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Developing Hydroxide Nanoclusters for Novel Green Processes

Research Project

Project/Area Number 16K18240
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionOsaka Prefecture University

Principal Investigator

Yasuaki Tokudome  大阪府立大学, 工学(系)研究科(研究院), 准教授 (50613296)

Research Collaborator TAKAHASHI MASAHIDE  大阪府立大学, 工学研究科, 教授 (20288559)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords層状水酸化物 / グリーンプロセス / 液相合成 / セラミックス / ナノ材料 / 触媒材料 / 層状複水酸化物 / ナノクラスター / ナノ触媒 / 水 / ゾル-ゲル反応 / 環境材料 / 触媒・化学プロセス / 無機工業化学 / 二酸化炭素排出削減
Outline of Final Research Achievements

A novel and versatile strategy to synthesize Li-Al, Co-Al, Zn-Al as well as Ni-Al hydroxide nanoclusters were successfully demonstrated. The synthesis route was found to be applicable to various types of layered metal hydroxide salts.These achievements are based on the insights on the formation mechanism of hydroxide nanoclusters elucidated in the first year of the present project. Additionally, application aspects of hydroxide nanoclusters, especially, basic- and photo-catalytic activities, were developed towards the construction of novel green processes. Thus obtained hydroxides nanoclusters were also found to be able to work as nano-building blocks to form thin films and microparticles with well defined mesostructures. In summary, the present research has successfully established a versatile and simple method to access to a novel family of functional (catalytic active and adsorptive) crystalline materials with controllable meso and macro architectures.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (50 results)

All 2017 2016 Other

All Int'l Joint Research (9 results) Journal Article (6 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 6 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (33 results) (of which Int'l Joint Research: 13 results,  Invited: 8 results) Book (2 results)

  • [Int'l Joint Research] CNRS/University of Clermont Auvergne(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Universidade De Lisboa(ポルトガル)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ISIS/University of Birmingham(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Universidad de Buenos Aires/UNSAM(アルゼンチン)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Southern Denmark(デンマーク)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] CNRS/Universite Blaise Pascal(フランス)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Universidade de Lisboa(ポルトガル)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] ISIS/The University of Manchester(英国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Universidad de Buenos Aires/Comision Nacional de Energia Atomica/UNSAM(アルゼンチン)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Aqueous synthesis of metal hydroxides with controllable nano/macro architectures2017

    • Author(s)
      Yasuaki TOKUDOME
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 8 Pages: 597-602

    • DOI

      10.2109/jcersj2.17095

    • NAID

      130005878361

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of CoAl layered double hydroxid s as reduction nanocatalyst in aqueous mediananocluster2017

    • Author(s)
      Daisuke Kino, Yasuaki Tokudome, Pedro D.Vaz, Carla D.Nunes, MasahideTakahashi
    • Journal Title

      Journal of Asian Ceramic Societies

      Volume: 5 Issue: 4 Pages: 466-471

    • DOI

      10.1016/j.jascer.2017.10.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 3D Hierarchical and porous layered double hydroxide structures: an overview of synthesis methods and applications2017

    • Author(s)
      V. Prevot, Y. Tokudome
    • Journal Title

      Journal of Materials Science

      Volume: 印刷中 Issue: 19 Pages: 11229-11250

    • DOI

      10.1007/s10853-017-1067-9

    • NAID

      120006501822

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-Density Protein Loading on Hierarchically Porous LDH-Aluminum Hydroxide Composites with a Rational Mesostructure2016

    • Author(s)
      Tokudome Y., Fukui M., Tarutani N., Nishimura S., Prevot V., Forano C., Poologasundarampillai G., Lee P., Takahashi M.,
    • Journal Title

      Langmuir

      Volume: 32 Issue: 35 Pages: 8826-8833

    • DOI

      10.1021/acs.langmuir.6b01925

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Single-nanometer sized low-valence metal hydroxide crys-tals: synthesis via epoxide-mediated alkalinization and as-sembly towards functional mesoporous materials2016

    • Author(s)
      Naoki Tarutani, Yasuaki Tokudome, Matias Jobbagy, Federico A. Viva, Galo J. A. A. Soler-Illia, Masahide Takahashi
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 16 Pages: 5606-5610

    • DOI

      10.1021/acs.chemmater.6b02510

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Layered Double Hydroxide Nanocluster: Aqueous, Concentrated, Stable, and Catalytically-Active Colloids Towards Green Chemistry2016

    • Author(s)
      Tokudome Y., Morimoto T., Tarutani N., Vaz P., Nunes C., Prevot V., Stenning G., Takahashi M.
    • Journal Title

