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Study about the suitability evaluation of polymer alloy with high thermal stability as matrix resin for next generation CFRTP

Research Project

Project/Area Number 16K18245
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Research InstitutionNagoya University

Principal Investigator

Irisawa Toshihira  名古屋大学, 工学研究科, 助教 (30737333)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords複合高分子 / 耐熱性ポリマーアロイ / CFRTP / リサイクル
Outline of Final Research Achievements

This study evaluated about the suitability of polymer alloy with high thermal stability as matrix resin for next generation CFRTP which can be used as aircraft application. CFRTP made with polyetherimide (PEI), which has relatively high thermal stability, has achieved high mechanical properties close to the theoretical value and they also have high recyclability. Furthermore, the thermal stability of them was about 150 oC. By alloying with polybenzimidazole which has low thermoplasticity but very high thermal stability, it was revealed that the thermal stability of CFRTP made with PEI/PBI was improved and also maintain the recyclability of them.

Academic Significance and Societal Importance of the Research Achievements

極めて高い耐熱性を有する樹脂をポリマーアロイ化法を応用することによって,CFRTPの母材樹脂として利用可能とする新規なアイデアを学術的なアプローチによって実現した点は実用化の観点からも意義深い研究であったと言える.今後,さらに成形プロセス等最適化の必要性を残すが,得られた知見は現在遂行中の関連企業等にも率先して開示を進めており,今後は実用化研究へと移行する予定である.本研究で可能性を見出した次世代超耐熱性CFRTPは,航空機ジェットエンジンの圧縮機ブレード用素材として,合金素材を代替できるポテンシャルを有しており,航空機のさらなる燃費向上,省エネに貢献できる社会的にも意義ある結果が得られた.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (40 results)

All 2019 2018 2017 2016

All Journal Article (5 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (31 results) (of which Int'l Joint Research: 10 results,  Invited: 10 results) Book (4 results)

  • [Journal Article] 完全循環型炭素繊維強化熱可塑性樹脂の実現に向けた取り組み2019

    • Author(s)
      入澤寿平
    • Journal Title

      炭素誌

      Volume: 288

    • NAID

      130007679424

    • Related Report
      2018 Annual Research Report
  • [Journal Article] The influence of oxygen containing functional groups on carbon fibers for mechanical properties and recyclability of CFRTPs made with in-situ polymerizable polyamide 62018

    • Author(s)
      Toshihira Irisawa, Ryohei Inagaki, Junya Iida, Ryosuke Iwamura, Kento Ujihara, Kento, Sarasa Kobayashi, Yasuhiro Tanabe
    • Journal Title

      Composites Part A: Applied Science and Manufacturing

      Volume: 112 Pages: 91-99

    • DOI

      10.1016/j.compositesa.2018.05.035

    • NAID

      120006536921

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recycling methods for thermoplastic-matrix composites having high thermal stability in focusing on reuse of the carbon fibers2017

    • Author(s)
      Irisawa Toshihira、Iwamura Ryosuke、Kozawa Yoshiki、Kobayashi Sarasa、Tanabe Yasuhiro
    • Journal Title

      TANSO

      Volume: 2017 Issue: 280 Pages: 175-181

    • DOI

      10.7209/tanso.2017.175

    • NAID

      130006284865

    • ISSN
      0371-5345, 1884-5495
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] The Suitability Evaluation of Aromatic Amorphous Thermoplastics as Matrix Resin for CFRTP Having High Thermal Stability2017

    • Author(s)
      入澤寿平, 橋本玲央, 荒井政大, 田邊靖博
    • Journal Title

      Journal of Fiber Science and Technology

      Volume: 73 Issue: 3 Pages: 61-66

    • DOI

      10.2115/fiberst.2017-0008

    • NAID

      130005439650

    • ISSN
      2189-7654
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 複合材料-炭素繊維強化プラスチックに関する最近の研究動向-その22016

    • Author(s)
      入澤寿平
    • Journal Title

      成形加工

      Volume: 28 Pages: 260-264

    • Related Report
      2016 Research-status Report
  • [Presentation] The development of CFRTP having both high mechanical properties and high recyclability.2019

