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Development of photo-electronic-magnetic functions by anisotoropic assembly of luminescent open-shell molecules

Research Project

Project/Area Number 17H04870
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionInstitute for Molecular Science (2018-2019)
The University of Tokyo (2017)

Principal Investigator

Kusamoto Tetsuro  分子科学研究所, 生命・錯体分子科学研究領域, 准教授 (90585192)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥23,530,000 (Direct Cost: ¥18,100,000、Indirect Cost: ¥5,430,000)
Fiscal Year 2019: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2018: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywordsラジカル / 発光 / スピン / 磁性 / 金属錯体 / 磁場効果 / 励起状態 / 一次元 / magnetoluminescence / 光物性 / 磁気物性 / 開殻 / 光機能 / 光安定性 / 物性 / 電子状態
Outline of Final Research Achievements

I have developed several organic radicals possessing high photostability and luminescent properties. In previous studies, the decomposition of radicals upon photoirradiation is a bottleneck to investigate their luminescent properties. In this study, I have prepared a novel luminescent radical bisPyTM whose photostability is higher than that of TIPS pentacene, known as a photostable closed-shell molecule. Furthermore, I have revealed for the first time that the emission properties of radicals can be controlled by applying magnetic field. This is the first realization of interplay between spin and luminescence in radicals.

Academic Significance and Societal Importance of the Research Achievements

ラジカルの発光特性に着目した研究例は極めて限られており、その特徴や発現メカニズムは十分に理解されていなかった。本研究ではラジカルの発光および非発光過程の要因を明らかにすることができた。また開殻電子系を有するラジカルが示す発光は、通常の閉殻分子の発光とは異なる特徴があることを実験的に明らかにした。これらは分子科学や光物性科学に新たな知見を与える成果であり、学術的に大きな意義を有する。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (44 results)

All 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (31 results) (of which Int'l Joint Research: 16 results,  Invited: 14 results) Remarks (2 results)

  • [Int'l Joint Research] Cavendish Laboratory(英国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Cavendish laboratory(英国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] NIR Emission and Acid-Induced Intramolecular Electron Transfer Derived from a SOMO-HOMO Converted Non-Aufbau Electronic Structure2019

    • Author(s)
      Tanushi Akira、Kimura Shun、Kusamoto Tetsuro、Tominaga Moe、Kitagawa Yasutaka、Nakano Masayoshi、Nishihara Hiroshi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 7 Pages: 4417-4423

    • DOI

      10.1021/acs.jpcc.8b08574

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn-Teller distortion correlated to π-conjugation and magnetic properties2019

    • Author(s)
      Kimura Shun、Uchida Hikaru、Kusamoto Tetsuro、Nishihara Hiroshi
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 21 Pages: 7090-7093

    • DOI

      10.1039/c8dt05104f

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescent Radical-Excimer: Excited-State Dynamics of Luminescent Radicals in Doped Host Crystals2019

    • Author(s)
      Kato Ken、Kimura Shun、Kusamoto Tetsuro、Nishihara Hiroshi、Teki Yoshio
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 9 Pages: 2606-2611

    • DOI

      10.1002/anie.201813479

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zero-, one- and two-dimensional bis(dithiolato)metal complexes with unique physical and chemical properties2019

    • Author(s)
      Kusamoto Tetsuro、Nishihara Hiroshi
    • Journal Title

      Coordination Chemistry Reviews

      Volume: 380 Pages: 419-439

    • DOI

      10.1016/j.ccr.2018.09.012

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identifying the Factors Governing the Early-Stage Degradation of Cu-Chabazite Zeolite for NH3-SCR2019

    • Author(s)
      Toyohiro Usui#, Zhendong Liu#, (# equal contribution), Hirokazu Igarashi, Yukichi Sasaki, Yuji Shiramata, Hiroki Yamada, Koji Ohara, Tetsuro Kusamoto, Toru Wakihara
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 2 Pages: 3653-3659

    • DOI

      10.1021/acsomega.8b03409

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Chemical reduction of Li+@C60 by decamethylferrocene to produce neutral Li+@C60・-2019

