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Molecular recognition by the surface electrical charge control under the solar-light irradiation and photocatalytic selective hydrogenation

Research Project

Project/Area Number 16K14478
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionOsaka University

Principal Investigator

Mori Kohsuke  大阪大学, 工学研究科, 准教授 (90423087)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsプラズモン / 選択水素化 / 選択的水素化 / プラズモン触媒 / 合金ナノ粒子 / 表面プラズモン共鳴 / 選択的水素化反応 / 分子認識能
Outline of Final Research Achievements

In this research, I developed the photocatalysts with novel functions enabling efficient and selective hydrogenation under solar-light irradiation. For example, the Pd/Ag bimetallic nanostructures were developed, in which Pd NPs were synthesized by a facile LSPR-assisted deposition on the highly dispersed Ag NPs with different sizes and morphologies under visible light irradiation. It can be envisaged and herein demonstrated that the plasmonic metal (Ag) with catalytically active component (Pd) can create a heterostructure exhibiting efficient catalytic activity and selectivity in the photocatalytic selective hydrogenation by the molecular recognition induced by the surface electrical charge control.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (31 results)

All 2018 2017 2016 Other

All Journal Article (21 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 20 results,  Open Access: 16 results,  Acknowledgement Compliant: 3 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 7 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Enhancement of plasmonic activity by Pt/Ag bimetallic nanocatalyst supported on mesoporous silica in the hydrogen production from hydrogen storage material2018

    • Author(s)
      P. Verma, K. Yuan, Y. Kuwahara, K. Mori, H. Yamashita
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 223 Pages: 10-15

    • DOI

      10.1016/j.apcatb.2017.05.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Plasmonic Au@Pd Nanoparticles Supported on a Basic Metal-Organic Framework: Synergic Boosting of H2 Production from Formic Acid2017

    • Author(s)
      Meicheng Wen, Kohsuke Mori, Yasutaka Kuwahara, Hiromi Yamashita
    • Journal Title

      ACS Energy Letters

      Volume: 2 Issue: 1 Pages: 1-7

    • DOI

      10.1021/acsenergylett.6b00558

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement of Ag-based Plasmonic Photocatalysis in the Hydrogen Production from Ammonia Borane by the Assist of Single-Site Ti-Oxide Moiety within the Silica Framework2017

    • Author(s)
      Priyanka Verma, Yasutaka Kuwahara, Kohsuke Mori, and Hiromi Yamashita
    • Journal Title

      Chemistry - A European Journal

      Volume: 23 Issue: 15 Pages: 3616-3622

    • DOI

      10.1002/chem.201604712

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Controlled synthesis of carbon-supported Co catalysts from single-sites to nanoparticles: characterization of the structural transformation and investigation of their oxidation catalysis2017

    • Author(s)
      K. Nakatsuka, T. Yoshii, Y. Kuwahara, K. Mori, H. Yamashita
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 7 Pages: 4967-4974

    • DOI

      10.1039/c6cp06388h

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Shape Effect of MnO<i><sub>x</sub></i>-Decorated CeO<sub>2</sub> Catalyst in Diesel Soot Oxidation2017

    • Author(s)
      K. Mori, Y. Miyauchi, Y. Kuwahara, and H. Yamashita
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 90 Issue: 5 Pages: 556-564

    • DOI

      10.1246/bcsj.20170022

    • NAID

      130006770719

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Single-Atom Ru Catalyst Bound on a Layered Double Hydroxide for Hydrogenation of CO2 to Formic Acid2017

    • Author(s)
      Kohsuke Mori, Tomohisa Taga, Hiromi Yamashita
    • Journal Title

      ACS Catalysis

      Volume: 7 Issue: 5 Pages: 3147-3151

    • DOI

      10.1021/acscatal.7b00312

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Specific Enhancement of Activity of Carbon-supported Single-site Co Catalyst in the Microwave-assisted Solvent-free Aerobic Oxidation2017

    • Author(s)
      T. Yoshii, K. Nakatsuka, Y. Kuwahara, K. Mori, H. Yamashita
    • Journal Title

      Chem. Lett.

      Volume: 印刷中 Issue: 6 Pages: 789-791

    • DOI

      10.1246/cl.170118

    • NAID

      130005689359

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] High Surface Area Plasmonic MoO3-x: Rational Synthesis and Enhanced Ammonia Borane Dehydrogenation Activity2017

    • Author(s)
      Haibo Yin, Yasutaka Kuwahara, Kohsuke Mori, Hefeng Cheng, Meicheng Wen, Hiromi Yamashita
    • Journal Title

      Journal of Materials Chemistry A [Inside Front Cover]

      Volume: 5 Issue: 19 Pages: 8946-8953

    • DOI

      10.1039/c7ta01217a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Phenylamine-functionalized mesoporous silica supported PdAg nanoparticles: a dual heterogeneous catalyst for the formic acid/CO2-mediated chemical hydrogen delivery/storage2017

    • Author(s)
      Kohsuke Mori, Shinya Masuda, Hiromasa Tanaka, K. Yoshizawa, Michel Che, and Hiromi Yamashita
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 34 Pages: 4677-4680

    • DOI

      10.1039/c7cc00864c

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of Mesoporous Silica Supported Ag Nanorods-based Bimetallic Catalysts and Investigation of Their Plasmonic Activity under Visible Light Irradiation2017

    • Author(s)
      Priyanka Verma, Yasutaka Kuwahara, Kohsuke Mori, Hiromi Yamashita
    • Journal Title

      Catalysis Science & Technology

      Volume: 7 Issue: 12 Pages: 2551-2558

    • DOI

      10.1039/c7cy00321h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Design and Architecture of Metal Organic Frameworks for Visible Light Enhanced Hydrogen Production2017

    • Author(s)
      Meicheng Wen, Kohsuke Mori, Yasutaka Kuwahara, Taicheng An, Hiromi Yamashita
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 218 Pages: 555-569

    • DOI

      10.1016/j.apcatb.2017.06.082

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] PdCuCr Ternary Nanoparticles Constructed in Situ within a Basic Resin: Enhanced Activity for the Dehydrogenation of Formic Acid2017

    • Author(s)
      Kohsuke Mori, Kohei Naka, Shinya Masuda, KKohei Miyawaki, Hiromi Yamashita
    • Journal Title

      ChemCatChem

      Volume: 9 Issue: 18 Pages: 2456-2462

    • DOI

      10.1002/cctc.201700595

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mesoporous Silica Supported PdAg Bimetallic Nanoparticles as a Plasmonic Catalyst for Chemoselective Hydrogenation of p-Nitrostyrene under Visible Light Irradiation2017

    • Author(s)
      P. Verma, M. Navlani-Garc&iacute;a, Y. Kuwahara, K. Mori, and H. Yamashita
    • Journal Title

      J. Chem. Sci.

      Volume: 129 Issue: 11 Pages: 1661-1669

    • DOI

      10.1007/s12039-017-1364-5

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production of H2 from Ammonia Borane Solution Utilizing Surface Plasmon Resonance Enhancement of Photocatalytic Activity with Pd Nanoparticle Decorated-Cu2-xS Nanowires2017

    • Author(s)
      P.-H. Liu, M. Wen, C.-S. Tan, M. Navlani-Garc&iacute;a, Y. Kuwahara, K. Mori, H. Yamashita, L.-J, Chen
    • Journal Title

      Nano Energy

      Volume: 31 Pages: 57-63

    • DOI

      10.1016/j.nanoen.2016.10.064

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Non-Noble-Metal Nanoparticle Supported on Metal-Organic Framework as an Efficient and Durable Catalyst for Promoting H2 Production from Ammonia Borane under Visible Light Irradiation2016

    • Author(s)
      Meicheng Wen, Yiwen Cui, Yasutaka Kuwahara, Kohsuke Mori, Hiromi Yamashita
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 8 Issue: 33 Pages: 21278-21284

    • DOI

      10.1021/acsami.6b04169

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Design Strategy of Supported Metal Complexes on the Solid Matrices for Visible-Light-Driven Molecular Transformations2016

    • Author(s)
      Kohsuke Mori, Hiromi Yamashita
    • Journal Title

      Chemistry - A European Journal[Minireviews]

      Volume: 22 Issue: 32 Pages: 11122-11137

    • DOI

      10.1002/chem.201600441

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrogen Doped Metal Oxide Semiconductors with Exceptional and Tunable Localized Surface Plasmon Resonances2016

