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Development of highly effecienct catalytic systems based on pseudo-binary alloys

Research Project

Project/Area Number 17H04965
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

Furukawa Shinya  北海道大学, 触媒科学研究所, 准教授 (10634983)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥23,920,000 (Direct Cost: ¥18,400,000、Indirect Cost: ¥5,520,000)
Fiscal Year 2019: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2018: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2017: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords合金触媒 / 金属間化合物 / 擬二元系合金 / 脱水素 / 排ガス浄化 / 水素キャリア / ハイブリッドアロイ / 合金 / 触媒 / 固溶体合金 / 位置選択性 / 触媒設計
Outline of Final Research Achievements

In this study, we designed a novel alloy material "hybrid alloy of intermetallic compound and solid solution", which was more flexible for catalyst design compared with the conventional metallic materials, and performed a comprehensive study of the material development, its catalytic use, and mechanistic study. We successfully developed novel alloy materials showing remarkably high catalytic performances in exhaust gas purification and hydrogen production. The obtained catalytic performances cannot be achieved by using the conventional metal or alloy materials, which demonstrates the availability of our catalyst design concept based on "hybrid alloy of intermetallic compound and solid solution".

Academic Significance and Societal Importance of the Research Achievements

本研究成果は、これまでの金属触媒の設計概念を大幅に拡張できることを示したものであり、今回達成した反応系以外にも展開可能な普遍的な学術的理念と化学技術を確立したと言える。そのため、今後の自身の研究展開はもちろん、世界の研究者に対しても波及効果が期待できるものである。また、今回高効率化を達成した反応系は排ガス浄化や水素生成といった社会的重要度の高いものであり、本触媒系が社会に与えるインパクトも非常に大きいと言える。実際に、水素生成(メチルシクロヘキサン脱水素)の成果は新聞記事としても取り上げられ、社会からの関心の高さが示された。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (32 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (14 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 14 results,  Open Access: 2 results) Presentation (15 results) (of which Int'l Joint Research: 11 results,  Invited: 9 results)

  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Active, Selective, and Durable Catalyst for Alkane Dehydrogenation Based on a Well-designed Trimetallic Alloy2020

    • Author(s)
      Yuki Nakaya, Masayoshi Miyazaki, Seiji Yamazoe, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 9 Pages: 5163-5172

    • DOI

      10.1021/acscatal.0c00151

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic production of alanine from waste glycerol2020

    • Author(s)
      Yunzhu Wang, Shinya Furukawa, Song Song, Qian He, Hiroyuki Asakura, Ning Yan
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 6 Pages: 2289-2293

    • DOI

      10.1002/anie.201912580

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Organonitrogen Chemicals from Oxygen-Containing Feedstock over Heterogeneous Catalysts2020

    • Author(s)
      Yunzhu Wang, Shinya Furukawa, Xinpu Fu, Ning Yan
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 1 Pages: 311-335

    • DOI

      10.1021/acscatal.9b03744

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Highly Active and Noble-Metal-Alternative Hydrogenation Catalysts Prepared by Dealloying Ni-Si Intermetallic Compounds2019

    • Author(s)
      Wiyanti F. Simanullang, Hiroshi Itahara, Naoko Takahashi, Satoru Kosaka, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 93 Pages: 13999-14002

    • DOI

      10.1039/c9cc07862b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Cu-Pd single-atom alloy catalyst for highly efficient NO reduction2019

    • Author(s)
      Feilong Xing, Jaewan Jeon, Takashi Toyao, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 36 Pages: 8292-8298

    • DOI

      10.1039/c9sc03172c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extraordinarily large kinetic isotope effect on alkene hydrogenation over Rh-based intermetallic compounds2019

    • Author(s)
      Shinya Furukawa, Pingping Yi, Yuji Kunisada, Ken-ichi Shimizu
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 20 Issue: 1 Pages: 805-812

    • DOI

      10.1080/14686996.2019.1642139

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identification of an Active NiCu Catalyst for Nitrile Synthesis from Alcohol2019

    • Author(s)
      Yunzhu Wang, Shinya Furukawa, Ning Yan
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 8 Pages: 6681-6691

    • DOI

      10.1021/acscatal.9b00043

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Na-Melt Synthesis of Fine Ni3Si Powders as a Hydrogenation Catalyst2019

    • Author(s)
      Hiroshi Itahara, Wiyanti F. Simanullang, Naoko Takahashi, Satoru Kosaka, Shinya Furukawa
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 9 Pages: 5406-5409

    • DOI

      10.1021/acs.inorgchem.9b00521

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Modification of PdZn Nanoparticles via Galvanic Replacement for the Selective Hydrogenation of Terminal Alkynes2019

    • Author(s)
      Miyazaki Masayoshi、Furukawa Shinya、Takayama Tomoaki、Yamazoe Seiji、Komatsu Takayuki
    • Journal Title

      ACS Applied Nano Materials

      Volume: 2 Issue: 5 Pages: 3307-3314

    • DOI

      10.1021/acsanm.9b00761

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of Pd-based pseudo-binary alloy catalysts for highly active and selective NO reduction2019