    • Author(s)
      Toshihira Irisawa,Naoaki Nagao Sarasa Kobayashi, Yasuhiro Tanabe
    • Organizer
      ICACC2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高機能繊維材料の開発に向けて ~アクチュエータへの応用~2019

    • Author(s)
      入澤寿平
    • Organizer
      機能材料セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] The effects of interfacial adhesion for mechanical properties of CFRTPs made with polyamide 62018

    • Author(s)
      Toshihira Irisawa, Kento Ujihara, Sarasa Kobayashi, Yasuhiro Tanabe
    • Organizer
      The Fiber Society's Spring 2018 Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The study toward to the realization of sustainable CFRTP having both high mechanical properties and recyclability2018

    • Author(s)
      Toshihira Irisawa, Ryo Hashimoto, Naoaki Nagao, Masahiro Arai, Yasuhiro Tanabe
    • Organizer
      Carbon2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] THE EFFECT OF CNTS FOR CFRTPS MADE WITH POLYAMIDE 62018

    • Author(s)
      Masataka Shibata, Toshihiro Irisawa, Yasuhiro Tanabe
    • Organizer
      Carbon2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The study of interfacial adhesion of CFRTP made with in-site polymerizable thermoplastics2018

    • Author(s)
      Sarasa Kobayashi, Toshihiro Irisawa, Yasuhiro Tanabe
    • Organizer
      Carbon2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リサイクル炭素繊維ーPA6間の界面接着性2018

    • Author(s)
      リサイクル炭素繊維ーPA6間の界面接着性
    • Organizer
      複合材料界面科学研究会2018年度総会講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 熱分解温度・時間がリサイクル炭素繊維の損傷具合に与える影響2018

    • Author(s)
      新竹礼佳,入澤寿平,氏原研人,花井美穂,田邊靖博
    • Organizer
      平成30年度繊維学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ポリアミド6を母材とするCFRTPのリサイクル性に関する研究2018

    • Author(s)
      入澤寿平,氏原研人,岩村亮佑,新竹礼佳,田邊靖博
    • Organizer
      第21回プラスチックリサイクル化学研究会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] サステナブルな社会を実現するサステナブルCFRTP開発の実現に向けて2018

    • Author(s)
      入澤寿平
    • Organizer
      第48回繊維学会夏季セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] CNT分散現場重合型ポリアミド6母材CFRTP中の界面における重合促進に関して2018

    • Author(s)
      入澤寿平,柴田眞孝,山本徹也,田邊靖博
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 繊維材料の過去と未来2018

    • Author(s)
      入澤寿平
    • Organizer
      高分子同友会2018年11月勉強会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] トータルで考える炭素繊維強化樹脂複合材料の性能2018

    • Author(s)
      入澤寿平
    • Organizer
      第52回化学工学の進歩講習会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 常圧溶解法及び熱分解法で回収した各リサイクル炭素繊維の強度低下因子に関する比較2018

    • Author(s)
      新竹礼佳,入澤寿平,田邊靖博
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] CFRP,CFRTPにおける界面の重要性とその改善手法2018

    • Author(s)
      入澤寿平
    • Organizer
      第17回産官学接着若手フォーラム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] The effects of interfacial adhesion between carbon fiber and thermoplastics for mechanical properties of CFRTP2018

    • Author(s)
      Yoshihira Irisawa
    • Organizer
      ICACC2018
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] The damage evaluation of recycle carbon fiber from CFRP made with epoxy resin2017

    • Author(s)
      Toshihira Irisawa, Kento Ujihara, Reika Aratake, Sarasa Kobayashi, Yohsuke Fumiyasu, Hiroshi Kawazoe, Yasuhiro Tanabe
    • Organizer
      ISFR2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Optimization of molding process for CFRTP having high thermal stability2017

    • Author(s)
      Toshihira Irisawa, Ryo Hashimoto, Naoaki Nagao, Masahiro Arai, Yasuhiro Tanabe
    • Organizer
      Carbon 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] The study of interfacial shear strength between thermoplastics having high thermal stability and carbon fiber2017

