Development of advanced nanosheet bumbles, structural control and applications to energy devices
Project/Area Number |
17K06347
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Electronic materials/Electric materials
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Research Institution | Shizuoka University |
Principal Investigator |
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Project Period (FY) |
2017-04-01 – 2020-03-31
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Project Status |
Completed (Fiscal Year 2019)
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Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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Keywords | シリサイド / 化学気相成長法 / 結晶成長 / ナノシート / ナノ構造制御 / テンプレート結晶粒 / 熱電素子 / 自然エネルギー / シリコン / トポケミカル反応 / ボールミリング処理 / ナノ材料 / 電子・電気材料 / 半導体物性 / 再生可能エネルギー |
Outline of Final Research Achievements |
Synthesis techniques of a variety of compound nanosheet bundles has been developed, and structural control and morphological modification of the bundles were studied. Si nanosheet bundles were synthesized by IP6 treatment in aqueous solution, or heat treatment with NH4Cl or metal chlorides, using CaSi2-based crystal powder or CaSi2 domains grown on substrates, as templates, and their detailed structural properties were compared. In addition, Mg2Si/Si and MnSi1.7/Si nanosheet composites, Mg2Si nanosheet bundles, Si nanosheet / Si nanowire composites, MnSi1.7, Mg2SiO4, Ge, and CaF2 nanosheet bundles, oxide nanosheets in which Ca is desorbed from CaCuSi4O10 , were also synthesized. Furthermore, pellets were prepared using Mg2Si nanosheet bundle powders by thermal treatment with Sn powders.
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Academic Significance and Societal Importance of the Research Achievements |
CaSi2等の層状結晶からある原子を引き抜く事だけでなく,異種原子を添加する事により化合物ナノシート束を作製できた事,さらにフッ化水素酸処理を施す事によりCaF2ナノシート束を作製したように,ひとつの出発原料から様々なバラエティーに富んだナノシート束が作製出来る事を示した.ナノシート束からなる粉末より作製したペレットはバルクの場合と比べ,熱伝導率が大幅に減少している事が分かった.これらのナノシート束は熱電発電に有効である.また基板上にも作製出来ることからLiイオン電池の電極に有用である. 同手法で作製したSiナノシート/Siナノワイヤ複合体とあわせ,さらなる構造制御による機能化が期待される.
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Report
(4 results)
Research Products
(65 results)
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[Journal Article] Synthesis of CaF2 nanostructures from calcium silicide powders in diluted aqueous HF solution2020
Author(s)
Y. Ono, R. Ogino, M. Sakaida, K. Sasaki, N. Atsumi, Y. Numazawa, S. Itoh, T. Koga, Y. Huang, Y. Shimura, H. Tatsuoka, and N. Takahashi
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Journal Title
Jpn. J.Appl.Phys. Cof. Proc.
Volume: -
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Structural and Photoluminescence Properties of Mg2Si/Si Nanocomposites Consisting of Si Nanosheet Bundles and Mg2Si Deposits2019
Author(s)
Y. Huang, R. Tamaki, P. Yuan, Y. Kumazawa, N. Atsumi, V. Saxena, N. Ahsan, Y. Okada, Y. Hayakawa, and H. Tatsuoka
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Journal Title
Jpn. J. Appl. Phys.
Volume: 58 (SB)
Issue: SB
Pages: SBBK04-SBBK04
DOI
NAID
Related Report
Peer Reviewed
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[Journal Article] Morphological and Structural Modifications of Si-Based Nanostructures Synthesized from Metal Silicide Templates in IP6, Acid and Metal Chloride Solutions2018
Author(s)
Yalei Huang, Peiling Yuan, Yuki Kumazawa, Shinya Kusazaki, Yuya Saito, Vimal Saxena, Kazuma Konishi, Yuya Kujime, Tubasa Kato, Kaito Tanaka, Yasuhiro Hayakawa, Hirokazu Tatsuoka
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Journal Title
Defect and Diffusion Forum
Volume: 386
Pages: 61-67
Related Report
Peer Reviewed
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[Journal Article] Synthesis of flower-like Si nanostructures on Si substrates2017
Author(s)
Peiling Yuan, Ryo Tamaki, Hiroaki Suzuki, Kenta Sasaki, Makoto Nakayama, Yuya Saito, Shinya Kusazaki, Yuki Kumazawa, Xiang Meng, Nazmul Ahsan, Yoshitaka Okada and Hirokazu Tatsuoka
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Journal Title
Jpn. J. Appl. Phys.
Volume: 56
Issue: 5S1
Pages: 05DE05-05DE05
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Presentation] Morphological and structural modifications of Si-based nanostructures synthesized from metal silicide templates in IP6, acid and metal chloride solutions2018
Author(s)
Yalei Huang, Peiling Yuan, Yuki Kumazawa, Shinya Kusazaki, Yuya Saito, Vimal Saxena, Kazuma Konishi, Yuya Kujime, Tubasa Kato, Kaito Tanaka, Yasuhiro Hayakawa, and Hirokazu Tatsuoka
Organizer
The Fourth Asian School-Conference on Physics and Technology of Nanostructured Materials ASCO-NANOMAT 2018
Related Report
Int'l Joint Research / Invited
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[Presentation] Photoluminescence of Superlattice-like Structures in Si-based Nanosheet Bundles2018
Author(s)
P. Yuan, R. Tamaki, K. Sasaki, M. Nakayama, Y. Saito, S. Kusazaki, Y. Kumazawa, X. Meng, N. Ahsan, Y. Okada, and H. Tatsuoka
Organizer
第18回シリサイド系半導体夏の学校
Related Report
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[Presentation] KFM によるゼーベック係数評価のための Si ワイヤの表面電位測定2018
Author(s)
鈴木悠平, 岡晃人, 川合健斗, 熊田剛大, 島圭佑, 富田基裕, 立岡浩一, ファイズ サレ, 松木武雄, 渡邉孝信, 池田浩也
Organizer
第65回応用物理学会春季学術講演会
Related Report
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