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Electronic and optical functionalities of metal-organic framework films with vrystallographic orientation

Research Project

Project/Area Number 17H06237
Research Category

Grant-in-Aid for Challenging Research (Pioneering)

Allocation TypeSingle-year Grants
Research Field Inorganic/Coordination chemistry, Analytical chemistry, and related fields
Research InstitutionOsaka Prefecture University

Principal Investigator

Takahashi Masahide  大阪府立大学, 工学(系)研究科(研究院), 教授 (20288559)

Co-Investigator(Kenkyū-buntansha) 岡田 健司  大阪大学, 工学研究科, 助教 (30750301)
徳留 靖明  大阪府立大学, 工学(系)研究科(研究院), 准教授 (50613296)
Project Period (FY) 2017-06-30 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥25,610,000 (Direct Cost: ¥19,700,000、Indirect Cost: ¥5,910,000)
Fiscal Year 2019: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2018: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2017: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Keywordsナノ多孔性材料 / 配位化合物 / エピタキシャル成長 / ホストーゲストシステム / 配向薄膜 / 光機能性 / 電子機能性 / 多孔性材料 / 金属有機構造体 / 光機能性材料 / 有機-無機ハイブリッド / ヘテロエピタキシャル / プラズモン吸収 / 配向性薄膜 / 配向ナノ多孔性薄膜 / 電荷分離 / 金属吸着 / ナノ多孔性薄膜
Outline of Final Research Achievements

Epitaxial metal-organic framework files have been established as a new family of nano porous materials with macroscopic alignments of framework structure and pores. We have reported following achievements from the present study: epitaxial films are grown for MOFs with 3-dimensional frameworks, organic functional molecules of linear shape are accommodated in the aligned pore and show unique optical responses, and MOF-on-MOF epitaxial films are fabricated.

Academic Significance and Societal Importance of the Research Achievements

ホストーゲストアプローチによる機能材料は、機能性を非常に広範囲で制御できることから電子、光、磁気デバイスのホストとして大いに期待されている。しかしながら、実用化の最も大きな阻害因子として、配向薄膜(エピタキシャル技術)の困難さが指摘されてきた。本研究では、ナノ多孔性のMOFのエピタキシャル技術の基礎を確立し、ホストとしての可能性を大きく拡張した。今後、ゲスト分子の含浸方法の発展やユニークな分子の発見により、これまでは困難とされてきた応用が開拓されて聞くことが期待できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (56 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (5 results) Journal Article (14 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 14 results,  Open Access: 9 results,  Acknowledgement Compliant: 2 results) Presentation (35 results) (of which Int'l Joint Research: 25 results,  Invited: 16 results) Book (1 results) Remarks (1 results)

  • [Int'l Joint Research] The university of Adelaide(オーストラリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] TU Graz(オーストリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Universita di Sassari(イタリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Graz Universityu of Technology(Austria)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] The University of Adelaide(Australia)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Imparting CO2 reduction selectivity to ZnGa2O4 photocatalysts by crystallization from hetero nano assembly of amorphous-like metal hydroxides2020

    • Author(s)
      Takemoto Masanori、Tokudome Yasuaki、Kikkawa Soichi、Teramura Kentaro、Tanaka Tsunehiro、Okada Kenji、Murata Hidenobu、Nakahira Atsushi、Takahashi Masahide
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 14 Pages: 8066-8073

    • DOI

      10.1039/d0ra00710b

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Monolithic SrTiO<sub>3</sub>/titanate nanotube/TiO<sub>2</sub> nanocomposite toward enhanced photocatalytic activity2019

    • Author(s)
      Okada Kenji、Takahashi Masahide
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 127 Issue: 10 Pages: 761-766

    • DOI

      10.2109/jcersj2.19089

    • NAID

      130007722611

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2019-10-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Preparation of Silicophosphate Alternating Hybrid Copolymers via Nonaqueous Acid-Base Reactions of Phosphoric Acid and Organo-Bridged Bis(chlorosilane)2019

    • Author(s)
      Okada Kenji、Takano Masanari、Tokudome Yasuaki、Tokuda Yomei、Takahashi Masahide
    • Journal Title

      Molecules

      Volume: 25 Issue: 1 Pages: 127-127

    • DOI

      10.3390/molecules25010127

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microparticles with hetero-nanointerfaces: controlled assembly of cobalt hydroxide and nickel hydroxide nanoclusters towards improved electrochemical functions2019