    • Author(s)
      Toshihira Irisawa, Yasuhiro Tanabe, Ryo Hashimoto, Naoaki Nagao, Masahiro Arai
    • Organizer
      JISSE 15
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] リサイクル炭素繊維の欠陥評価手法に関する提案2017

    • Author(s)
      入澤寿平,岩村亮佑,氏原研人,新竹礼佳,田邊靖博
    • Organizer
      平成29年度繊維学会年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] リサイクル炭素繊維の実用化に向けて2017

    • Author(s)
      入澤寿平
    • Organizer
      第55回炭素材料夏季セミナー
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 新時代を拓く炭素繊維強化プラスチックの作製,利用,リサイクル2017

    • Author(s)
      入澤寿平
    • Organizer
      2017年度 第4回CPC研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] CFRTPから回収したリサイクル炭素繊維とPA6間の界面接着性に関する研究2017

    • Author(s)
      入澤寿平,氏原研人,岩村亮佑,田邊靖博
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 炭素繊維強化プラスチックに関する最近の研究動向2017

    • Author(s)
      入澤寿平
    • Organizer
      IPF JAPAN 2017 先端技術セミナー
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 現場重合法によって作製したCFRTP中の界面接着性に関する研究2017

    • Author(s)
      小林更紗,入澤寿平,田邊靖博
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 非晶性高分子を母材に使用したCFRTPの耐熱特性2016

    • Author(s)
      入澤寿平,橋本玲央,長尾直晃,田邊靖博
    • Organizer
      第30回東海支部若手繊維研究会
    • Place of Presentation
      岐阜
    • Year and Date
      2016-12-10
    • Related Report
      2016 Research-status Report
  • [Presentation] 現場重合型ポリアミド6と炭素繊維界面の接着メカニズムと CFRTPの力学物性・耐熱性への効果について2016

    • Author(s)
      入澤寿平,飯田純也,稲垣良平,小林更紗,田邊靖博
    • Organizer
      第43回炭素材料学会年次大会
    • Place of Presentation
      千葉
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 炭素繊維・CFRP の低価格化及び汎用化への挑戦2016

    • Author(s)
      入澤寿平
    • Organizer
      炭素材料学会 第3回次世代の会定例会
    • Place of Presentation
      千葉
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 炭素繊維・CFRPの研究開発の重要性2016

    • Author(s)
      入澤寿平
    • Organizer
      第157回東海高分子研究会
    • Place of Presentation
      岐阜
    • Year and Date
      2016-09-02
    • Related Report
      2016 Research-status Report
  • [Presentation] The Relationship between the Mechanical Properties and the Interfacial Adhesion of CFRTP made with Aromatic Thermoplastics2016

    • Author(s)
      Toshihira Irisawa, Yasuhiro Tanabe, Ryo Hashimoto, Masahiro Arai
    • Organizer
      US-Japan Conference on Composite Materials
    • Place of Presentation
      北海道
    • Year and Date
      2016-08-01
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 炭素繊維-PA6界面接着への炭素繊維表面官能基の効果2016

    • Author(s)
      入澤寿平,飯田純也,稲垣良平,田邊靖博
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Research-status Report
  • [Book] 炭素材料科学の進展2018

    • Author(s)
      入澤寿平(分担),他多数
    • Total Pages
      196
    • Publisher
      学振117委員会
    • ISBN
      9784990343910
    • Related Report
      2018 Annual Research Report
  • [Book] 炭素繊維・炭素繊維複合材料の未来2018

    • Author(s)
      入澤寿平(分担),他多数
    • Total Pages
      342
    • Publisher
      S&T出版
    • ISBN
      9784907002749
    • Related Report
      2018 Annual Research Report
  • [Book] 最新物質循環とマテリアル開発2018

    • Author(s)
      入澤寿平(分担),他多数
    • Total Pages
      217
    • Publisher
      三恵社
    • ISBN
      9784864879682
    • Related Report
      2018 Annual Research Report
  • [Book] 高耐熱性樹脂の開発事例集2018

    • Author(s)
      入澤寿平(分担),他多数
    • Total Pages
      529
    • Publisher
      技術情報協会
    • ISBN
      9784861047206
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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