• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Study on magnetic correlations in molecule-based magnets by inelastic neutron scattering using a chopper spectrometer

Research Project

Project/Area Number 17K05129
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

Kawamura Seiko  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 J-PARCセンター, 研究副主幹 (70360518)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords中性子非弾性散乱 / 分子磁性体 / 圧力効果 / 高圧下測定 / 中性子散乱 / 分子磁性
Outline of Final Research Achievements

Molecule-based magnets have variety in the material design and then exhibit various non-trivial phenomena. Since they are sensitive to physical pressure, we can study their magnetic properties systematically.
Inelastic neutron scattering (INS) is a powerful tool to study the magnetic properties. However, there are few reports of INS studies on molecule-base materials because of the difficulty to apply it on the molecule-based materials due to some reasons such as contained protons.
In this study, I have prepared high-pressure environment for the INS experiments, and developed a compact radial collimator to extract weak signals from a molecule-based magnet in the pressure cell by eliminating background from the cell. Furthermore, I observed phonon vibration modes of a molecule-based magnet reflecting the crystal structure under pressure. This study will suggest a possibility of the INS measurement for studies of magnetism in molecule-based materials.

Academic Significance and Societal Importance of the Research Achievements

分子磁性体は、新しいデバイスとしての応用を見据えた基礎的な磁性研究が盛んに行われている物質群である。物質の磁性研究において最も強力な実験手法の一つが中性子非弾性散乱であるが、分子性の物質特有のいくつかの困難により、中性子散乱実験がほとんど行われていなかった。
本研究では、中性子非弾性散乱実験を行うためのチョッパー分光器における分子性物質の圧力下測定のデータを改善することに成功した。これにより、分子磁性体の中性子散乱による研究が推進されるようになれば、磁気的性質の解明が進み、ひいては将来の新規デバイス開発に繋がることも期待される。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (28 results)

All 2021 2020 2019 2018 2017

All Journal Article (16 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 16 results,  Open Access: 10 results) Presentation (12 results) (of which Int'l Joint Research: 7 results,  Invited: 2 results)

  • [Journal Article] Recent Update of AMATERAS: A Cold-Neutron Disk-Chopper Spectrometer2021

    • Author(s)
      Nakajima Kenji、Ohira-Kawamura Seiko、Kofu Maiko、Murai Naoki、Inamura Yasuhiro、Kikuchi Tatsuya、Wakai Daisuke
    • Journal Title

      JPS Conf. Proc.

      Volume: 3

    • DOI

      10.7566/jpscp.33.011089

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gapless spin liquid in a square-kagome lattice antiferromagnet2020

    • Author(s)
      M. Fujihala, K. Morita, R. Mole, S. Mitsuda, T. Tohyama, S. Yano, D. Yu, S. Sota, T. Kuwai, A. Koda, H. Okabe, H. Lee, S. Itoh, T. Hawai, T. Masuda, H. Sagayama, A. Matsuo, K. Kindo, S. Ohira-Kawamura, and K. Nakajima
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 3429-3429

    • DOI

      10.1038/s41467-020-17235-z

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] q=0 long-range magnetic order in centennialite CaCu3(OD)6Cl2・0.6D2O: A spin-1/2 perfect kagome antiferromagnet with J1-J2-Jd;2020

    • Author(s)
      K. Iida, H. K. Yoshida, A. Nakao, H. O. Jeschke, Y. Iqbal, K. Nakajima, S. Ohira-Kawamura, K. Munakata, Y. Inamura, N. Murai, M. Ishikado, R. Kumai, T. Okada, M. Oda, K. Kakurai, and M. Matsuda
    • Journal Title

      Phys. Rev. B

      Volume: 101 Issue: 22 Pages: 220408-220408

    • DOI

      10.1103/physrevb.101.220408

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Colossal barocaloric effects in plastic crystals2019

    • Author(s)
      Li Bing、Kawakita Yukinobu、Ohira-Kawamura Seiko、Sugahara Takeshi、Wang Hui、Wang Jingfan、Chen Yanna、Kawaguchi Saori I.、Kawaguchi Shogo、Ohara Koji、他13名
    • Journal Title

      Nature

      Volume: 567 Issue: 7749 Pages: 506-510

    • DOI

      10.1038/s41586-019-1042-5

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Status of neutron spectrometers at J-PARC2019

    • Author(s)
      Ryoichi Kajimoto, Tetsuya Yokoo, Mitsutaka Nakamura, Yukinobu Kawakita, Masato Matsuura, Hitoshi Endo, Hideki Seto, Shinichi Itoh, Kenji Nakajima, Seiko Ohira-Kawamura
    • Journal Title

      Physica B

      Volume: 562 Pages: 148-152

    • DOI

      10.1016/j.physb.2018.11.061

    • NAID

      120007153036

    • Related Report
      2019 Research-status Report 2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Cryogenic sample environments shared at the MLF, J-PARC2019

