Organizer
      2017 International Workshop on Dielectric Thin Films for Future Electron Devices (2017 IWDTF)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 4H-SiC熱酸化に伴う基板表面領域における酸素原子侵入とそれに対する酸化条件の影響2017

    • Author(s)
      平井悠久,喜多浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第4回講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Demonstration of Large Flatband Voltage Shift by Designing Al2O3/SiO2 Laminated Structures with Multiple Interface Dipole Layers2017

    • Author(s)
      Koji Kita and Hironobu Kamata
    • Organizer
      232nd The Electrochemical Society (ECS) Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interface-Selective Low-Temperature Wet-O2 Annealing to Enhance 4H-SiC (0001) MOSFET Mobility by Improving Near Interface SiO2 Quality2017

    • Author(s)
      Hirohisa Hirai, Kei Ishinoda and Koji Kita
    • Organizer
      International Conference on Silicon Carbide and Related Materials (ICSCRM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interface Dipole Layers between Two Dielectrics: Considerations on Physical Origins and Opportunities to Control Their Formation2017

    • Author(s)
      Koji Kita, Hironobu Kamata, and Jiayang Fei
    • Organizer
      2017 International Conference on Solid State Devices and Materials (SSDM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Consideration on the interfacial dipole layer formation at non-SiO2 oxide interfaces in the examples of MgO/Al2O3 and HfO2/Al2O32017

    • Author(s)
      Jiayang Fei and Koji Kita
    • Organizer
      2017 International Conference on Solid State Devices and Materials (SSDM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 4H-SiC MOSキャパシタにおける遅い欠陥準位の光照射により観測されるC-V特性ヒステリシス解析による評価2017

    • Author(s)
      西田水輝,喜多浩之
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Anomalous temperature dependence of dipole layer strength at the Al2O3/SiO2 interface2017

    • Author(s)
      iri Nittayakasetwa, Hironobu Kamata and Koji Kita
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al2O3/SiO2界面のダイポール層の生成・抑制の制御 -界面の組成急峻性の与える効果-2017

    • Author(s)
      鎌田啓伸,喜多浩之
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Opportunity of dipole layer formationat non-SiO2 dielectric interfaces in two cases: multi-cation systems and multi-anion systems2017

    • Author(s)
      Jiayang Fei and Koji Kita
    • Organizer
      20th Conference on Insulating Films on Semiconductors (INFOS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of Origins of the Critically Different MOS Interface Characteristics between Dry-oxidized and Wet-Oxidized Silicon Carbide2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, Hiroyuki Kajifusa, Kohei Kuroyama and Kei Ishinoda
    • Organizer
      20th Conference on Insulating Films on Semiconductors (INFOS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 4H-SiC m 面ウェット酸化によるMOS 界面の電気特性と界面近傍SiO2 微視的構造の特徴の相関2016

    • Author(s)
      黒山 滉平,平井 悠久,山本 建策,林 真理子,喜多 浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第3回講演会
    • Place of Presentation
      つくば国際会議場,茨城県つくば市
    • Year and Date
      2016-11-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Design of Al2O3/SiO2 Laminated Stacks with Mutiple Interface Dipole Layers to Induce Large Flatband Voltage Shifts of MOS Capacitors2016

    • Author(s)
      Hironobu Kamata and Koji Kita
    • Organizer
      2016 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      つくば国際会議場,茨城県つくば市
    • Year and Date
      2016-09-27
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study on Dipole Layer Formation and its Origin at Al2O3/AlFxOy and Al2O3/AlNxOy Multi-anion Dielectric Interfaces by considering Anion Areal Density and Valence Differences2016

    • Author(s)
      Jiayang Fei, Ryota Kunugi, Takanobu Watanabe and Koji Kita
    • Organizer
      2016 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      つくば国際会議場,茨城県つくば市
    • Year and Date
      2016-09-27
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Opportunities to Design Thermal Oxidation and Post-OxidationProcesses to Control 4H-SiC MOS Interface Characteristics2016

    • Author(s)
      Koji Kita
    • Organizer
      2016 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      つくば国際会議場,茨城県つくば市
    • Year and Date
      2016-09-27
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Consideration on the Origin of Dipole Layer Formation at Dielectric Interfaces with Different Anions (Fluorine, Oxygen and Nitrogen)2016

    • Author(s)
      Jiayang Fei, Ryota Kunugi, Takanobu Watanabe, and Koji Kita
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ,新潟県新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 界面近傍のSiO2微視的構造とMOS界面の電気特性から見た4H-SiC m面のウェット酸化により形成されたMOS界面の特徴2016

    • Author(s)
      黒山 滉平,平井 悠久,山本 建策,林 真理子,喜多 浩之
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ,新潟県新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Remarks] 東京大学大学院工学系研究科マテリアル工学専攻 機能性ナノ薄膜工学 喜多研究室

    • URL

      http://www.scio.t.u-tokyo.ac.jp/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京大学大学院工学系研究科マテリアル工学専攻 喜多研究室

    • URL

      http://www.scio.t.u-tokyo.ac.jp/index.html

    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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