    • Author(s)
      Jaewan Jeon, Ken-ichi Kon, Takashi Toyao, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 15 Pages: 4148-4162

    • DOI

      10.1039/c8sc05496g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Heterogeneous Additive-Free Hydroboration of Alkenes Using Cu-Ni/Al2O3: Concerted Catalysis Assisted by Acid-Base Properties and Alloying Effects2019

    • Author(s)
      Shinya Furukawa, Mayuko Ieda, Ken-ichi Shimizu
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 6 Pages: 5096-5103

    • DOI

      10.1021/acscatal.8b04988

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidant free conversion of alcohols to nitriles over Ni-based catalysts2019

    • Author(s)
      Yunzhu Wang, Shinya Furukawa, Zhang Zhang, Laura Torrente-Murciano, Saif A. Khan, Ning Yan
    • Journal Title

      Catalysis Science & Technology

      Volume: 9 Issue: 1 Pages: 86-96

    • DOI

      10.1039/c8cy01799a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Remarkable Enhancement in Hydrogenation Ability by Phosphidation of Ruthenium: Specific Surface Structure Having Unique Ru Ensembles2018

    • Author(s)
      Furukawa Shinya、Matsunami Yukihiko、Hamada Ikutaro、Hashimoto Yasushi、Sato Yasushi、Komatsu Takayuki
    • Journal Title

      ACS Catalysis

      Volume: 8 Issue: 9 Pages: 8177-8181

    • DOI

      10.1021/acscatal.8b02582

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface2017

    • Author(s)
      Miyazaki Masayoshi, Furukawa Shinya, Komatsu Takayuki
    • Journal Title

      Journal of the American Chemical Society

      Volume: 139 Issue: 50 Pages: 18231-18239

    • DOI

      10.1021/jacs.7b08792

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Novel Concept for Catalyst Design based on Alloy Materials2019

    • Author(s)
      Shinya Furukawa
    • Organizer
      Southeast Asia Catalysis Conference 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 合金材料を基盤とした金属反応場の精密設計2019

    • Author(s)
      古川 森也
    • Organizer
      第35回ライックセミナー
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Design of Palladium-based alloy catalyst for highly active and selective NO reduction2019

    • Author(s)
      Shinya Furukawa, Jaewan Jeon, Kenichi Shimizu
    • Organizer
      the 8th Asia Pacific Congress in Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel Concept for Catalyst Design based on Alloy Materials2019

    • Author(s)
      Shinya Furukawa
    • Organizer
      ETH-ICAT joint symposium on catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Concept for Catalyst Design based on Intermetallic Compounds2019

    • Author(s)
      Shinya Furukawa
    • Organizer
      International Symposium Intermetallic Compounds in Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属反応場の精密設計 ー現状と展望ー2019

    • Author(s)
      古川 森也
    • Organizer
      触媒材料の金属学研究会 第4回ミニシンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Highly active and selective deNOx catalyst using Pd(In1-xCux)/Al2O3 pseudo-binary alloys2019

    • Author(s)
      Jaewan Jeon, Ken-ichi Kon, Takashi Toyao, Ken-ichi Shimizu, Shinya Furukawa
    • Organizer
      Cardiff Catalysis Institute - Hokkiado ICAT Joint International Symposium on Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalyst Design based on Alloy Materials2019

    • Author(s)
      Shinya Furukawa
    • Organizer
      6th International Symposium of Institute for Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NO-CO反応に高い活性・選択性を示す Pd(In0.33Cu0.67)擬二元系合金の開発とその作用機構2019

    • Author(s)
      古川森也・全載完・今健一・清水研一
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Selective Catalysis Controlled by Specific andHighly Ordered Surface Atomic Arrangementof Intermetallic Compounds2018

    • Author(s)
      Shinya Furukawa, Takayuki Komatsu
    • Organizer
      Pre-conference of TOCAT8 and the 5th International Symposium of Institute for Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 合金材料に潜む新しい触媒化学の描像2018

    • Author(s)
      古川 森也
    • Organizer
      第16回触媒化学ワークショップ
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Highly efficient molecular transformation using ordered alloys as catalysts2018

    • Author(s)
      Shinya Furukawa
    • Organizer
      The 255th ACS National Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Steric Effects on Bimetallic Catalysis Governed by Specific Atomic Arrangement of Ordered Alloys2017

    • Author(s)
      Shinya Furukawa
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Well-structured Bimetallic Surface Capable of Molecular Recognition for Chemoselective Nitroarene Hydrogenation2017

    • Author(s)
      Shinya Furukawa, Katsuya Takahashi, Takayuki Komatsuc
    • Organizer
      EUROPACAT2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic Chemistry of Ordered Alloys2017

    • Author(s)
      Shinya Furukawa
    • Organizer
      TU/e-ICAT Joint International Symposium on Catalysis for Sustainable Society
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2017-04-28   Modified: 2021-02-19  

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