    • Author(s)
      S. Ohira-Kawamura, R. Takahashi, M. Ishikado, Y. Yamauchi, M. Nakamura, K. Ohuchi, H. Kira, W. Kambara, K. Aoyama, Y. Sakaguchi, M. Watanabe and T. Oku
    • Journal Title

      J. Neutron Research

      Volume: 21 Issue: 1-2 Pages: 17-22

    • DOI

      10.3233/jnr-190106

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Background issues encountered by cold-neutron chopper spectrometer AMATERAS2019

    • Author(s)
      T. Kikuchi, K. Nakajima, S. Ohira-Kawamura, Y. Inamura, M. Nakamura, D. Wakai, K. Aoyama, T. Iwahashi and W. Kambara
    • Journal Title

      Physica B

      Volume: 564 Pages: 45-53

    • DOI

      10.1016/j.physb.2019.02.015

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spin correlations of quantum spin liquid and quadrupole-ordered state of Tb2+xTi2-xO7+y2019

    • Author(s)
      H. Kadowaki, M. Wakita, B. Fak, J. Ollivier, S. Ohira-Kawamura, K. Nakajima and J. W. Lynn
    • Journal Title

      Phys. Rev. B

      Volume: 99 Issue: 1

    • DOI

      10.1103/physrevb.99.014406

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Recent issues encountered by AMATERAS: a cold neutron disk chopper spectrometer2018

    • Author(s)
      K. Nakajima, S. Ohira-Kawamura, T. Kikuchi, M. Kofu, Y. Kawakita, Y. Inamura, W. Kambara, K. Aoyama, D. Wakai, M. Harada and M. Ooi
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: 1021 Pages: 012031-012031

    • DOI

      10.1088/1742-6596/1021/1/012031

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quantum paramagnet near spin-state transition2018

    • Author(s)
      K. Tomiyasu, N. Ito, R. Okazaki, Y. Takahashi, M. Onodera, K. Iwasa, T. Nojima, T. Aoyama, K. Ohgushi, Y. Ishikawa, T. Kamiyama, S. Ohira-Kawamura, M. Kofu and S. Ishihara
    • Journal Title

      Advanced Quantum Technology

      Volume: 2018 Issue: 3 Pages: 1800057-1800057

    • DOI

      10.1002/qute.201800057

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Continuum excitation and pseudospin wave in quantum spin-liquid and quadrupole ordered states of Tb2+xTi2-xO7+y2018

    • Author(s)
      H. Kadowaki, M. Wakita, B. Fak, J. Ollivier, S. Ohira-Kawamura, K. Nakajima, H. Takatsu and M. Tamai
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 87 Issue: 6 Pages: 0647041-6

    • DOI

      10.7566/jpsj.87.064704

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic properties of one-dimensional quantum spin system Rb2Cu2Mo3O12 studied by muon spin relaxation2018

    • Author(s)
      S. Ohira-Kawamura, K. Tomiyasu, A. Koda, D. P. Sari, R. Asih, S. Yoon, I. Watanabe and K. Nakajima
    • Journal Title

      JPS Conf. Proc.

      Volume: 21 Pages: 11007-11007

    • DOI

      10.7566/jpscp.21.011007

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structure of the magnetic excitations in the spin-1/2 triangular-lattice Heisenberg antiferromagnet Ba3CoSb2O92017

    • Author(s)
      Ito Saya、Kurita Nobuyuki、Tanaka Hidekazu、Ohira-Kawamura Seiko、Nakajima Kenji、Itoh Shinichi、Kuwahara Keitaro、Kakurai Kazuhisa
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1

    • DOI

      10.1038/s41467-017-00316-x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sample Environment at the J-PARC MLF2017

    • Author(s)
      S. Ohira-Kawamura, T. Oku, M. Watanabe, R. Takahashi, K. Munakata, S. Takata, Y. Sakaguchi, M. Ishikado, K. Ohuchi, T. Hattori, H. Kira, K. Sakai, T. Aso, Y. Yamauchi and S. Isomae
    • Journal Title

      J. Neutron Research

      Volume: 19 Issue: 1-2 Pages: 15-22

    • DOI

      10.3233/jnr-170046

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polar rotor scattering as atomic-level origin of low mobility and thermal conductivity of perovskite CH3NH3PbI32017

    • Author(s)
      B. Li, Y. Kawakita, Y. Liu, M. Wang, M. Matsuura, K. Shibata, S. Ohira-Kawamura, T. Yamada, S. Lin, K. Nakajima and S. Liu
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1

    • DOI

      10.1038/ncomms16086

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interaction of spin-orbital-lattice degrees of freedom - vibrionic state of corner-sharing-tetrahedral spin frustrated system HoBaFe4O7 by dynamical Jahn-Teller Effect -2017

