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Development of Highly Emissive Host-Guest Complexes via Encapsulation of Metal Complexes within Hydrogen-bonded Capsules

Research Project

Project/Area Number 17K14463
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionNagasaki University

Principal Investigator

HORIUCHI Shinnosuke  長崎大学, 工学研究科, 助教 (50755915)

Project Period (FY) 2017-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords発光性超分子 / 自己集合 / 分子認識 / 光化学 / 超分子化学 / 自己組織化 / 光物性
Outline of Final Research Achievements

In this study, we investigated development of supramolecular metal complexes insulated by hydrogen-bonded capsules. We found size-dependent formation, excited-state dependent photophysical properties, and encapsulation-condition dependent photophysical properties of the supramolecular metal complexes. These results will open up broad prospects for designing new luminescent materials based on supramolecular metal complexes encapsulated within self-assembled capsules.

Academic Significance and Societal Importance of the Research Achievements

本研究によって金属錯体の包接に基づいた新規発光性超分子の合成手法の開拓とその発光特性の解明を達成した。これらの成果が基礎となり,新しいタイプの発光素子としての応用が見込めれば,材料工学の分野においても新たな切り口を与える可能性がある。現時点では,材料としての可能性は未知であるが,今後これらがもっと洗練され明確な有用性が実証された時には,既存の発光性材料に取って代わる可能性がある。

Report

(3 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • Research Products

    (23 results)

All 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (14 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Remarks (3 results)

  • [Int'l Joint Research] ドルトムント工科大学(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] フィリップ大学マーブルグ(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ドルトムント工科大学(ドイツ)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Encapsulation condition dependent photophysical properties of polypyridyl Ru(II) complexes within a hydrogen-bonded capsule2019

    • Author(s)
      Horiuchi Shinnosuke、Tanaka Hiroto、Sakuda Eri、Arikawa Yasuhiro、Umakoshi Keisuke
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 16 Pages: 5156-5160

    • DOI

      10.1039/c9dt00737g

    • NAID

      120006987732

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] U- to Z-shape isomerization in a Pt2Ag2 framework containing pyridyl-NHC ligands2018

    • Author(s)
      Horiuchi Shinnosuke、Moon Sangjoon、Sakuda Eri、Ito Akitaka、Arikawa Yasuhiro、Umakoshi Keisuke
    • Journal Title

      Dalton Transactions

      Volume: 印刷中 Issue: 21 Pages: 7113-7117

    • DOI

      10.1039/c8dt01047a

    • NAID

      120006988011

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible formation and cleavage of Pt→Ag dative bonds in a pre-organized cavity of a luminescent heteropolynuclear platinum(ii) complex2017

    • Author(s)
      Ueda Misa、Horiuchi Shinnosuke、Sakuda Eri、Nakao Yoshihide、Arikawa Yasuhiro、Umakoshi Keisuke
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 48 Pages: 6405-6408

    • DOI

      10.1039/c7cc03447d

    • NAID

      120006987456

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] NHC配位子を有する異種混合金属錯体の合成と構造2019

    • Author(s)
      文常準、堀内新之介、作田絵里、有川康弘、馬越啓介
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 白金及び11族元素からなる金属微粒子を担持した酸化チタン被覆石英粉末の光触媒活性2018

    • Author(s)
      水本駿人、荒木佑允、森村隆夫、堀内新之介、作田絵里、狩野伸自、有川康弘、馬越啓介
    • Organizer
      第55回化学関連支部合同九州大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Photophysical Properties of Mixed Metal Complexes Having NHC-based Chelating Ligands2018

    • Author(s)
      S. MOON, S. HORIUCHI, E. SAKUDA, A. ITO, Y. ARIKAWA, K. UMAKOSHI
    • Organizer
      錯体化学会第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水素結合性カプセル内でのカチオン性Ir錯体の発光挙動2018

    • Author(s)
      松尾知春、田中寛隆、堀内新之介、作田絵里、有川康弘、馬越啓介
    • Organizer
      錯体化学会第68回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Formation and Luminescent Properties of Emissive Supramolecular Complexes via Self-assembly and Encapsulation2018

    • Author(s)
      S. Horiuchi, E. Sakuda, Y. Arikawa, K. Umakoshi
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Luminescent Supramolecular Complexes via Encapsulation of Coordination Complexes within a Hexameric Capsule2018

    • Author(s)
      S. Horiuchi
    • Organizer
      ICCC 2018: Post Conference in Nagasaki
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dpa部位を二つ有する配位子を用いたZn二核錯体の合成と反応性2018

    • Author(s)
      松尾康優、堀内新之介、作田絵里、有川康弘、馬越啓介
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Enhanced Emission Properties of Ir(III) Complexes by Encapsulation within a Hydrogen-bonded Capsule2017

    • Author(s)
      S. Horiuchi, H. Tanaka, E. Sakura, Y. Arikawa, K. Umakoshi
    • Organizer
      22nd International Symposium on Photochemistry and Photophysics of Coordination Compounds
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Encapsulation and Enhanced Emission Properties of IrIII Complexes within a Hexameric Self-Assembled Capsule2017

    • Author(s)
      S. Horiuchi, H. Tanaka, E. Sakuda, Y. Arikawa, K. Umakoshi
    • Organizer
      The 12th International Symposium on Macrocyclic and Supramolecular Chemistry
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] ビピリジン部位をリンカーとするビス(ジピコリルアミン)配位子の錯形成挙動2017

    • Author(s)
      松尾康優、堀内新之介、作田絵里、有川康弘、馬越啓介
    • Organizer
      第54回化学関連支部合同九州大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 2種類のアセチリド配位子を有する新規ヘテロレプティック白金(II)錯体の合成とその発光特性2017

    • Author(s)
      廣岩寛隆、堀内新之介、作田絵里、有川康弘、馬越啓介
    • Organizer
      第54回化学関連支部合同九州大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 水素結合性カプセルへの発光性金属錯体の包接2017

    • Author(s)
      堀内新之介、田中寛隆、作田絵里、有川康弘、馬越啓介
    • Organizer
      第38回光化学若手の会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Development of Highly Emissive Host-Guest Complexes via Self-assembly and Encapsulation2017

    • Author(s)
      S. Horiuchi, H. Tanaka, E. Sakuda, Y. Arikawa, K. Umakoshi
    • Organizer
      The 14th Joint Symposium of Jeju National University and Nagasaki University on Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] White Emission of Dinuclear Pt(II) Complexes bearing Cyclometalated Pyridyl-NHC Ligand2017

    • Author(s)
      S. J. Moon, S. Horiuchi, A. Ito, E. Sakuda, Y. Arikawa, K. Umakoshi
    • Organizer
      The 14th Joint Symposium of Jeju National University and Nagasaki University on Science and Technology
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Remarks] 長崎大学大学院工学研究科 錯体化学研究室Webページ

    • URL

      http://www.cms.nagasaki-u.ac.jp/lab/sakutai/

    • Related Report
      2017 Research-status Report
  • [Remarks] 長崎大学 大学Webページの学術情報欄における研究成果の紹介記事(日本語)

    • URL

      http://www.nagasaki-u.ac.jp/ja/about/info/science/science134.html

    • Related Report
      2017 Research-status Report
  • [Remarks] 長崎大学 大学Webページの学術情報欄における研究成果の紹介記事(英語)

    • URL

      http://www.nagasaki-u.ac.jp/en/about/research/news36.html

    • Related Report
      2017 Research-status Report

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Published: 2017-04-28   Modified: 2020-03-30  

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