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Synthesis of Functional Materials from Carbon Dioxide and Biomass

Research Project

Project/Area Number 17K05959
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionOsaka Research Institute of Industrial Science and Technology

Principal Investigator

Mihara Masatoshi  地方独立行政法人大阪産業技術研究所, 有機材料研究部, 主任研究員 (70416296)

Co-Investigator(Kenkyū-buntansha) 水野 卓巳  地方独立行政法人大阪市立工業研究所, 有機材料研究部, 部長 (10416290)
中井 猛夫  地方独立行政法人大阪産業技術研究所, 森之宮センター, 主任研究員 (60443545)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2020: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2019: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords二酸化炭素 / バイオマス / カーボネート / エポキシド / 合成化学
Outline of Final Research Achievements

The conversion of carbon dioxide and biomass derivatives into raw materials that potentially possess self-healing functionality was achieved. The key step in this process is the synthesis of cyclic carbonates from carbon dioxide and epoxides, and we developed the catalytic system that worked efficiently even under ambient conditions. The present catalyst composed of metal halides and a strong organic base is considered to show high activity because of the cooperative effect of an iodide anion and Lewis acids.

Academic Significance and Societal Importance of the Research Achievements

常温・常圧下、入手容易な試薬を触媒として利用し、二酸化炭素を環状カーボネート類へ変換した。本反応を利用することにより、温和な条件で二酸化炭素やバイオマスを構成ユニットとする有用物質への変換が行える。本変換は、加熱エネルギーの消費を抑え、しかも持続可能な原料を利用できることから、今後の合成プロセス開発へ有益な指針を与える。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • Research Products

    (16 results)

All 2021 2020 2019 2018 2017

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (9 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] 質量分析の基礎(第5回/全5回)2019

    • Author(s)
      静間基博、三原正稔、中井猛夫、岩井利之、松元深、佐藤博文
    • Journal Title

      科学と工業

      Volume: 93 Pages: 50-61

    • Related Report
      2018 Research-status Report
  • [Journal Article] Selective Synthesis of Carbonates from Glycerol, CO2, and Alkyl Halides Using tert-Butyltetramethylguanidine2018

    • Author(s)
      Masatoshi Mihara, Kaname Moroga, Tetsuo Iwasawa, Takeo Nakai, Takatoshi Ito, Toshinobu Ohno, Takumi Mizuno
    • Journal Title

      Synlett

      Volume: 29 Issue: 13 Pages: 1759-1764

    • DOI

      10.1055/s-0037-1610027

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] グリセロールと二酸化炭素の有効利用を目指した付加価値製品への変換2018

    • Author(s)
      三原正稔
    • Journal Title

      アグリバイオ

      Volume: 2 Pages: 48-49

    • Related Report
      2018 Research-status Report
  • [Journal Article] Transition-Metal-Free and Oxidant-Free Cross-Coupling of Arylhydrazines with Disulfides: Base-Promoted Synthesis of Unsymmetrical Aryl Sulfides2017

    • Author(s)
      Toshihide Taniguchi, Takuya Naka, Mitsutaka Imoto, Motonori Takeda, Takeo Nakai, Masatoshi Mihara, Takumi Mizuno, Akihiro Nomoto, and Akiya Ogawa
    • Journal Title

      J. Org. Chem.

      Volume: 82 Issue: 13 Pages: 6647-6655

    • DOI

      10.1021/acs.joc.7b00767

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] tert-Butyltetramethylguanidine-Promoted Synthesis of Butyl Carbamate from Ammonium Carbamate and Butyl Bromide2021

    • Author(s)
      三原正稔、野﨑大雅、兵藤憲吾、中井猛夫、伊藤貴敏
    • Organizer
      第101回日本化学会春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] グリーンケミストリーを指向した反応開発ー二酸化炭素の有効利用を中心にー2021

    • Author(s)
      三原正稔
    • Organizer
      第9回若手学識者との異分野交流会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ZnI2-NbCl5-MTBD-Catalyzed Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides under Ambient Conditions2020

    • Author(s)
      三原正稔、中井猛夫、伊藤貴敏
    • Organizer
      第100回日本化学会春季年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 常温・常圧で二酸化炭素を利用するカーボネート合成2019

    • Author(s)
      三原正稔
    • Organizer
      森之宮センター研究懇談会
    • Related Report
      2019 Research-status Report
  • [Presentation] 常温・常圧で二酸化炭素を利用するカーボネート合成2019

    • Author(s)
      三原正稔、中井猛夫
    • Organizer
      ORIST技術シーズ・成果発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] Metal Halide-Organic Base: Efficient Catalytic System for Coupling of Carbon Dioxide and Styrene Oxide2019

    • Author(s)
      三原正稔、中井猛夫、伊藤貴敏、大野敏信、水野卓巳
    • Organizer
      第99回日本化学会春季年会
    • Related Report
      2018 Research-status Report
  • [Presentation] 二酸化炭素やグリセロールを原料として用いる有用物質への変換2018

    • Author(s)
      三原正稔
    • Organizer
      ORIST技術情報セミナー
    • Related Report
      2018 Research-status Report
  • [Presentation] Synthesis of Cyclic Carbonates from Carbon Dioxide and Styrene Oxide under Room Temperature and Atmospheric Pressure2018

    • Author(s)
      三原正稔、中井猛夫、伊藤貴敏、大野敏信、水野卓巳
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] アリールヒドラジン類とジスルフィド類を用いた遷移金属および酸化剤を必要としない非対称アリールスルフィド合成2017

    • Author(s)
      谷口寿英、中拓弥、井本充隆、竹田元則、中井猛夫、三原正稔、水野卓巳、野元昭宏、小川昭弥
    • Organizer
      日本プロセス化学会2017サマーシンポジウム
    • Related Report
      2017 Research-status Report
  • [Patent(Industrial Property Rights)] 新規なジエポキシ化合物2018

    • Inventor(s)
      山本智也、芦田一仁、水野卓巳、伊藤貴敏、三原正稔
    • Industrial Property Rights Holder
      山本智也、芦田一仁、水野卓巳、伊藤貴敏、三原正稔
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2018 Research-status Report
  • [Patent(Industrial Property Rights)] 新規なビス(ヒドロキシフェニル)ベンゾオキサゾール化合物2017

    • Inventor(s)
      西原匡彦、芦田一仁、水野卓巳、伊藤貴敏、三原正稔
    • Industrial Property Rights Holder
      西原匡彦、芦田一仁、水野卓巳、伊藤貴敏、三原正稔
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Acquisition Date
      2018
    • Related Report
      2018 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 新規なビス(ヒドロキシフェニル)ベンゾオキサゾール化合物2017

    • Inventor(s)
      西原、芦田、水野、伊藤、三原、岩井、中井
    • Industrial Property Rights Holder
      西原、芦田、水野、伊藤、三原、岩井、中井
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Acquisition Date
      2017
    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2022-01-27  

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