    • Author(s)
      H. Okada, H. Ueno, Y. Takabayashi, T. Nakagawa, M. Vrankic;, J. Arvanitidis, T. Kusamoto, K. Prassides, and Y. Matsuo
    • Journal Title

      Carbon

      Volume: 153 Pages: 467-471

    • DOI

      10.1016/j.carbon.2019.07.028

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A luminescent organic radical with two pyridyl groups: high photostability and dual stimuli-responsive properties, with theoretical analyses of photophysical processes2018

    • Author(s)
      Kimura Shun、Tanushi Akira、Kusamoto Tetsuro、Kochi Shuntaro、Sato Tohru、Nishihara Hiroshi
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 7 Pages: 1996-2007

    • DOI

      10.1039/c7sc04034b

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetoluminescence in a Photostable, Brightly Luminescent Organic Radical in a Rigid Environment2018

    • Author(s)
      Kimura Shun、Kusamoto Tetsuro、Kimura Shojiro、Kato Ken、Teki Yoshio、Nishihara Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 39 Pages: 12711-12715

    • DOI

      10.1002/anie.201805466

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cation-responsive turn-on fluorescence and absence of heavy atom effects of pyridyl-substituted triarylmethyl radicals2018

    • Author(s)
      Hattori Yohei、Kimura Shun、Kusamoto Tetsuro、Maeda Hiroaki、Nishihara Hiroshi
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 6 Pages: 615-618

    • DOI

      10.1039/c7cc08568k

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Photofunctions of Stable Organic Radicals2019

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      PCOSS-IMS Bilateral Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 安定有機ラジカルが示す発光機能2019

    • Author(s)
      草本 哲郎
    • Organizer
      有機EL討論会第29回例会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 安定ラジカルを基とする発光機能創出2019

    • Author(s)
      草本 哲郎
    • Organizer
      第4回有機若手ワークショップ
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Luminescence and Structure-Magnetism Correlation of Open-Shell Metal Complexes2019

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      7TH ASIAN CONFERENCE ON COORDINATION CHEMISTRY (ACCC7)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 錯体化学を基とする開殻電子系分子の光機能創出2019

    • Author(s)
      草本 哲郎
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 解離性プロトンを有する金属五核錯体の合成と性質2019

    • Author(s)
      石原芽衣・草本 哲郎・近藤 美欧・正岡 重行
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Co4O4キュバン型錯体の自己集積による新規フレームワーク構築とその物性評価2019

    • Author(s)
      藤澤真由・石見輝・可知真美・草本哲郎・近藤美欧・正岡重行
    • Organizer
      錯体化学会第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Magnetoluminescence in photostable radicals2019

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      Spin Chemistry Meeting 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetic Field Effect on the Luminescence of Stable Radicals in a Rigid Environment2019

    • Author(s)
      Shun Kimura, Tetsuro Kusamoto, Shojiro Kimura, Ken Kato, Yoshio Teki, Hiroshi Nishihara
    • Organizer
      Spin Chemistry Meeting 2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 解離性プロトンを有する金属五核錯体の合成と性質2019

    • Author(s)
      石原芽衣・岡村将也・草本 哲郎・近藤 美欧・正岡 重行
    • Organizer
      錯体化学若手研究会「錯体化学若手の会夏の学校2019」
    • Related Report
      2019 Annual Research Report
  • [Presentation] 相補的相互作用部位を有する配位子を導入したCo4O4キュバン型錯体の自己集積による新規フレームワークの構築2019

    • Author(s)
      藤澤真由・石見輝・可知真美・草本哲郎・近藤美欧・正岡重行
    • Organizer
      錯体化学若手研究会「錯体化学若手の会夏の学校2019」
    • Related Report
      2019 Annual Research Report
  • [Presentation] Photostable Organic Radicals with Unique Photofunctions2019

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      17th Japan-Korea Symposium on Molecular Science
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetoluminescence in photostable radicals2019

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      9th Pacific Symposium on Radical Chemistry (PSRC-9)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 開殻π電子系が拓く発光・磁気特性2019

    • Author(s)
      草本 哲郎
    • Organizer
      第4回固体化学フォーラム研究会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] An organic radical with three pyridyl groups: luminescence properties and its two dimensional complexes2019