    • Author(s)
      Tarutani Naoki、Tokudome Yasuaki、Jobbagy Matias、Soler-Illia Galo J. A. A.、Takahashi Masahide
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 7 Issue: 44 Pages: 25290-25296

    • DOI

      10.1039/c9ta07141e

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oriented Growth of Multiple Layered Thin Films of Metal-Organic Frameworks (MOF-on-MOF)2019

    • Author(s)
      Ikigaki K., Okada K., Tokudome Y., Toyao T., Falcaro P., Doonan C.J., Takahashi M.
    • Journal Title

      Angewandte Chemie International Edition,

      Volume: 印刷中 Issue: 21 Pages: 6886-6890

    • DOI

      10.1002/anie.201901707

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Anisotropic and Reversible Deformation of Mesopores and Mesostructures in Silica-Based Films under Mechanical Stimuli toward Adaptive Optical Components2019

    • Author(s)
      Okada Kenji、Asakura Genki、Yamamoto Tatsuya、Tokudome Yasuaki、Takahashi Masahide
    • Journal Title

      ACS Applied Nano Materials

      Volume: 印刷中 Issue: 4 Pages: 2377-2382

    • DOI

      10.1021/acsanm.9b00269

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metal-organic framework thin films from copper hydroxide nano-assemblies2018

    • Author(s)
      Ikigaki K., Okada K., Tokudome Y., Takahashi M.
    • Journal Title

      J. Sol-Gel Sci, Technol.

      Volume: 89 Issue: 1 Pages: 128-134

    • DOI

      10.1007/s10971-018-4805-9

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Responsive and adaptive micro wrinkles on organic-inorganic hybrid materials2018

    • Author(s)
      Takahashi M.
    • Journal Title

      The Chemical Record

      Volume: 18 Issue: 7-8 Pages: 1222-1231

    • DOI

      10.1002/tcr.201800007

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Ordered Mesoporous Hydroxide Thin Films through Self-Assembly of Size-Tailored Nanobuilding Blocks: A Theoretical-Experimental Approach2018

    • Author(s)
      Tarutani Naoki、Tokudome Yasuaki、Jobbbgy Mattias、Soler-Illia Galo J. A. A.、Tang Qiyun、Muller Marcus、Takahashi Masahide
    • Journal Title

      Chemistry of Materials

      Volume: 31 Issue: 2 Pages: 322-330

    • DOI

      10.1021/acs.chemmater.8b03082

    • NAID

      120006782455

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-Throughput Screening of Metal-Organic Frameworks for Macroscale Heteroepitaxial Alignment2018

    • Author(s)
      Tarzia A., Takahashi M., Falcaro P., Thornton A., Doonan C., Huang D.,
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 47 Pages: 128-134

    • DOI

      10.1021/acsami.8b14756

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Responsive and adaptive micro wrinkles on organic-inorganic hybrid materials2018

    • Author(s)
      M. Takahashi
    • Journal Title

      The Chemical Records

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrochemical sensor and catalyst on Cu3(BTC)2 coating electrode from Cu(OH)2 films2017

    • Author(s)
      Kenji Okada , Shota Sawai , Ken Ikigaki , Yasuaki Tokudome , Paolo Falcaro and Masahide Takahashi
    • Journal Title

      CrystEngComm

      Volume: 印刷中 Issue: 29 Pages: 4194-4200

    • DOI

      10.1039/c7ce00416h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Integrating magnetic nanoparticles into HKUST-1 (Cu3(BTC)2) via conversion from a Cu-based ceramic: a novel approach for development of magnetically recyclable catalysts2017

    • Author(s)
      Toyao T., Styles M.J., Yago T., Sadiq M.M., Ricco R., Horiuchi Y., Takahashi,M., Matsuoka M., Falcaro P.
    • Journal Title

      Cryst. Eng. Comm.

      Volume: 19 Issue: 29 Pages: 4201-4210

    • DOI

      10.1039/c7ce00390k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Centimetre scale micropore alignment in oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth2017

    • Author(s)
      Falcaro P., Okada K., Hara T., Ikigaki K., Tokudome Y., Thornton A.W., Hill A.J., Williams T., Doonan C., Takahashi M.,
    • Journal Title

      Nature Mater.

