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Fabrication of ferroelectric b-axis-orientated lead-free film with robust design against abnormal heat

Research Project

Project/Area Number 17K05063
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionHosei University

Principal Investigator

AKASHI Takaya  法政大学, 生命科学部, 教授 (20312647)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords強誘電体 / 二チタン酸バリウム / チタン酸バリウム / コンポジット薄膜 / 高温 / 電気泳動堆積法 / 薄膜 / 配向
Outline of Final Research Achievements

Artificial intelligence (AI) is applied to the industrial field which has serious influence on human life. Therefore, we are aiming at development of capacitor materials for high-temperature application that could supply electric power to a central processing unit (CPU) until safety is secured when the fire accident occurs.
For fabrication of the capacitor materials for high-temperature application, high-temperature ferroelectric BaTi2O5 particles was dispersed in ferroelectric BaTiO3. Because crystal of BaTi2O5 particle must be oriented for the anisotropic ferroelectric property and BaTi2O5 phase is decomposed at high temperature above 1000 degree Celsius, BaTiO3 precursor solution with BaTi2O5 suspended particle was coated in the electric field.

Academic Significance and Societal Importance of the Research Achievements

準安定相のBaTi2O5粉末を、比較的高い生成率で効率的に作製する種々の方法を試行し、急冷凝固法を適用するに至った。また、このBaTi2O5粉末を用いた電気泳動堆積法と、ゾル-ゲル法を用いたBaTiO3薄膜作製の技術を組み合わせて、BaTi2O5粒子を分散させたBaTiO3薄膜を作製することに成功した。この高温用コンデンサの性能を向上させるためには、薄膜中のBaTi2O5粒子の結晶配向度をさらに高めることが必要であるが、ゾル-ゲル法と電気泳動堆積法の両方の特徴を活かした独自の装置設計を開発するに至った。この独自の装置設計は本研究課題の重要な成果の一つであり、今後の展開が大いに期待できる。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (12 results)

All 2019 2018 2017

All Presentation (12 results) (of which Int'l Joint Research: 5 results)

  • [Presentation] Crystalline-oriented Lanthanum Silicate Oxyapatite Ceramics Fabricated by Electrophoretic Deposition under a Strong Magnetic Field2019

    • Author(s)
      S. Takano, K. Kobayashi, T. Uchikoshi, T. Akashi, T. S. Suzuki
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal Expansion and Shrinkage during a Heating Stage of Firing of BaTiO3 Powder Compact at Various Heating Rates2019

    • Author(s)
      N. Hamada, N Iwata, T. Akashi, T. Mori
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] オキシアパタイト型ランタンシリケート配向膜の作製と伝導度の評価2019

    • Author(s)
      鷹野紗央里,小林清,明石孝也,打越哲郎,鈴木達
    • Organizer
      第57回セラミックス基礎科学討論会
    • Related Report
      2018 Research-status Report
  • [Presentation] オキシアパタイト型ランタンシリケートの3段階熱処理プロセスにおける再酸化条件の影響2018

    • Author(s)
      山添敦司,小林清,打越哲郎,明石孝也,鈴木達
    • Organizer
      セラミックス協会第31回秋季シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Fabrication of Lanthanum Silicate Oxyapatite Ceramics with Crystal Orientation by Slip Casting in a Strong Magnetic Field2018

    • Author(s)
      Atsushi Yamazoe, Kiyoshi Kobayashi, Tetsuo Uchikoshi, Takaya Akashi, Thoru S. Suzuki
    • Organizer
      WAIM 2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 焼成時の昇温速度がチタン酸バリウム成形体の膨張・収縮挙動に与える影響2018

    • Author(s)
      濱田奈美,岩田尚也,明石孝也,森 隆昌
    • Organizer
      無機マテリアル学会第137回学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] 強磁場配向法と熱処理最適化によるc軸配向オキシアパタイト型ランタンシリケートの高イオン伝導体化2018

    • Author(s)
      山添敦司, 小林 清, 打越哲郎, 明石孝也, 鈴木 達
    • Organizer
      第56回セラミック基礎科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 層状ペロブスカイト型混合伝導体の配向制御と異方特性評価2018

    • Author(s)
      矢野広将, 打越哲郎, 小林 清, 明石孝也, 鈴木 達
    • Organizer
      第56回セラミック基礎科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Orientation Control and Anisotropy Evaluation of Layered Perovskite-Type Mixed Conductor2017

    • Author(s)
      Hiromasa Yano, Tetsuo Uchikoshi, Kiyoshi Kobayashi, Takaya Akashi, Tohru S. Suzuki
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Heat Treatment Dependence on the Degree of Crystalline Orientation and Oxide-ion Conductivity of Lanthanum Silicate Oxyapatite2017

    • Author(s)
      Atsushi Yamazoe, Kiyoshi Kobayashi, Tetsuo Uchikoshi, Takaya Akashi, Tohru S. Suzuki
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 層状ペロブスカイト型混合伝導体の配向制御と異方特性評価2017

    • Author(s)
      矢野広将, 打越哲郎, 明石孝也, 小林 清, 鈴木 達
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] オキシアパタイト型ランタンシリケートの熱処理による結晶配向と酸化物イオン伝導への影響2017

    • Author(s)
      山添敦司, 小林 清, 打越哲郎, 明石孝也, 鈴木 達
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-03-04  

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