      ACS Nano

      Volume: 10 Issue: 5 Pages: 5550-5559

    • DOI

      10.1021/acsnano.6b02110

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 層状金属水酸化物ナノ結晶をビルディングブロックとする規則的メソ多孔性材料の作製2017

    • Author(s)
      樽谷直紀, 徳留靖明, M. Jobbagy, F. A. Viva, G. J. A. A. Soler-Illia, 高橋雅英
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] ナノ/マクロ構造が制御された金属水酸化物合成手法の開発2017

    • Author(s)
      徳留靖明
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Hierarchically porous layered double hydroxide monoliths2017

    • Author(s)
      V. Prevot, C. Forano, M. Fukui, N. Tarutani, S. Nishimura, M. Takahashi
    • Organizer
      5th International Conference on Multifunctional, Hybrid and Nanomaterials
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Layered metal hydroxide crystals in single-nanometer scale for nano-building approach toward ordered mesoporous materials2017

    • Author(s)
      Naoki TARUTANI, Yasuaki TOKUDOME, Matias JOBBAGY, Galo SOLER-ILLIA, Masahide TAKAHASHI
    • Organizer
      SOL-GEL 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spontaneous deflocculation of nanocrystalline hydrogels for the synthesis of aqueous suspension of nanometric metal hydroxides2017

    • Author(s)
      Yasuaki TOKUDOME, Tsuyoshi MORIMOTO, Naoki TARUTANI, Masahide TAKAHASHI
    • Organizer
      SOL-GEL 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノ結晶性層状複水酸化物コンポジットの合成と水中でのCO2光還元活性評価2017

    • Author(s)
      徳留 靖明、福井 めぐ、長谷川 雄大、井口 翔之、寺村 謙太郎、田中 庸裕、高橋 雅英
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] アモルファスAl(OH)3のナノ/マクロ構造転写によるLi-Al系層状複水酸化物の合成2017

    • Author(s)
      竹本 晶紀、徳留 靖明、高橋 雅英
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Co-Al系層状複水酸化物ナノ粒子の合成と水中での触媒活性の評価2017

    • Author(s)
      寄能 大佑、徳留 靖明、高橋 雅英
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] M(II)/M(III) Hydroxides with Controllable Nano/macro Architectures toward Environmental Applications2017

    • Author(s)
      Yasuaki TOKUDOME, Masahide TAKAHASHI
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pseudomorphic Replication for the Synthesis of Li-Al Layered Double Hydroxide from Amorphous Al(OH)3 Precursor2017

    • Author(s)
      Masanori Takemoto, Yasuaki Tokudome, Masahide Takahashi
    • Organizer
      The 34th International Japan-Korea Seminar on Ceramics
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Hydroxide-based Materials with Controllable 3D Architectures for Photocatalytic Reactions in Aqueous Media2017

    • Author(s)
      Yasuaki TOKUDOME, Megu FUKUI, Masahide TAKAHASHI
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Co-Al layered double hydroxide nanoparticles with catalytic properties for the reduction of dye molecules in the aqueous media2017

    • Author(s)
      Daisuke KINO, Yasuaki TOKUDOME, Masahide TAKAHASHI
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of single-nm-size layered nickel hydroxide as nano-building blocks toward functional ordered mesoporous materials2017

    • Author(s)
      Naoki TARUTANI, Yauaki TOKUDOME, Matias JOBBAGY, Galo J. A. A. SOLER-ILLIA, Msahide TAKAHASHI
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 構造転写による非晶質水酸化アルミニウムからのLi-Al系層状複水酸化物多孔体の合成と触媒特性評価2017

    • Author(s)
      竹本晶紀、徳留靖明、高橋雅英
    • Organizer
      第12回 日本セラミックス協会関西支部 学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナノ/マクロ構造が制御された金属水酸化物合成手法の開発2017

    • Author(s)
      徳留 靖明
    • Organizer
      日本セラミックス協会関西支部H28年度協会賞受賞記念講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 層状ハイブリッドナノクラスターの合成とその応用2017

    • Author(s)
      徳留 靖明
    • Organizer
      日本セラミックス協会2018年年会サテライトシンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Zn-Ga 層状複水酸化物ナノ結晶の合成と尿素を用いたGaN:ZnOへの転換2017

    • Author(s)
      吉行里紗、片桐清文、犬丸啓、徳留靖明
    • Organizer
      日本セラミックス協会2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Zn-Al系層状複水酸化物のナノ粒子コロイド溶液作製と光学的応用へ向けた特性評価2017

