Synthesis of Functional Materials from Carbon Dioxide and Biomass
| Project/Area Number |
17K05959
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Osaka Research Institute of Industrial Science and Technology |
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Principal Investigator |
Mihara Masatoshi 地方独立行政法人大阪産業技術研究所, 有機材料研究部, 主任研究員 (70416296)
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| Co-Investigator(Kenkyū-buntansha) |
水野 卓巳 地方独立行政法人大阪市立工業研究所, 有機材料研究部, 部長 (10416290)
中井 猛夫 地方独立行政法人大阪産業技術研究所, 森之宮センター, 主任研究員 (60443545)
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| Project Period (FY) |
2017-04-01 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2020)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 二酸化炭素 / バイオマス / カーボネート / エポキシド / 合成化学 |
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| Outline of Final Research Achievements |
The conversion of carbon dioxide and biomass derivatives into raw materials that potentially possess self-healing functionality was achieved. The key step in this process is the synthesis of cyclic carbonates from carbon dioxide and epoxides, and we developed the catalytic system that worked efficiently even under ambient conditions. The present catalyst composed of metal halides and a strong organic base is considered to show high activity because of the cooperative effect of an iodide anion and Lewis acids.
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| Academic Significance and Societal Importance of the Research Achievements |
常温・常圧下、入手容易な試薬を触媒として利用し、二酸化炭素を環状カーボネート類へ変換した。本反応を利用することにより、温和な条件で二酸化炭素やバイオマスを構成ユニットとする有用物質への変換が行える。本変換は、加熱エネルギーの消費を抑え、しかも持続可能な原料を利用できることから、今後の合成プロセス開発へ有益な指針を与える。
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Report
(5 results)
Research Products
(16 results)