      Volume: 16 Issue: 3 Pages: 342-348

    • DOI

      10.1038/nmat4815

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Aligning pores in framework compounds via sol-gel approach2019

    • Author(s)
      M. Takahashi
    • Organizer
      NANOAPP 2019ーNanomaterials & Applications
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solventless condensation of alternating organically-modified silocophosphate polymers: preparation and optical applications2019

    • Author(s)
      M. Takahashi
    • Organizer
      3rd International Symposium on Silicon-based polymers
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermoresponsive Wrinkles on Hydrogels for Micro Soft Actuators2019

    • Author(s)
      M.Takahashi
    • Organizer
      3rd International Symposium on Silsesquioxanes-based Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mesostructured silica-based film: nm-scale structural deformation and μm-scale structuring2019

    • Author(s)
      K. Okada, M. Takahashi
    • Organizer
      3rd International Symposium on Silsesquioxanes-based Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Aligning micropores of framework compounds2019

    • Author(s)
      M.Takahashi
    • Organizer
      International Sol-Gel Conference, Sol-Gel 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thermo-responsive wettability in hydrophobic regime on polymer-coated titanate nanorod brushes2019

    • Author(s)
      K. Okada, T. Chiya, Y. Tokudome, M. Takahashi
    • Organizer
      International Sol-Gel Conference, Sol-Gel 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Directing pores in framework compounds via heteroepitaxial approach2019

    • Author(s)
      M.Takahashi
    • Organizer
      Asian Conference on Coordination Chemistry (ACCC) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Responsive Wrinkles on Hybrid Gels/Hydrogels for Micro Soft Actuators2019

    • Author(s)
      M.Takahashi
    • Organizer
      Materials Science & Technology (MS&T) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Oriented growth of Covalent organic framework (COF) crystals on metal-hydroxides thin film2019

    • Author(s)
      K. Ikigaki, K. Okada, Y. Tokudome, P. Falcaro, A. Tarzia, C. Coleman, C.J. Doonan, M. Takahashi
    • Organizer
      Materials Science & Technology (MS&T) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポルフィリン誘導体を有機配位子とした金属有機構造体(MOF)配向薄膜の作製とその光学特性2019

    • Author(s)
      岡田健司, 藤井翔悟, 徳留靖明, 高橋雅英, Paolo Falcaro, Christian Doonan
    • Organizer
      日本セラミックス協会 2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水酸化物上におけるCovalent organic framework (COF)薄膜の配向成長2019

    • Author(s)
      生垣賢, 岡田健司, 徳留靖明, Paolo Falcaro, Andrew Tarzia, Christopher Coleman, Christian Doonan, 高橋雅英
    • Organizer
      日本セラミックス協会 2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Enhanced electrochromic properties of organic-inorganic thin films based on Layered Double Hydroxides2018

    • Author(s)
      V. Prevot, C. Mousty, P. Koilraj, I. Mjejri, A. Rougier, M. Takemoto, M. Takahashi, Y. Tokudome
    • Organizer
      6th International Conference on Multifunctional, Hybrid and Nanomaterials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and application of oriented metal-organic framework films via heteroepitaxial growth on inorganic substrate2018

    • Author(s)
      M. Takahashi
    • Organizer
      6th International Conference on Metal-Organic Frameworks (MOF 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of porphyrin-based MOF oriented films and their optical properties2018

    • Author(s)
      K. Okada, S. Fujii, K. Ikigaki, Y. Tokudome, P. Falcaro, C. Doonan, M. Takahashi
    • Organizer
      6th International Conference on Metal-Organic Frameworks (MOF 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Oriented growth of COF crystals on metal-hydroxides thin film2018

    • Author(s)
      K. Ikigaki, K. Okada, Y. Tokudome, A. Tarzia, P. Falcaro, C. Coleman, C. Doonan, M. Takahashi
    • Organizer
      6th International Conference on Metal-Organic Frameworks (MOF 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Centimetre-scale oriented film of Metal Organic Framework via heteroepitaxial growth on metal hydroxides2018

    • Author(s)
      K. Okada, Y. Tokudome, M. Takahashi
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hybrid Microactuators2018

    • Author(s)
      M. Takahashi
    • Organizer
      6th ISGS Summer School, Frontiers in Hybrid Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Oriented oxide and MOF films using metal hydroxides2018

    • Author(s)
      K. Okada, K. Ikigaki, S. Shirashiki, Y. Tokudome, M. Takahashi
    • Organizer
      6th ISGS Summer School, Frontiers in Hybrid Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ag loaded MOF-on-MOF film on oriented copper hydroxides substrates for anisotropic plasmonic resonance2018

    • Author(s)
      K. Ikigaki, K. Okada, Y. Tokudome, P. Falcaro, C. Doonan, M. Takahashi
    • Organizer
      6th ISGS Summer School, Frontiers in Hybrid Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reactivity of silanol group in phenyl-methyl siloxane oligomer2018

