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Preparation of bimetallic catalyst using surface chemistry approach

Research Project

Project/Area Number 16K18293
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionSeikei University

Principal Investigator

Tada Shohei  成蹊大学, 理工学部, 研究員 (60769941)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords表面化学的アプローチ / 水酸基 / 非晶質 / 銅 / ジルコニア / 選択析出 / メソポーラスシリカ / XAFS / メタノール合成 / ナノ粒子 / 担持金属触媒 / 表面化学 / 触媒調製 / 不均一触媒 / 二元金属触媒
Outline of Final Research Achievements

I prepared Cu-Zr mixed oxides nanoparticles on mesoporous silica using a surface chemistry approach. When a mixture of mesoporous silica and zirconium precursor was calcined at 400 C, I obtained amorphous-zirconia nanoparticles supported on mesoporous silica. After that, the crude powder was impregnated with a copper nitrate solution, copper species were selectively deposited on the amorphous-zirconia surface. I concluded that the copper precursor was reacted with the surface hydroxyl groups of amorphous-zirconia.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (6 results)

All 2018 2017 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Remarks (2 results)

  • [Journal Article] Cu Species Incorporated into Amorphous ZrO2 with High Activity and Selectivity in CO2-to-methanol Hydrogenation2018

    • Author(s)
      A. Katagiri, K. Kiyota, T. Honma, H. Kamei, A. Nariyuki, S. Uchida, S. Satokawa
    • Journal Title

      J. Phys. Chem. C

      Volume: 122 Issue: 10 Pages: 5430-5442

    • DOI

      10.1021/acs.jpcc.7b11284

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] CO2水素化によるメタノール合成触媒の新たな展開2017

    • Author(s)
      多田昌平, 里川重夫
    • Organizer
      日本エネルギー学会 天然ガス部会 科学・反応システム分科会シンポジウム 二酸化炭素の再資源化
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] メソポーラスシリカを利用したメタノール合成のためのCuO-ZrO2系触媒の開発2017

    • Author(s)
      多田昌平, 片桐彩花, 清田景子, 霜田直宏, 里川重夫
    • Organizer
      石油学会第60回年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local structure snalyses of a CuO/ZrO2/KIT-6 catalyst for CO2-to-methanol hydrogenation2017

    • Author(s)
      S. Tada, A. Katagiri, K. Kiyota, N. Shimoda, H. Honma, H. Kamei, A. Nariyuki, S. Satokawa
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] Google Scholar

    • URL

      https://scholar.google.co.jp/citations?user=zXlmSBUAAAAJ&hl=en

    • Related Report
      2017 Annual Research Report
  • [Remarks] researchmap

    • URL

      https://researchmap.jp/tadashohei/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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