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Adsorption purification of biogas and high-efficiency utilization of the adsorption heat

Research Project

Project/Area Number 17K00626
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionToyohashi University of Technology

Principal Investigator

MATSUMOTO AKIHIKO  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (90239088)

Co-Investigator(Kenkyū-buntansha) 伊藤 博光  豊橋技術科学大学, 工学(系)研究科(研究院), 助教 (00780579)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords吸着 / 真空圧力スイング吸着 / ゼオライト / 二酸化炭素 / 吸着熱 / 消化ガス / 脱着 / Toth式 / VPSA / CO2 / 分離精製 / 高純度化
Outline of Final Research Achievements

A vacuum pressure swing adsorption system with twin adsorption towers is applicable to high efficiency adsorption separation of carbon dioxide (CO2). In this study, two adsorption towers are connected together with thermal conducting devices to transfer adsorption heat evolved at an adsorption tower (A) in the adsorption process of CO2 to another tower (B) in the desorption process. The adsorption heat in the tower A successfully conducts the tower B; the temperature inside the tower A dropped by ca.10K and that in the tower B increased. The adsorption amount of CO2 in the tower A increased by 1.5 times since the temperature in the tower A was suppressed by the heat conductor. These results is applicable to highly efficient separation of CO2 by the system.

Academic Significance and Societal Importance of the Research Achievements

本研究での吸着剤の検討によりCO2とゼオライト表面の陽イオン間の相互作用機構に対するイオン数・種の効果が明らかになった。また,適切な熱伝導体で2つの吸着塔を熱的に連結することで,吸着に伴い発生する熱の除去と有効利用が実現した。本技術を最適化して実用化できれば,CO2除去が望まれている,製鉄,下水処理に利用できる。さらに本技術は他の気体についての効率良い吸着脱離への応用が期待できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (13 results)

All 2019 2018

All Journal Article (3 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Journal Article] Water adsorption characteristics and microcalorimetric studies of MOF-5 and MOF-199 synthesized using “green” sol-gel2019

    • Author(s)
      H. Misran, S.Z. Othman, N. Mahadi, Z. Aspanut, Z. Lockman, A. Matsumoto, N. Amin
    • Journal Title

      Acta Physica Polonica A

      Volume: 135 Issue: 5 Pages: 1119-1122

    • DOI

      10.12693/aphyspola.135.1119

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] ポリフェニレンスルフィド樹脂/熱伝導性フィラー複合材料の高熱伝導化におよびアボスフィラーの形状効果2018

    • Author(s)
      永谷,寺尾,松山,高木,高木,伊藤,松本,竹市
    • Journal Title

      材料の科学と工学

      Volume: 50 Pages: 1-7

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Room Temperature Synthesis and Characterizations of ZIF-8 Formation at Water-Fatty Alcohols Interface2018

    • Author(s)
      H. Misran, N. Mahadi, S.Z. Othman, Z. Lockman, N. Amin, A. Matsumoto
    • Journal Title

      IOP Conf. Series: Journal of Physics: Conf. Series

      Volume: 1082 Pages: 1-6

    • DOI

      10.1088/1742-6596/1082/1/012046

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Correlation Between Adsorption Energy and Chromatographic Selectivity of Aromatics on Silanized Mesoporous Silica2019

    • Author(s)
      A. Matsumoto, S. Nishimura, H. Ito
    • Organizer
      The 13th International Conference on Fundamentals of Adsorption
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dynamic Cluster Aggregation and Molecular Hopping of Water in Carbon Nano Pores2019

    • Author(s)
      Hiromitsu Ito, Yuji Ono, Fernando Vallejos-Burgos, Ryusuke Futamura, Katsumi Kaneko, Taku Iiyama, Akihiro Matsumoto
    • Organizer
      The 13rh International Conference on Fundamentals of Adsorption
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hopping Diffusion of CO2 in Pores of Na-FAU Type Zeolite2019

    • Author(s)
      Hiromitsu ITO, Ryota, OZAKI, Kango SAKASHITA, Akihiko MATSUMOTO
    • Organizer
      The 13th International Conference on Fundamentals of Adsorption
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] FAU型ゼオライトへのCO2吸着における細孔内拡散と粒子表面透過の競争2019

    • Author(s)
      尾崎稜太,伊藤博光,松本明彦
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 粒子径に依存したZIF-8のVOCs吸着熱挙動2019

    • Author(s)
      中谷祐太,伊藤博光,松本明彦
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 吸着熱を利用した高効率VPSAシステムの開発2019

    • Author(s)
      吉川幸佑,伊藤博光,松本明彦,清野重之,秋葉喜久男,網谷基徳
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] アンモニア吸着ミクロカロリメトリ―によるCa-Xの酸点の特性化2019

    • Author(s)
      小熊亮弘,伊藤博光,松本明彦
    • Organizer
      第35回ゼオライト研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Characterization of Adsorption-Desorption and Diffusion of Carbon Dioxide in Micropores of Low Silica X Zeolite by Frequency Response Method2018

    • Author(s)
      A. Matsumoto, K. Sakashita, H. Ito
    • Organizer
      International Symposium on Zeolites and Microporous Crystals 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characterization of Electrostatic Field Strength in Zeolite Cavities by Adsorption Microcalorimetry of Methane as Probe Molecule2018

    • Author(s)
      A. Matsumoto, S. Mizuno, H.Ito
    • Organizer
      8th Pacific Basin Conference on Adsorption Science and Technology
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Na-LSX細孔内におけるCO2分子のホッピング酢酸に対する交換性カチオンの影響2018

    • Author(s)
      尾崎,坂下,伊藤,松本
    • Organizer
      第32回日本吸着学会研究発表会
    • Related Report
      2018 Research-status Report
    • Invited

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Published: 2017-04-28   Modified: 2021-02-19  

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