    • Author(s)
      D. Kino, K. Okada, Y. Tokudome, M. Takahashi
    • Organizer
      6th ISGS Summer School, Frontiers in Hybrid Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hierarchically Porous Metal Hydroxides Through an Assembly of Crystalline Nanobuilding Blocks.2018

    • Author(s)
      Y. Tokudome, M. Takahashi
    • Organizer
      14th International Ceramics Congress (CIMTEC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication and application of oriented metal-organic framework films via heteroepitaxial growth on inorganic substrate2018

    • Author(s)
      M. Takahashi
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Oriented Metal Organic Framework films on centimetre length scales2018

    • Author(s)
      K. Okada, K. Ikigaki, P. Falcaro, C. Doonan, Y. Tokudome, M. Takahashi
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oriented oxide and MOF films from metal hydroxide quasi-single-crystal films.2018

    • Author(s)
      K. Okada, Y. Tokudome, M. Takahashi
    • Organizer
      3rd International Conference on Nanomaterials for Health, Energy and the Environment
    • Related Report
      2018 Annual Research Report
  • [Presentation] Hierarchically Porous Layered Double Hydroxide (LDH) Toward Enhanced Adsorption and Catalytic Properties.2018

    • Author(s)
      Y. Tokudome, M. Fukui, S. Nishimura, M. Takemoto, K. Okada, V. Prevot, C. Forano, M. Takahashi
    • Organizer
      J-FR 2018: Journee Francophone De La Recherche 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポルフィリン誘導体を有機配位子とした配向Metal-organic framework(MOF)薄膜の作製と光学的応用に向けた特性評価2018

    • Author(s)
      藤井翔悟, 徳留靖明, 岡田健司, 高橋雅英
    • Organizer
      日本セラミックス協会関西支部 第13回 学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fabrication and functionalization of oriented multi-layered thin films of metal-organic frameworks (MOF-on-MOF)2018

    • Author(s)
      K. Ikigaki, K. Okada, Y. Tokudome, P. Falcaro, C. Doonan, M. Takahashi
    • Organizer
      錯体化学会第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Coarsening in oriented films of Cu-puddle wheel MOF via heteroepitaxially-growth on Cu(OH)2 surface2018

    • Author(s)
      M. Nakanishi, K. Ikigaki, K. Okada, Y. Tokudome, M. Takahashi
    • Organizer
      錯体化学会第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水酸化銅基板上に成長した多層配向性MOF薄膜への銀ナノ粒子導入2018

    • Author(s)
      生垣賢, 岡田健司, 徳留靖明, P. Falcaro, C. Doonan, 高橋雅英
    • Organizer
      日本ゾルーゲル学会 第16回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光学的応用に向けたポルフィリン誘導体を骨格とする配向金属有機構造体(MOF)薄膜の形成2018

    • Author(s)
      藤井翔悟, 岡田健司, 徳留靖明, 高橋雅英
    • Organizer
      日本ゾルーゲル学会 第16回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高配向度を有するMOF薄膜の作製と細孔修飾による光機能性付与2018

    • Author(s)
      中西美晴,岡田健司, 徳留靖明, 高橋雅英
    • Organizer
      日本ゾルーゲル学会 第16回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属水酸化物擬単結晶薄膜を用いたトポタクティック反応による配向性酸化物薄膜の形成2018

    • Author(s)
      岡田健司, 白敷修平, 徳留靖明, 高橋雅英
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Centimetre scale micropore alignment in the oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth2017

    • Author(s)
      Takahashi M.
    • Organizer
      NANOAPP
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Metal hydroxides as platform for interfacial functionalities2017

    • Author(s)
      Takahashi M.
    • Organizer
      PACRIM 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Centimetre scale micropore alignment in the oriented polycrystalline Metal-Organic Framework films via heteroepitaxial growth2017

    • Author(s)
      Takahashi M.
    • Organizer
      International Sol-Gel Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] PCP/MOFおよび各種多孔質材料の 作り方,使い方,評価解析2019

    • Author(s)
      岡田健司,高橋雅英(分担執筆)
    • Total Pages
      30
    • Publisher
      技術情報協会
    • ISBN
      9784861047695
    • Related Report
      2019 Annual Research Report
  • [Remarks] 大阪府立大学大学院工学研究科物質化学系専攻マテリアル工学分野ナノテク基盤材料研究グループ

    • URL

      http://mtr1.osakafu-u.ac.jp/lmnt/

    • Related Report
      2019 Annual Research Report

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Published: 2017-07-21   Modified: 2021-02-19  

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