    • Author(s)
      Shun Kimura, Tetsuro Kusamoto, Hiroshi Nishihara
    • Organizer
      日本化学会第100回春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] The synthesis, properties, and coordination ability of a novel luminescent organic radical with two pyridyl groups2019

    • Author(s)
      Hikaru Uchida, Shun Kimura, Tetsuro Kusamoto, Hiroshi Nishihara
    • Organizer
      日本化学会第100回春季年会
    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
  • [Presentation] 剛直マトリクス中の有機ラジカルにおける発光の磁場効果2018

    • Author(s)
      木村舜・草本哲郎・木村尚次郎・加藤賢・手木芳男・西原寛
    • Organizer
      有機固体若手の会2018秋の学校
    • Related Report
      2018 Annual Research Report
  • [Presentation] 分子結晶にドープした有機ラジカルにおける発光の磁場効果2018

    • Author(s)
      Shun Kimura, Tetsuro Kusamoto, Shojiro Kimura, Ken Kato, Yoshio Teki, Hiroshi Nishihara
    • Organizer
      日本化学会第99回春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 常磁性金属イオンと有機ラジカルからなる一次元錯体ポリマーの創製と構造―磁性相関2018

    • Author(s)
      内田 光・木村 舜・草本 哲郎・西原 寛
    • Organizer
      有機固体若手の会2018秋の学校
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fabrication and structure-magnetism correlation of one-dimensional polymer complex consistingof paramagnetic metal ions and organic radicals2018

    • Author(s)
      Hikaru Uchida, Shun Kimura, Tetsuro Kusamoto, Hiroshi Nishihara
    • Organizer
      日本化学会第99回春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Magnetic field effect on emission spectrum and lifetime of a PyBTM radical doped into host crystals2018

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      4th Kanto Area Spin Chemistry Meeting (KASC 4th meeting)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemically-controlled luminescence and magnetism of stable radicals2018

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      Rising star ICMM2018 Pre-Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Impact of metal ions on the photofunctionalities of luminescent organic radicals2018

    • Author(s)
      Tetsuro Kusamoto, Yohei Hattori, Hiroshi Nishihara
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Doublet-based luminescence of photostable organic radicals2018

    • Author(s)
      Tetsuro Kusamoto, Hiroshi Nishihara
    • Organizer
      27th IUPAC International Symposium on Photochemistry (PhotoIUPAC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photostable Fluorescent Radicals: Modulated Luminescence by Coordination to Metal2017

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      8th Pacific Symposium on Radical Chemistry (PSRC-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Stimuli-Responsive Fluorescent Radicals2017

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      International Symposium on Pure & Applied Chemistry (ISPAC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enhanced luminescence of gold(I) complexes with a fluorescent radical ligand2017

    • Author(s)
      Tetsuro Kusamoto, Yohei Hattori, Yasuyo Ogino, Hiroshi Nishihara
    • Organizer
      6th Asian Conference on Coordination Chemistry (ACCC6)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A possible quantum spin liquid state on highly anisotropic triangular lattices of bilayer Mott system2017

    • Author(s)
      Tetsuro Kusamoto, Chie Ohde, Shiori Sugiura, Taichi Terashima, Shinya Uji, Satoshi Yamashita, Yasuhiro Nakazawa, and Hiroshi Nishihara
    • Organizer
      The 12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic field effect on luminescence behaviors of organic radicals in rigid matrices2017

    • Author(s)
      Shun Kimura, Tetsuro Kusamto, Shojiro Kimura, Hiroshi Nishihara
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development and magnetic field effect of luminescent stable radicals2017

    • Author(s)
      Tetsuro Kusamoto
    • Organizer
      3rd KASC meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A luminescent triarylmethyl radical with two pyridyl groups: Superior photostability and the formation of 1D CuII coordination polymer2017

    • Author(s)
      Shun Kimura, Tetsuro Kusamoto, Hiroshi Nishihara
    • Organizer
      The 6th Asian Conference on Coordination Chemistry (ACCC6)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 草本グループホームページ

    • URL

      https://groups.ims.ac.jp/organization/kusamoto_g/index.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 草本グループのホームページ

    • URL

      https://groups.ims.ac.jp/organization/kusamoto_g/

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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