    • Author(s)
      桂怜央、徳留靖明、高橋雅英
    • Organizer
      日本ゾル-ゲル学会第15回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水溶媒系での触媒応用に向けたCo-Al系層状複水酸化物ナノ粒子の合成2017

    • Author(s)
      寄能大佑、徳留靖明、高橋雅英
    • Organizer
      日本ゾル-ゲル学会第15回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Surface Modification of Layered Double Hydroxide Nanoclusters2017

    • Author(s)
      Chao-an Lin, Yasuaki Tokudome, Masahide Takahashi,
    • Organizer
      日本ゾル-ゲル学会第15回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nanocrystalline Metal Hydroxide with Controllable Nano/Macro Structures for Biomedical and Environmental Applications2017

    • Author(s)
      Yasuaki Tokudome
    • Organizer
      International Symposium on Biomedical and EnvironmentalMaterials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノビルディングブロックからのナノ/マクロ構造が制御された金属水酸化物材料の合成2017

    • Author(s)
      徳留 靖明
    • Organizer
      日本セラミックス協会 関西支部 第20回若手フォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Hierarchically porous layered double hydroxide through pseudomorphic replication from amorphous hydroxide2017

    • Author(s)
      Y. Tokudome, M. Takemoto, V. Prevot , C. Forano, M. Takahashi
    • Organizer
      XVI International Clay Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Aqueous Colloidal LDH Nanocrystals: Alkalization Reaction Accompanied with Gelation-Defloculation Transition2017

    • Author(s)
      Y. Tokudome, M. Takemoto, M. Takahashi
    • Organizer
      XVI International Clay Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 規則的メソ構造を有する層状金属水酸化物材料の合成2017

    • Author(s)
      樽谷直紀、徳留靖明、Matias Jobbagy、Galo Soler-Illia、高橋雅英
    • Organizer
      第56回セラミックス基礎科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 解こうを伴うプロセスによるナノ層状複水酸化物懸濁液の合成2016

    • Author(s)
      徳留靖明, 森本剛司, 樽谷直紀, 高橋雅英
    • Organizer
      第60回粘土科学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2016-09-15
    • Related Report
      2016 Research-status Report
  • [Presentation] 高比表面積を有するLi-Al系層状複水酸化物の合成2016

    • Author(s)
      竹本晶紀, 徳留靖明, 高橋雅英
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Co-Al系層状複水酸化物ナノ粒子の合成2016

    • Author(s)
      寄能大佑, 徳留靖明, 高橋雅英
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 層状複水酸化物ナノクラスターの合成とナノ触媒特性評価2016

    • Author(s)
      徳留靖明, 森本剛司, 樽谷直紀, P. D. Vaz, C. D. Nunes, V. Prevot, 高橋雅英
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] メソ構造体形成に向けた層状水酸化物ナノ結晶の成長制御2016

    • Author(s)
      樽谷直紀, 徳留靖明, M. Jobbagy, F. A. Viva, G. J. A. A. Soler-Illia, 高橋雅英
    • Organizer
      日本ゾル-ゲル学会第14回討論会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-08-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Layered double hydroxides with controlled mesostructures toward high-density protein immobilization.2016

    • Author(s)
      M. Fukui, Y. Tokudome, N. Tarutani, V. Prevot, C. Forano, M. Takahashi
    • Organizer
      13th International Conference on Ceramic Processing Science
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-05-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Stable and Concentrated Colloidal Suspension of Metal Hydroxides and Their Applications in Green Processes2016

    • Author(s)
      Y. Tokudome, T. Morimoto, N. Tarutani, P. D. Vaz, C. D. Nunes, M. Takahashi
    • Organizer
      13th International Conference on Ceramic Processing Science
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-05-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of nanocrystalline layered hydroxide salt mesoporous films and pseudomorphic conversion to mesostructural transition metal compounds.2016

    • Author(s)
      N. Tarutani, Y. Tokudome, M. Jobbagy, F. A. Viva, G. J. A. A. Soler-Illia, M. Takahashi
    • Organizer
      13th International Conference on Ceramic Processing Science
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-05-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] Handbook of Solid State Chemistry: 4. Nano and Hybrid Materials (Chapter 9, Sol-Gel Processing of Porous Materials)2017

    • Author(s)
      K. Nakanishi, K. Kanamori, Y. Tokudome, G. Hasegawa, Y. Zhu
    • Total Pages
      47
    • Publisher
      Wiley
    • ISBN
      9783527325870
    • Related Report
      2017 Annual Research Report
  • [Book] ゾル-ゲルテクノロジーの最新動向(「第13章 層状水酸化物材料の合成と構造制御」))2017

    • Author(s)
      徳留 靖明
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • ISBN
      9784781312583
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2022-06-16  

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