    • Author(s)
      K. Kamazawa, M. Ishikado, S. Ohira-Kawamura, Y. Kawakita, K. Kakurai, K. Nakajima and M. Sato
    • Journal Title

      Phys. Rev. B

      Volume: 92 Issue: 10

    • DOI

      10.1103/physrevb.95.104413

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 冷中性子ディスクチョッパー型分光器AMATERASの2020年2020

    • Author(s)
      河村 聖子、古府 麻衣子、中島 健次、村井 直樹、稲村 泰弘、若井 大介
    • Organizer
      日本中性子科学会第20回年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Introduction of cold-neutron disk chopper spectrometer AMATERAS and recent results2019

    • Author(s)
      S. Ohira-Kawamura
    • Organizer
      Workshop on Neutron and X-ray Characterizations on Caloric Materials (NXCalorics-2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] μSR法でみたEt2Me2Sb[Pd(dmit)2]2の中間非整合相のスピンダイナミクス2019

    • Author(s)
      河村聖子、Laurent Guerin、渡邊功雄、加藤礼三
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Magnetic properties of intermediate incommensurate phase in Et2Me2Sb[Pd(dmit)2]2 studied by μSR2019

    • Author(s)
      S. Ohira-Kawamura, L. Guerin, I. Watanabe and R. Kato
    • Organizer
      13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] MLFにおける試料環境の現状2018

    • Author(s)
      河村聖子、奥隆之、渡辺真朗、坂口佳史、高橋竜太、有馬寛、高田慎一、石角元志、大内啓一、山内康弘、中村雅俊
    • Organizer
      User Group Meeting on MLF Spectrometers(DIRECTION 2018)
    • Related Report
      2018 Research-status Report
  • [Presentation] クランプセルを用いた圧力下非弾性散乱測定の手法開発2018

    • Author(s)
      河村聖子、服部高典、佐野亜沙美、有馬寛、町田真一、石角元志、宗像孝司、菊地龍弥、古府麻衣子、中島健次
    • Organizer
      User Group Meeting on MLF Spectrometers(DIRECTION 2018)
    • Related Report
      2018 Research-status Report
  • [Presentation] Status of cryogenics and magnets at J-PARC MLF2018

    • Author(s)
      S. Ohira-Kawamura, R. Takahashi, S. Ohira-Kawamura, M. Ishikado, K. Ohuchi, Y. Yamauchi, M. Nakamura, H. Kira, W. Kambara, K. Aoyama, M. Watanabe and T. Oku
    • Organizer
      10th International Workshop on Sample Environment at Scattering Facilities
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic ground state and dynamics in one-dimensional quantum spin system Rb2Cu2Mo3O12 studied by μSR2018

    • Author(s)
      S. Ohira-Kawamura, K. Tomiyasu, A. Koda, D. P. Sari, R. Asih, S. Yoon, I. Watanabe, and K. Nakajima
    • Organizer
      3rd International Symposium of Quantum Beam Science at Ibaraki University
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] クランプセルを用いた圧力下の低エネルギー中性子非弾性散乱の手法開発2018

    • Author(s)
      河村聖子、服部高典、佐野亜沙美、菊地龍弥、古府麻衣子、中島健次、宗像孝司
    • Organizer
      2017年度量子ビームサイエンスフェスタ
    • Related Report
      2017 Research-status Report
  • [Presentation] Phonon modes of β'-(BEDT-TTF)2ICl2 coupled with charge and spin studied by inelastic neutron scattering2017

    • Author(s)
      S. Ohira-Kawamura, M. Matsuura, S. Iguchi, T. Sasaki, H. Taniguchi, A. Kubota, K. Satoh, Y. Inamura, T. Kikuchi and K. Nakajima
    • Organizer
      12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Studies on phonon modes in a molecular dimer-Mott insulator β'-(BEDT-TTF)2ICl2 by inelastic neutron scattering2017

    • Author(s)
      S. Ohira-Kawamura, M. Matsuura, S. Iguchi, T. Sasaki, H. Taniguchi, A. Kubota, K. Satoh, Y. Inamura, T. Kikuchi and K. Nakajima
    • Organizer
      International Conference on Neutron Scattering (ICNS2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic properties of one-dimensional quantum spin system Rb2Cu2Mo3O12 studied by mSR2017

    • Author(s)
      S. Ohira-Kawamura, K. Tomiyasu, A. Koda, Dita P. Sari, R. Asih, S. Yoon, I. Watanabe, K. Nakajima
    • Organizer
      14th International Conference on Muon Spin Rotation, Relaxation and Resonance (mSR2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

URL: 

Published: 2017-04-28   Modified: 2022-01-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi