Project/Area Number |
16K14478
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Catalyst/Resource chemical process
|
Research Institution | Osaka University |
Principal Investigator |
Mori Kohsuke 大阪大学, 工学研究科, 准教授 (90423087)
|
Project Period (FY) |
2016-04-01 – 2018-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | プラズモン / 選択水素化 / 選択的水素化 / プラズモン触媒 / 合金ナノ粒子 / 表面プラズモン共鳴 / 選択的水素化反応 / 分子認識能 |
Outline of Final Research Achievements |
In this research, I developed the photocatalysts with novel functions enabling efficient and selective hydrogenation under solar-light irradiation. For example, the Pd/Ag bimetallic nanostructures were developed, in which Pd NPs were synthesized by a facile LSPR-assisted deposition on the highly dispersed Ag NPs with different sizes and morphologies under visible light irradiation. It can be envisaged and herein demonstrated that the plasmonic metal (Ag) with catalytically active component (Pd) can create a heterostructure exhibiting efficient catalytic activity and selectivity in the photocatalytic selective hydrogenation by the molecular recognition induced by the surface electrical charge control.
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