| Budget Amount *help |
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2019: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2018: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
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| Outline of Final Research Achievements |
Hypervalent organoiodine compounds has been utilized as excellent oxidants or electrophiles in current synthetic organic chemistry. In contrast, studies and uses on Group 17 analogue, hypervalent chlorine compounds are essentially limited, probably because of the lack of the avalilable synthetic method.
In this study, we have developed practical and efficient methods for the synthesis of hypervalent chlorine compounds: diaryl-, and vinyl(aryl)-λ3-chlorane, which serve as unprecedented arylation and vinylation agents. These insights will be of great value not only for the main group organic chemistry but also for organic synthesis.
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