Development of Highly Emissive Host-Guest Complexes via Encapsulation of Metal Complexes within Hydrogen-bonded Capsules
| Project/Area Number |
17K14463
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagasaki University |
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Principal Investigator |
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| Project Period (FY) |
2017-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2018: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 発光性超分子 / 自己集合 / 分子認識 / 光化学 / 超分子化学 / 自己組織化 / 光物性 |
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| Outline of Final Research Achievements |
In this study, we investigated development of supramolecular metal complexes insulated by hydrogen-bonded capsules. We found size-dependent formation, excited-state dependent photophysical properties, and encapsulation-condition dependent photophysical properties of the supramolecular metal complexes. These results will open up broad prospects for designing new luminescent materials based on supramolecular metal complexes encapsulated within self-assembled capsules.
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| Academic Significance and Societal Importance of the Research Achievements |
本研究によって金属錯体の包接に基づいた新規発光性超分子の合成手法の開拓とその発光特性の解明を達成した。これらの成果が基礎となり，新しいタイプの発光素子としての応用が見込めれば，材料工学の分野においても新たな切り口を与える可能性がある。現時点では，材料としての可能性は未知であるが，今後これらがもっと洗練され明確な有用性が実証された時には，既存の発光性材料に取って代わる可能性がある。
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Report
(3 results)
Research Products
(23 results)
