| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Outline of Final Research Achievements |
This project established the water reduction molecular catalysts based on amino acid and metal ions. The palladium(II) penicillaminato complexes revealed the catalytic water reduction behavior under electrochemical conditions. The incorporation of nickel(II) in the hetero- and multi-nuclear coordination system showed the increased efficiency on the water reduction catalytic behavior, which is the first example of the cooperative effect of metal ions on water reduction catalysis. In addition, the cysteinato coordination compounds were found to show the water reduction functionality as similar to penicillaminato coordination systems.
|
