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Establishment and application of quantitative analytical method for lithium distribution of lithium-ion battery electrodes using laser-induced breakdown spectroscopy

Research Project

Project/Area Number 16K14444
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Metal making/Resorce production engineering
Research InstitutionTohoku University

Principal Investigator

Imashuku Susumu  東北大学, 金属材料研究所, 准教授 (40606620)

Co-Investigator(Renkei-kenkyūsha) WAGATSUMA Kazuaki  東北大学, 金属材料研究所, 教授 (30158597)
SUZUKI Shigeru  東北大学, 多元物質科学研究所, 教授 (40143028)
FUJIEDA Shun  東北大学, 多元物質科学研究所, 助教 (60551893)
KAWAMATA Toru  東北大学, 多元物質科学研究所, 助教 (90638355)
Research Collaborator TAGUCHI Hiroyuki  
KASHIWAKURA Shunsuke  
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsレーザ誘起プラズマ分光法 / リチウムイオン電池 / 反応分布 / リチウム分析 / リチウム元素マッピング / 負極 / 3次元分布 / 元素マッピング
Outline of Final Research Achievements

In the present study, we established a method to obtain the lithium distribution of lithium-ion battery cathode (LiCoO2 as an active material) and anode (graphite) using laser-induced breakdown spectroscopy (LIBS) measurements. Linearity of the calibration curve of lithium was improved by performing LIBS measurement in a reduced argon atmosphere of 1000 Pa. We could quantitatively or semi- quantitatively display lithium distribution of the cathode and anode after charge-discharge tests by measuring them in the reduced argon atmosphere.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (11 results)

All 2017

All Journal Article (1 results) Presentation (10 results) (of which Invited: 1 results)

  • [Journal Article] Observation of reaction distribution in electrodes of lithium-ion battery using laser-induced breakdown spectroscopy2017

    • Author(s)
      Hiroyuki Taguchi, Susumu Imashuku, Shunsuke Kashiwakura, Kazuaki Wagatsuma, Shun Fujieda, Toru Kawamata, Shigeru Suzuki
    • Journal Title

      ALC’17 Proceedings

      Volume: 1

    • Related Report
      2017 Annual Research Report
  • [Presentation] レーザー誘起プラズマ発光分析法を用いたリチウムイオン電池正極中の充放電過程におけるリチウム原子分布測定2017

    • Author(s)
      田口洋行・今宿晋・柏倉俊介・我妻和明・藤枝俊・鈴木茂
    • Organizer
      日本鉄鋼協会第173回春季講演大会
    • Place of Presentation
      首都大東京(東京都八王子市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Research-status Report
  • [Presentation] リチウムの直接測定によるリチウムイオン電池電極における不均一反応の観察2017

    • Author(s)
      田口洋行・今宿晋・柏倉俊介・我妻和明・藤枝俊・鈴木茂
    • Organizer
      日本鉄鋼協会「金属およびその関連材料に対する量子線解析」シンポジウム
    • Place of Presentation
      岩松旅館(宮城県仙台市)
    • Year and Date
      2017-02-10
    • Related Report
      2016 Research-status Report
  • [Presentation] レーザー誘起プラズマ発光分光法を用いたリチウムイオン電池電極のリチウム分布測定2017

    • Author(s)
      今宿 晋
    • Organizer
      第2回製錬関係討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] リチウムイオン電池中の不均一反応解析におけるレーザー誘起プラズマ発光分光法とX線吸収分光法の比較2017

    • Author(s)
      田口 洋行, 今宿 晋, 柏倉 俊介, 我妻 和明, 藤枝 俊, 川又 透, 鈴木 茂
    • Organizer
      日本鉄鋼協会第174回秋季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] リチウムイオン電池電極におけるリチウムの分布測定(LIBS)と遷移金属価数分布測定(XAS)の比較2017

    • Author(s)
      田口 洋行, 今宿 晋, 柏倉 俊介, 我妻 和明, 藤枝 俊, 川又 透, 鈴木 茂
    • Organizer
      第53回X線分析討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 走査レーザー誘起プラズマ発光分光法を用いたリチウムイオン電池中のリチウム原子の空間分布解析2017

    • Author(s)
      田口 洋行, 今宿 晋, 柏倉 俊介, 我妻 和明, 藤枝 俊, 川又 透, 鈴木 茂
    • Organizer
      第16回日本金属学会東北支部研究発表大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] レーザー誘起プラズマ発光分析法を用いたリチウムの定量分析による電池材料の不均一反応分布の観察2017

    • Author(s)
      田口 洋行, 今宿 晋, 柏倉 俊介, 我妻 和明, 藤枝 俊, 川又 透, 鈴木 茂
    • Organizer
      第133回東北大学金属材料研究所講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 走査レーザー誘起プラズマ発光分光法を用いたリチウムイオン電池中のリチウム原子の空間分布解析2017

    • Author(s)
      田口 洋行, 今宿 晋, 柏倉 俊介, 我妻 和明, 藤枝 俊, 川又 透, 鈴木 茂
    • Organizer
      第134回東北大学金属材料研究所講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Observation of reaction distribution in electrodes of lithium-ion battery using laser-induced breakdown spectroscopy2017

    • Author(s)
      Hiroyuki Taguchi, Susumu Imashuku, Shunsuke Kashiwakura, Kazuaki Wagatsuma, Shun Fujieda, Toru Kawamata, Shigeru Suzuki
    • Organizer
      11th International Symposium on Atomic Level Characterizations for New Materials and Devices ’17
    • Related Report
      2017 Annual Research Report
  • [Presentation] Observation of lithium distribution on lithium-ion battery cathode by laser-induced breakdown spectroscopy2017

    • Author(s)
      Susumu Imashuku
    • Organizer
      第3回 東北大&GREEN合同シンポジウム(第16回GREENシンポジウム)
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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