    • Author(s)
      H. Cheng, M. Wen, X. Ma, Y. Kuwahara, K. Mori, Y. Dai, B. Huang, H. Yamashita
    • Journal Title

      Journal of American Chemical Society

      Volume: 138 Issue: 29 Pages: 9316-9324

    • DOI

      10.1021/jacs.6b05396

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The effect of residual Zr on the catalytic oxidation property of skeletal Au prepared from Au-Zr amorphous alloy2016

    • Author(s)
      Ai Nozaki, Yasutomo Tanihara, Yasutaka Kuwahara, Tetsutaro Ohmichi,Kohsuke Mori, Takeshi Nagase, Hiroyuki Yasuda, Christophe Calers, Catherine Louis, Hiromi Yamashita
    • Journal Title

      Journal of Material Chemistry A

      Volume: 4(21) Issue: 21 Pages: 8458-8465

    • DOI

      10.1039/c6ta01963c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Pd/Ag and Pd/Au bimetallic nanocatalysts on mesoporous silica for plasmon-mediated enhanced catalytic activity under visible light irradiation2016

    • Author(s)
      Priyanka Verma, Yasutaka Kuwahara, Kohsuke Mori, Hiromi Yamashita
    • Journal Title

      Journal of Materials Chemistry A [Inside Front Cover]

      Volume: 4 Issue: 26 Pages: 10142-10150

    • DOI

      10.1039/c6ta01664b

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ru and Ru-Ni Nanoparticles on TiO2 Support as Extremely Active Catalysts for Hydrogen Production from Ammonia Borane2016

    • Author(s)
      Kohsuke Mori, Kohei Miyawaki, Hiromi Yamashita
    • Journal Title

      ACS Catalysis

      Volume: 6(5) Issue: 5 Pages: 3128-3135

    • DOI

      10.1021/acscatal.6b00715

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] ナノ細孔空間を利用したプラズモニック光触媒2016

    • Author(s)
      森浩亮、Priyanka Verma, 桑原泰隆、山下弘巳
    • Journal Title

      化学工業

      Volume: 67 Pages: 51-56

    • Related Report
      2016 Research-status Report
  • [Presentation] 水素輸送のためのギ酸合成/分解触媒の開発2017

    • Author(s)
      森浩亮
    • Organizer
      平成28年度・大阪大学「物質・材料科学研究推進機構」講演会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-01-26
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Design of Nano-Catalysts for the Use of Formic Acid as a Renewable Hydrogen Storage Material2017

    • Author(s)
      Kohsuke Mori
    • Organizer
      OKCAT2017(Osaka-Kansai International Symposium on Catalysis)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素エネルギーの貯蔵/輸送のためのギ酸合成/分解触媒の開発2017

    • Author(s)
      森浩亮
    • Organizer
      平成29年度触媒学会西日本支部およびナノ構造触媒研究会合同セミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Design of Nano-Catalysts for the use of Formic acid as a Hydrogen Energy Storage Material2016

    • Author(s)
      Kohsuke Mori
    • Organizer
      GREEN2016
    • Place of Presentation
      Taipei
    • Year and Date
      2016-12-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ギ酸からの水素生成を駆動する金属ナノ粒子触媒2016

    • Author(s)
      森浩亮
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学
    • Year and Date
      2016-09-22
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Design of Nano-Catalysts for Hydrogen Production from Formic Acid as an Energy Storage Material, International Symposium on Nanostrucured Photocayalysts and Catalysts2016

    • Author(s)
      Kohsuke Mori
    • Organizer
      NPC2016
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-04-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Hybrid Photocatalyst based on Metal Complex for Visible-light-driven Hydrogen Productionn2016

    • Author(s)
      Kohsuke Mori
    • Organizer
      26nd IUPAC Symposium on Photochemistry
    • Place of Presentation
      Osaka
    • Year and Date
      2016-04-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] http://www.dma.jim.osaka-u.ac.jp/view?l=ja&u=4266

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://www.mat.eng.osaka-u.ac.jp/msp1/MSP1-HomeJ.htm

    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] 水素化触媒、水素化触媒の製造方法、及び水素キャリア物質の製造方法2016

    • Inventor(s)
      森浩亮, 山下弘巳
    • Industrial Property Rights Holder
      国立研究開発法人科学技術振興機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-255193
    • Filing Date
      2016-12-28
    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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